1991 Fiscal Year Annual Research Report

新規プロセスによる機能性材料の作製

Research Project

Project/Area Number	03204003
Research Institution	University of Tsukuba
Principal Investigator	若槻雅男筑波大学, 物質工学系, 教授 (50114153)
Co-Investigator(Kenkyū-buntansha)	佐藤真理岡崎共同研究機構, 分子科研, 助教授 (70001724) 八木健彦東京大学, 物性研究所, 助教授 (20126189) 長田義仁茨城大学, 工学部, 教授 (60007804) 宮本欽生大阪大学, 産業科学研究所, 助教授 (60107084) 松井正顕名古屋大学, 工学部, 教授 (90013531)
Keywords	高圧力 / 格子定数制御 / 燃焼反応 / プラズマ重合 / 表面光化学反応 / ダイヤモンド / 傾斜機能材料 / 磁性
Research Abstract	超高圧を利用した物質作製プロセスに関しては、新しい機能性材料であるダイヤモンドの高純度化のために、成長ファセットの制御によって育成用溶融剤元素の包含を抑制することが出来た。また原料と育成実験雰囲気からの窒素排除を試み、窒素に関しても高純度化することが出来た(若槻)。さらに超高圧による黒鉛→六方晶ダイヤモンド変換過程をX線回折で追跡し、六方晶ダイヤモンドの出現過程を世界で初めてその場観察し、変換機構考察の重要な立脚点を構築した(八木)。 Cu(Au)合金上へのMBE成長によって非平衡格子定数を実現したfccーFe磁性薄膜に関しては、0〜4%の範囲で格子定数拡大を与えた。拡大率1%付近では原子当り磁気モ-メントは0.5〜0.7μ_B/%という大きな変化を示し、また観測された最大磁気モ-メントは2.5〜2.7μ_B(予想限界2.8〜3.0μ_B)で、高飽和磁化膜実現が期待される(松井)。生成熱を利用する超高温急速反応法(自己燃焼法)に関しては、雰囲気ガスの高圧(密度)化やや原料固体の形態、組成によって反応を制御し、設計された傾斜組成分布を持つ複合体セラミックス(TiC/Ni)を作製し、強度の向上を確認した(宮本)。通常の化学反応では実現しない新規高温化学反応を、ラジオ波及びマイクロ波を使用した非平衡プラズマプロセスで実現し、バナジウム含有有機金属化合物から幅広い電気伝導性や光伝導性をを有する高分子/金属多相系薄膜を合成し、高周波振動数、プラズマエネルギ-等が膜構造と特性に与える影響を明らかにした(長田)。材料作製への表面光化学反応の利用と反応解析では、SOR光に集光鏡を組み合わせ、従来の10倍に強化した極端紫外光源を実現し、固体表面での金属カルボニル、アルキル金属化合物の吸着と分解、表面の触媒作用等を観察し、極端光強度下の光化学の知見を集積した(佐藤)。

Research Products

(35 results)

All Other

All Publications (35 results)

