Syntheses of New Polynuclear and Low-Dimensional Metal Complexes and Chemical Consequences of Metal Ion Assemblage

1992 Fiscal Year Final Research Report Summary

• Project/Area Number: 02303006
• Research Category: Grant-in-Aid for Co-operative Research (A)
• Allocation Type: Single-year Grants
• Research Field: 無機・錯塩・放射化学
• Research Institution: TOHOKU UNIVERSITY
• Principal Investigator: ITO Tasuku Professor,Faculty of Science,Tohoku University, 理学部, 教授 (90007328)
• Co-Investigator(Kenkyū-buntansha): FUJITA Jyunnosuke Professor,Faculty of Science,Nagoya University, 理学部, 教授 (80004266) ; NAKAMURA Akira Professor,Faculty of Science,Osaka University, 理学部, 教授 (80029404) ; SAITO Taro Professor,Faculty of Science,University of Tokyo, 理学部, 教授 (90011006) ; KAIZAKI Suuumio Professor,Faculty of Science,Osaka University, 理学部, 教授 (20089874) ; OHTAKI Hitoshi Professor,Institute for Molecular Science, 分子科学研究所, 教授 (80022549)
• Project Period (FY): 1990 – 1992
• Keywords: Polynuclear Metal Complex / Metal cluster Complex / Low-dimensional Compound / 錯体集合体

Research Abstract

A total of 19 scientific members of the research group have worked on the titled research project for three years.Research results have been reported in a separate booklet(225 pages).

Research Products

• [Publications] H.Sato,A.Yamagishi,and S.Kato: "Monte Carlo Simulations for the Interactions of Metal Complexes with the silicate sheets of a clay:Comparison of binding states between tris-(1,10-phenanthroline)metal(II)and tris(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Sato,A.Yamagishi,and S.Kato: "Theoretical studies on racemic adsorption of tris(1,10-phenanthroline)matal(II)by a clay:Monte Carlo simulations" J.Phys.Chem.,. 96. 9382-9387 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Nakahanada,T.Fujihara,and S.Kaizaki: "Synthesis and X-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(μ-phenoxo)bis[bis(acetlyacetonato)chromium(III)]Complex and Its Para-Substituted Phenoxo Analogues" Inorg.Chem.,. 31. 1315-1316 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Nakahamada,T.Fujihara,N.Koine,and S.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylacetonate Ions" J.Chem.Soc.,Dalton Trans.,. 3423-3426 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Ohtaki,and N.Fukushima: "A Structural Study of Satutared Aqueous Solution of Some Alkali Halides by X-Ray Diffraction" J.Solution Chem.,. 21. 23-38 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Ozutsumi,T.Takamuku,S.ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate(II)Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.,. 65. 2104-2113 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi,Y.Nishio,K.Kajita,and W.Sasaki: "Metal Instability of(DMe-DCNQI)2Cu Induces by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.,. 115-118 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato,and H.Kobayashi: "Magnetoresistance of α-Et_2Me_2[Ni(dmit)_2]_2Salt" Solid State Commun.,. 82. 157-160 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Based on BEDT-TTF" Mat.Res.Soc.,. 247. 483-494 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] G.Saito: "Organic Superconductors Based on Sulfur and Selenium Compounds" Phosphorus,Sulfur,and Silicon.,. 67. 345-360 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnctic Properties of Oxygen Centeres Trinuclear Ru(III)and Rh(III) Complexes." Bull.Chem.Soc.Jpn.,. 65. 198-202 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] D.Akashi,H.Kido,Y.Sasaki,and T.Ito: "Preparation and Electrochemical Response of Response of Poly(4-vinyl-pyridine)-Coordinated Oxo-Acetato Triruthenium Cluster Film." Chem.Lett.,. 143-146 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide single crystals" Materials Res.Bull.,. 27. 555-562 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Imai,M.Koike,H.sawa,and H.Takei: "Structural change in rhombohedral single crystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.,.
