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1993 Fiscal Year Final Research Report Summary

Analysis of metal surface properties by impedance measurement and its method

Research Project

Project/Area Number 02403014
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionNagoya University

Principal Investigator

OKI Takeo  Nagoya University, Faculty of Engineering, Professor, 工学部, 教授 (30023039)

Co-Investigator(Kenkyū-buntansha) ICHINO Ryouichi  Nagoya University, Faculty of Engineering, Assistant Professor, 工学部, 助手 (70223104)
OKIDO Masazumi  Nagoya University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (50126843)
YAMAUCHI Chikabumi  Nagoya University, Faculty of Engineering, Professor, 工学部, 教授 (40115647)
CHOH Takao  Nagoya University, Faculty of Engineering, Professor, 工学部, 教授 (50023114)
Project Period (FY) 1990 – 1993
KeywordsImpedance / Surface reactivity / Surface Homogeneity / Frequency response / Ladder network / Electrochemical impedance
Research Abstract

Metal surfaces were characterized by interfacial impedance technique. Surface reactivity and its distribution degree were calculated from impedance parameters in order to estimate the metal electrodes in several aqueous solutions. A new electrical equivalent circuit accounting for metal/solution interface about the surface heterogeneity of electrode was proposed to be a ladder network consisting of surface double layr capacitance, charge transfer resistance and solution resistance. This surface estimation was applied to electrochemical processes such as degreasing for plated materials, evaluation of additives in solution, the corrosion under coated films, nickel plating, copper plating and the etching of aluminum foil for electric capacitor. In case of the additives in solution, the addition of inhibitor lead a surface homogeneity and low reactivity. The monitoring of the steel degreasing in acid solution was found to be possible by these parameters. In the etching for the aluminum, electrochemical dissolution of the regular tunnel pit into the certain direction had a low time constant value, but formation of irregular pits enlarged the time constant value. From these experimental results, impedance technique is considered to be useful to the characterization of metal surface.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 沖猛雄: "銅電析の析出形態、配向性とインピーダンス特性に及ぼす塩化物イオンの影響" 資源・素材学会誌. 106. 539-543 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 市野良一: "電極表面の反応サイトの均一性に及ぼす添加剤の効果" 日本金属学会誌. 54. 1072-1077 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 市野良一: "電気化学的手法による電解脱脂中の表面変化測定" 表面技術. 41. 761-765 (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.l.Zhou: "An Explanation for Depressed Semi-Circular Arcs in Interfacial Impedance Plots of the Materials Interface between Metal and Electrolyte" Transactions,JIM. 32. 1159-1163 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 興戸正純: "界面インピーダンス法の基礎と金属材料への応用" 日本金属学会会報. 32. 199-207 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 日比野淳: "定電位法による電解コンデンサー用アルミニウム箔のエッチング特性" 表面技術. 45. 207-212 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Oki, M.Okido, R.Ichino, Y.Zhou and A.Ohtsuka: "Effect of Chloride Ions on the Morphology, Orientation and Impedance characteristics for the Copper Deposition." J.Mining and Materials Processing Institute of Japan. 106-9. 539-543 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Ichino, M.Okido and T.Oki: "Effect of the Additives on Uniformity of Reaction Site on Electrode Surface." J.Japan Institute of Metals. 54-10. 1072-1077 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Ichino, M.Okido and T.Oki: "Monitoring of electrolytic Degreasing by Impedance Measurements." J.Surface Finishing Society of Japan. 41-7. 761-765 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Zhou, R.Ichino, M.Okido and T.Oki: "An Explanation for Depressed Semi-circular Arcs in Interfacial Impedance Plots of the Interface between Metal and Electrolyte." Materials Transactions, JIM. 32-12. 1159-1163 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Okido and T.Oki: "Fundamentals of Interfacial Impedance Methods and applications to Metallic Materials." Japan Institute of Metals. 32-4. 199-207 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A.Hibino, M.Okido and T.Oki: "Etching Behavior of Aluminium in Hydrochloric Acid under Potentiostatic Condition." J.Surface Finishing Society of Japan. 45-2. 207-212 (1990)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1995-03-27  

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