[Publications] M.Wakatsuki: "Detection of impurities in diamond grown in the metallic sonvent by x-ray fluorescence using synchrotron radiation." "New Diamond Science and Technology",ed.by R.Messier,et al(Proc.2nd International Conf.on New Diamond Science and Technology,Washington,1990),MRS,Pittsburg(1991). 143-148 (1991)
[Publications] K.J.Takano: "New high-pressure phases of carbon." Japan.J.Appl.Phys.30. L860-L863 (1991)
[Publications] K.J.Takano: "An optical high pressure cellwith spherical sapphire anvils" Rev.Sci.Instrum.62. 1576-1580 (1991)
[Publications] M.Wakatsuki: "Some features of growing process of diamond." Proc.13th International AIRAPT Conf.(International Association for The Advancement of High Pressure Science and Technology),Bangalore,India,Oct.9,1991(invited).
[Publications] M.Doyama: "Preparation and physical properties of fcc-iron and copper multilayers." J.Magn.Magn.Met.93. 374-378 (1991)
[Publications] 土居正晶: "Nd_2Fe_<14>BのFeサイトの置換効果" 日本応用磁気学会誌. 15. 233-236 (1991)
[Publications] M.Matsui: "Epitaxial growth and magnetic properties of multilayered fss-Fe/Cu films." First Kyoto-Duisburg Workshop on Ultrathin Megnetic films and Multilayers,1991. 30-31 (1991)
[Publications] S.Miatani: "Epitaxial growth and magnetic properties of multilayered fcc-Fe/Cu(100) and Fe/Cu(111) artificial lattice." Proc.Int.Symp.on 3d Transition-Semi Metal Thin Films-Magnetism and Processing-,Sendai,1991. 339-345 (1991)
[Publications] T.Kobayashi: "Interstitial heating of tumor tissue by implant heating system (IHS)." Hyperthermic Oncology in Japan '90. 71-74 (1991)
[Publications] I.Tohnai: "The histopathological effect of hyperthermochemotherapy using implant heating system for oral cancer." Hyperthermic Oncology in Japan "90. 99-100 (1991)
[Publications] K.Mitsudo: "Development of a platinel thermocouple using implant heating system (IHS)." Hyperthermic Oncology in Japan '90. 223-224 (1991)
[Publications] M.Matsui: "Heat generation of the powder magnetic implant materials." Hyperthermic Oncology in Japan '90. 243-244 (1991)
[Publications] T.Uchida: "Structural fluctuations in gold microclusters." Computer Aided Innovation of New Materials,(Proc.CAMSE'90). 371-374 (1991)
[Publications] 三谷誠司: "原子間隔制御による強磁性FCCーFeの飽和磁化" 日本応用磁気学会誌. 16. (1992)
[Publications] X.Ma,: "A new route for composites:Gas-pressure combustion sintering." Proc.1st Int.Symp.on The Science and Engineering Ceramics. 7-12 (1991)
[Publications] J.Zeng: "Combustion synthesis of Si_3N_4-SiC composite powders." J.Am.Ceram.Soc.74. 2197-2200 (1991)
[Publications] X.Ma: "Gas-pressure combustion sintering and properties of TiC-Ni composites using HIP." Proc.3rd Int.Conf.on Hot Isostatic Pressing,Elsevier Applied Science. 445-450 (1992)
[Publications] H.Klemm: "Gas-pressure combustion sintering of materials in the Ti-Si-C system." Proc.3rd Int.conf.on Hot Isostatic Pressing,Elsevier Applied Science. 451-456 (1991)
[Publications] X.Ma: "Gas-pressure combustion sintering of Cr_3C_2 ceramic and its composites with TIC." J.Ceram.Soc.Japan. 99. (1992)
[Publications] Y.Miyamoto: "Synthesis of functionally gradient materials by the gas-pressure combustion sintering." Proc.Japan congress on Materials Research,Soc.Mat.Sci.Japan. (1992)
[Publications] 長田義仁: "チタン含有プラズマ重合膜の導電率と有機ガス応答特性" 日本化学会誌. (1992)
[Publications] W.Utsumi: "Light transparent phase formed by room temperature compression of graphite." Science. 252. 1542-1544 (1991)
[Publications] W.Utsumi: "Formation of hexagonal diamond by room temperature compression of graphite." Proc.Jpn.Acad.67B. 159-164 (1991)
[Publications] T.Yagi: "High pressure in situ diffraction study of the phase transformation from graphite to hexagonal diamond at room temperature." ISSP Technical Report,Ser.A,. No.2507. (1992)
[Publications] T.Suzuki: "Metal-silicate-water reaction under high pressure-partition of Fe,Ni and Co between metal and silicate." Phys.Earth Planet.Interior.
[Publications] K.Leinenweber: "Unquenchable high pressure perovskite polymerphs of MnsnO_3 and FeTiO_3." Phys.Chem.Minarals. 18. 244-250 (1991)
[Publications] O.Shimomura: "MAX90:A new high pressure and high temperature apparatus with sintered diamond anvil for synchrotron radiation use." High Pressure Research in Mineral Physics:Application to Earth and Planetary Sciences.TERRAPUB/AGU. (1992)
[Publications] W.Utsumi: "High pressure and high temperature generation using sintered diamond anvils." High Pressure Research in Mineral Physics: Application to Earth and Planetary Sciences,TERRAPUB/AGU. (1992)
[Publications] T.Yagi: "Laser heating system for diamond anvil using CO_2 laser." High Pressure Research in Mineral Physics:Application to Earth and Planetary Sciences,TERRAPUB/AGU. (1992)
[Publications] S.Sato: "IR study on the photochemistry and adsorption states of iron carbonyls adsorbed on alumina." J.Phys.chem.95. 7778-7781 (1991)
[Publications] Y.Ukisu: "Photochemistry of iron pentacarbonyls adsorbed on titanium oxide." Appl.Organomet.chem.5. 243-246 (1991)
[Publications] Y.Ukisu: "Surface isocyanate intermediate formed during the catalytic reduction of nitrogen oxide in the pressure of oxigen and propylene." Catal.Lett.11. 177-182 (1991)
[Publications] 佐藤真理: "半導体粉末による水の完全光分解" 触媒. 33. 209-214 (1991)
[Publications] 若槻雅男: "実験化学講座4,「熱・圧力」(日本化学会編)11.4節(1)項“ダイヤモンドと窒化ホウ素の合成"を担当,PP.490ー497" 丸善, 534 (1992)
[Publications] Y.Osada: "Plasma Polymerization Process" Elsevier Pub.,

1991 Fiscal Year Annual Research Report

新規プロセスによる機能性材料の作製

Principal Investigator

若槻 雅男 筑波大学, 物質工学系, 教授 (50114153)

Research Products

[Publications] K.J.Takano: "New high-pressure phases of carbon." Japan.J.Appl.Phys.30. L860-L863 (1991)

[Publications] K.J.Takano: "An optical high pressure cellwith spherical sapphire anvils" Rev.Sci.Instrum.62. 1576-1580 (1991)

[Publications] M.Wakatsuki: "Some features of growing process of diamond." Proc.13th International AIRAPT Conf.(International Association for The Advancement of High Pressure Science and Technology),Bangalore,India,Oct.9,1991(invited).