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Suzuki,Y.Hayashi,K.Munezawa,M.Suenaga,H.Senda,and A.Uehara: "Synthesis and Characterization of a Novel Dimer of Di(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett,. 1229-1932 (1991)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] Y.Hayashi,M.Suzuki,and A.Uehara: "(μ-Alkoxo)-diiron(II,II)Comolexes of N,N,N',N'-Tetra-kis(2-6-methylpyridyl)nethyl)-1,3-diaminopropane-2-olate and the Reversible-Formation of the O_2-adduct" Chem.Lett,. 91-94 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Umakishi,A.Ichimura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] T.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II)and Nickel(II)" Chem.Lett,. 883-886 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] T.Shimada,M.Kodera,H.Okawa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaaza-cyclohexatriacontane(L)and its Complex[Cu_4L(OH)_4](ClO_4)_4" J.Chem.Soc.Dalton Trans.,. 1121-1125 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Tadokoro,H.Sakiyama,N.Matsumoto,M.kodera,H.Okawa,and S.Kida: "Template Synthesis of Copper(II)-Lead(II)Complexes of New Binucleating Macrocycles with Dissimilar Coordination Sites" J.Chem.Soc.Dalton Trans.,. 313-317 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] T.Kawamoto,and Y.Kushi: "Crystal and Molecular structure of Tetra-palladium Cluster with a C,N,S-Tridentate Ligand" Chem.Lett.,. 1057-1059 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] T.Kawamoto,and Y.Kushi: "Helical Bis[2-(ferrocanylmethyleneamino)benzenethiolato]Metal(II)Complexes (M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.,. 3137-3143 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] N.Sato,and Y.Fukuda: "Anion Sensing Electrodes Based on Nickel(II)Mixed Ligand Complexes" Chem.Lett.,. 399-402 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Yamada,K.Hori,and Y.Fukuda: "The Structure of(μ-Carbonato)bis[(acetylacetonato)(N,N,N',N'-Tetramethylethylenediamine)nickel(II)][aqua(methanol)(acetylacetonato)(N,N,N',N'-tetramethylethylenediamine)nickel(II)]tetraphenylborate" Acta Cryst.,. (1993)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Triangular Molybdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Eight Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Tsuge,H.Imoto,T.Saito: "Synthesis of[Mo_4S_6(SH)_2(PMe_3)_6]and[Mo_6S_<10>(SH)_2(PEt_3)_6]Consisting of Fused MO_3(μ_3-S)Cluster Units" Inorg.Chem.,. 23. 4715-4716 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II)Cluster Complexes[Pt_3(CH_3COO)_4(cdoH)_2(cdoH_2)]and[Pt_3(CH_3COO)_4(dmgH)_2(dmgH_2)](cdoH_2=cyclohexanedionedioxime and dmgH_2=dimethyglyoxime)" J.Am.Chem.Soc.,. 115. (1993)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H.Kobayashi,N.Uryu,and I.Mogi: "Mixed Chromium(III)-Ruthenium(III) Trinuclear Complex,[CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.,. 69-72 (1993)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] Y.Ozawa,A.Vazquez de Miguel,and K.Isobe: "μ-Methylene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^*_2(μ-CH_2)_2(μ-SH)]Bph_4 and trans[Rh_2Cp^*_2(μ-CH_2)_2(SH)_2](Cp^*=η^5-C_5Me_5)" J.Organomet.Chem.,. 433. 183-188 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Akashi,K.Isobe,Y.Ozawa,and A.Yagasaki.,: "β-Methallylrhodium(III)Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.,. 2. 291-296 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] N.Ueyama: "Synthesis,Crystal Structure and Electronic properties of a 2Fe-2S Complex with a Bulky Thiolato Ligand" J.Chem.Soc.,. 2723-2727 (1991)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenylphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] K.Nakajima,K.Kojima,M.Kojima,and J.Fujita: "Preparation and Characterization of Optically Active Schiff Base-Oxo-vanadium(IV)and-Oxovanadium(IV)Complexes and Catalytic Properties of These Complexes on Asymmetric Oxidation of Sulfid into Sulfoxides with Organic Hydroperoxides" Bull.Chem.Soc.Jpn.,. 63. 2620-2630 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] C.Sasaki,K.Nakajima,M.Kojima,and J.Fujita: "Preparation and Characterization of Optically Active Quadridentate Schiff Base-Titanium(IV)Complexes and the Catalytic Properties of These Complexes on Asymmetric Oxidation of Methyly Phenyl Sulfides with Organic Hydroperoxides" Bull.Chem.Soc.Jpn.64. 1318-1324 (1991)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Kawano,C.Hoshino,and K.Matsumoto: "Synthesis,Properties and Crystal Structure of a Novel μ-Hydragine-Bridged Mixed-Valonce Rutenium(II,III) Complex Stabilized by Hydrazine Hydrogen Bonds,[RuCl(TMP)_2]_2(μ-Cl)(μ-N_2H_4)(μ-S_2)(TMP=P(OMe)_3)" Inorg.Chem.,. 31. 