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1991 Fiscal Year Final Research Report Summary

Synthesis and property of new functionalized porphyrins

Research Project

Project/Area Number 02453022
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 有機化学一般
Research InstitutionEhime University

Principal Investigator

ONO Noboru  Ehime University Professor Faculty of Science, 理学部, 教授 (40093215)

Project Period (FY) 1990 – 1991
Keywordsnitroalkene / pyrrole / porphyrin / water-soluble / oxidation / Iron porphyrin
Research Abstract

General synthesis of pyrroles and porphyrins starting from nitroalkenes has been studied and the following results have been obtained.
(1)Synthesis of dodecathienylporphyrins(DTP) ; This porphyrins show several unusual properties ; it is more easily oxidized and absorbs light at lower energies than the usual tetraarylporphyrins. FE-DTP is an efficient catalyst for epoxidation of alkenes. (2)Synthesis of Porphyrins with donor and acceptor : Porphyrins with anisyl and nitro grouptend to aggragation(S, for example, the ESR spectra of such porphyrins show the strong triplet which indicate the aggregation of porphyrins. The distance of Cu-Cu is estimated to be 4A. (3)Porphyrins substituted with four sugar moieties are prepared, which are freely soluble in water and show the efficient photosensitizing activity. (4)Preparation of porphyrins with ester, cyano, nitro. A new porphyrin with electron withdrawing groups has been prepared. Thus, we could develop the new way to control the property of porphyrins.

  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] Noboru Ono: "preparation of 2-formyl-4-nilropyrroles" J.Heterocyclc Chem. 28. 2053-2055 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Noboru Ono: "preparation of porphyurins having esters and nibo functions." Chem Expreas. 6. 869-872 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Noboru Ono: "preparation of slable 5,15-dihydroporplyrins" Bull.Chem.Soc.Jpn. 64. 3471-3472 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Rui Tamura: "Displacement of alipholc nitro groups by corlon and heterom nucleophcle" Synthis. 423-434 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Noboru Ono: "Water-soluble pophyrins with four sugin molecules" Tetrahidron. (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Noboru Ono: "Preparation of 2-formyl-4-nitropyrrole" J. Heterocyclic Chem. 28. 2053-2055 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Noboru Ono: "Preparation of porphyrins having ester and nitro functions" Chem. Express. 6. 869-872 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Noboru Ono: "Preparation of stable 5, 15-dihydro porphyrins" Bull. Chem. Soc. Jpn.64. 3471-3472 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Rui Tamura and Noboru Ono: "Displacement of aliphatic nitro groups by carbon and heteroatom nucleophiles" Synthesis. 423-434 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Noboru Ono: "Water-soluble porphyrins with four sugar molecules" Tetrahedron Lett. (1992)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-03-16  

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