5158-5159 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Uemura,M.Kawano,T.Watanabe,T.Matsumoto,and K.Matsumoto: "Synthesis and Crystal Structure of a Binuclear Rutenium Compound Containing[Ru_2(μ-S_5)(μ-S_2CNMe_2)(S_2CNMe_2)(CO)_2(PPh_3)_2]and[Ru_2(μ-S_6)(μ-S_2CNMe_2)(S_2CNMe_2)(CO)_2(PPh_3)_2]:The First RutheniumCompounds with Bridging S_5 and S_6 Ligands" Inorg.Chem,.31. 5137-5139 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I)Complexes with Alkynes and 1,10-Phenanthroline." J.Chem.Soc.,Dalton.Trans.,. 2225-2230 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinite-Sheet and-Chain Copper(I)Complex Polymers,{[Cu(C_4H_4N_2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_∞ and{[Cu(C_8H_<12>N_2)_3](ClO_4)_2}_∞ and Their X-ray Crystal Structures" Inorg.Chem.,. 31. 1714-1717 (1992)
  • Description: 「研究成果報告書概要(和文)」より
• [Publications] H.Sato,A.Yamagishi,and S.Kato: "Monte Carlo Simulations for the Interactions of Metal Complexes with the silicate sheets of a clay: Comparison of binding states between tris-(1,10-phenanthroline)metal (II) and tris(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.114. 10933-10940 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Sato,A.Yamagishi,and S.Kato: "Theoretical studies on racemic adsorption of tris(1,10-phenanthroline)metal(II) by a clay:Monte Carlo simulations" J.Phys.Chem.96. 9382-9387 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Nakahanada,T.Fujihara,and,S.Kaizaki: "Synthesis and X-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(mu-phenoxo)bis(bis(acetylacetonato)chromium(III))Complex and Its Para-Substituted Phenoxo Analogues" Inorg.Chem.31. 1315-1316 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Nakahanada,T.Fujihara,N.Koine,and S.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylacetonate Ions" J.Chem.Soc.,Dalton Trans.3423-3426 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Ohtaki and N.Fukushima: "A Structural Study of Satutared Aqueous Solution of Some Alkali Halides by X-Ray Diffraction" J.Solution Chem.21. 23-38 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Ozutsumi,T.Takamuku,S.Ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate (II) Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.65. 2104-2113 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Suzuki,Y.Hayashi,K.Munezawa,M.Suenaga,H.Senda,and A.Uehara: "Synthesis and Characterization of a Novel Dimer of Di(mu-oxo) manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.1229-1932 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] Y.Hayashi,M.Suzuki,and A.Uehara: "(mu-Alkoxo)-diiron(II,II) Complexes of N,N,N',N'-Tetra-kis(2-6-methylpyridyl)methyl)-1,3- diaminopropane-2-olate and the Reversible Formation of the O_2-adduct" Chem.Lett.91-94 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] T.Umakoshi,A.Ichimura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II) Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.29. 4005-4010 (1990)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] Y.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II) and Nickel(II)" Chem.Lett.883-886 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] T.Shimada,M.Kodera,H.Okawa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaaza-cyclohexatriacontane(L)and its Complex [Cu_4L(OH)_4](ClO_4)_4" J.Chem.Soc.Dalton Trans.1121-1125 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Tadokoro,H.Sakiyama,N.Matsumoto,M.Kodera,H.Okawa,and s.Kida: "Template Synthesis of Copper(II)-Lead(II)Complexes of New Binucleating Macrocycles with Dissimilar Coordination Sites" J.Chem.Soc.Dalton Trans.313-317 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] T.Kawamoto and Y.Kushi: "Crystal and Molecular structure of Tetra-palladium Cluster with a C,N,S-Tridentate Ligand" Chem.Lett.1057-1059 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] T.Kawamoto and Y.Kushi: "Helical Bis(2-(ferrocanylmethyleneamino)benzenethiolato)Metal(II)Complexes(M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.3137-3143 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi Y.Nishio,K.Kajita, and W.Sasaki: "Metal Instability of(DMe-DCNQI)2Cu Induced by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.115-118 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato and H.Kobayashi: "Magnetoresistance of alpha-Et_2Me_2[Ni(dmit)_2]_2 Salt" Solid State Commun.82. 157-160 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Based on BEDT-TTF" Mat.Res.Soc.247. 483-494 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] G.Saito: "Organic Superconductors Based on Sulfur and Selenium Compounds" Phosphorus,Sulfur,and Silicon.67. 345-360 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnectic Properties of Oxygen Centered Trinuclear Ru(III)and Rh(III) Complexes" Bull.Chem.Soc.Jpn.65. 198-202 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] D.Akashi,H.Kido,Y.Sasaki,and T.Ito: "Preparation and Electrochemical Response of Poly(4-vinyl-pyridine)-Coordinated Oxo-Acetato Triruthenium Cluster Film" Chem.Lett.143-146 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide single crystals" Materials Res.Bull.27. 555-562 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Imai,M.Koike,H.sawa,and H.Takei: "Structural change in rhombohedral single crystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] N.Ueyama,S.Ueno,T.Sugawara,K.Tatsmi,A.Nakamura,and N.Yasuoka: "Synthesis,Crystal Structure and Electronic properties of a 2Fe-2S Complex with a Bulky Thiolato Ligand" J.Chem.Soc.2723-2727 (1991)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Mashima,H.Nakano,T.Mori,H.Takaya,and A.Nakamura: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters.Crystal Structure of Tetrakis(6-di-phenylphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Nakajima,K.Kojima,M.Kojima,and J.fujita: "Preparation and Characterization of Optically Active Schiff Base-Oxo-vanadium(IV) AND -Oxovanadium(IV) Complexes and Catalytic Properties of These Complexes on Asymmetric Oxidation of Sulfid into Sulfoxides with Organic Hydroperoxides" Bull.Chem.Soc.Jpn.63. 2620-2630 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] C.Sasaki,K.Nakajima,M.Kojima,and J.Fujita: "Preparation and Characterization of Optically Active Quadridentate Schiff Base-Titanium (IV) Complexes and the Catalytic Properties of These Complexes on Asymmetric Oxidation of Methyly Phenyl Sulfides with Organic Hydroperoxides" Bull.Chem.Soc.Jpn.64. 1318-1324 (1991)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Kawano,C.Hoshino,and K.Matsumoto: "Synthesis, Properties and Crystal Structure of a Novel mu-Hydragine-Bridged Mixed-Valonce Rutenium(II,III) Complex Stabilized by Hydrazine Hydrogen Bonds, [RuCl(TMP)_2]_2(mu-Cl)(mu-N_2H_4)(mu-S_2)(TMP=P(OMe)_3)" Inorg.Chem.31. 5158-5159 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Uemura,M.Kawano,T.Watanabe,T.Matsumoto,and K.Matsumoto: "Synthesis and Crystal Structure of a Binuclear Rutenium Compound Containing[Ru_2(mu-S_5)(mu-S_2CNMe_2)(S_2CNMe_2)(CO)_2 (PPh_3)_2] and [Ru_2(mu-S_b)(mu-S_2CNMe_2)(S_2CNMe_2)(CO)_2(PPh_3)_2]:The First Ruthenium Compounds with Bridging S_5 and S_6 Ligands" Inorg.Chem.31. 5137-5139 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I) Complexes with Alkynes and 1,10-Phenanthroline" J.Chem.Soc.,Dalton.Trans.2225-2230 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinite-Sheet and -Chain Copper(I) Complex Polymers,{[Cu(C_4H_4N_2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_* and {[Cu(C_8H_<12>N_2)_3](ClO_4)_2}_* and Their X-ray Crystal Structures" Inorg.Chem.31. 1714-1717 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] N.Sato and Y.Fukuda: "Anion Sensing Electrodes Based on Nickel(II) Mixed Ligand Complexe" Chem.Lett.399-402 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Yamada,K.Hori,and Y.Fukuda: "The Structure of(mu-Carbonato)bis *(acetylacetonato)(N,N,N',N'-Tetra-methylethylenediamine)nickel(II) *aqua(methanol)(acetylacetonato)(N,N,N',N'- tetramethylethylenediamine)nickel(II)*tetraphenylborate" Acta Crystallog.(1993)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Triangular Molybdenum Cluster Complex [Mo_3(mu_3-S)_2(mu-S)_3(PMe_3)_6] with Eight Cluster Valence Electrons" J.Am.Chem.Soc.114. 7910-7912 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] K.Tsuge.H.Imoto,T.Saito: "Synthesis of [Mo_4S_6(SH)_2(PMe_3)_6] and [Mo_6S_<10>(SH)_2(PEt_3)_6]Consisting of Fused MO_3(mu_3-S) Cluster Units" Inorg.Chem.23. 4715-04716 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II) Cluster Complexes[Pt_3(CH_3COO)_4(cdoH)_2(cdoH_2)] and [Pt_3(CH_3COO)_4(dmgH)_2(dmgH_2)](cdoH_2=cyclohexanedionedioxime and cmgH_2=dimethyglyoxime)" J.Am.Chem.Soc.115. (1993)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H.Kobayashi,N.Uryu,and I.Mogi: "Mixed Chromium(III)-Ruthenium(III) Trinuclear Complex, [CrRu_2(mu_3-O)(mu-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.69-72 (1993)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] Y.Ozawa,A.Vazquez de Miguel,and K.Isobe: "mu-Methylene Rhodium Complexes with SH Ligand:Synthesis and Structures of [Rh_2Cp*_2(mu-CH_2)_2(mu-SH)]Bph_4 and trans [Rh_2Cp*_2(mu-CH_2)_2(SH)_2](Cp*=eta^5-C_5Me_5)" J.Organomet.Chem.433. 183-188 (1992)
  • Description: 「研究成果報告書概要(欧文)」より
• [Publications] H.Akashi,K.Isobe,Y.Ozawa,and A.Yagasaki: "beta-Methallylrhodium(III) Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.2. 291-296 (1992)
  • Description: 「研究成果報告書概要(欧文)」より