[Publications] M.Doyama: "Preparation and physical properties of fcc-iron and copper multilayers." J.Magn.Magn.Met.93. 374-378 (1991)

[Publications] 土居 正晶: "Nd_2Fe_<14>BのFeサイトの置換効果" 日本応用磁気学会誌. 15. 233-236 (1991)

[Publications] M.Matsui: "Epitaxial growth and magnetic properties of multilayered fss-Fe/Cu films." First Kyoto-Duisburg Workshop on Ultrathin Megnetic films and Multilayers,1991. 30-31 (1991)

[Publications] S.Miatani: "Epitaxial growth and magnetic properties of multilayered fcc-Fe/Cu(100) and Fe/Cu(111) artificial lattice." Proc.Int.Symp.on 3d Transition-Semi Metal Thin Films-Magnetism and Processing-,Sendai,1991. 339-345 (1991)

[Publications] T.Kobayashi: "Interstitial heating of tumor tissue by implant heating system (IHS)." Hyperthermic Oncology in Japan '90. 71-74 (1991)

[Publications] I.Tohnai: "The histopathological effect of hyperthermochemotherapy using implant heating system for oral cancer." Hyperthermic Oncology in Japan "90. 99-100 (1991)

[Publications] K.Mitsudo: "Development of a platinel thermocouple using implant heating system (IHS)." Hyperthermic Oncology in Japan '90. 223-224 (1991)

[Publications] M.Matsui: "Heat generation of the powder magnetic implant materials." Hyperthermic Oncology in Japan '90. 243-244 (1991)

[Publications] T.Uchida: "Structural fluctuations in gold microclusters." Computer Aided Innovation of New Materials,(Proc.CAMSE'90). 371-374 (1991)

[Publications] 三谷 誠司: "原子間隔制御による強磁性FCCーFeの飽和磁化" 日本応用磁気学会誌. 16. (1992)

[Publications] X.Ma,: "A new route for composites:Gas-pressure combustion sintering." Proc.1st Int.Symp.on The Science and Engineering Ceramics. 7-12 (1991)

[Publications] J.Zeng: "Combustion synthesis of Si_3N_4-SiC composite powders." J.Am.Ceram.Soc.74. 2197-2200 (1991)

[Publications] X.Ma: "Gas-pressure combustion sintering and properties of TiC-Ni composites using HIP." Proc.3rd Int.Conf.on Hot Isostatic Pressing,Elsevier Applied Science. 445-450 (1992)

[Publications] H.Klemm: "Gas-pressure combustion sintering of materials in the Ti-Si-C system." Proc.3rd Int.conf.on Hot Isostatic Pressing,Elsevier Applied Science. 451-456 (1991)

[Publications] X.Ma: "Gas-pressure combustion sintering of Cr_3C_2 ceramic and its composites with TIC." J.Ceram.Soc.Japan. 99. (1992)

[Publications] Y.Miyamoto: "Synthesis of functionally gradient materials by the gas-pressure combustion sintering." Proc.Japan congress on Materials Research,Soc.Mat.Sci.Japan. (1992)

[Publications] 長田 義仁: "チタン含有プラズマ重合膜の導電率と有機ガス応答特性" 日本化学会誌. (1992)

[Publications] W.Utsumi: "Light transparent phase formed by room temperature compression of graphite." Science. 252. 1542-1544 (1991)

[Publications] W.Utsumi: "Formation of hexagonal diamond by room temperature compression of graphite." Proc.Jpn.Acad.67B. 159-164 (1991)

[Publications] T.Yagi: "High pressure in situ diffraction study of the phase transformation from graphite to hexagonal diamond at room temperature." ISSP Technical Report,Ser.A,. No.2507. (1992)

[Publications] T.Suzuki: "Metal-silicate-water reaction under high pressure-partition of Fe,Ni and Co between metal and silicate." Phys.Earth Planet.Interior.

[Publications] K.Leinenweber: "Unquenchable high pressure perovskite polymerphs of MnsnO_3 and FeTiO_3." Phys.Chem.Minarals. 18. 244-250 (1991)

[Publications] O.Shimomura: "MAX90:A new high pressure and high temperature apparatus with sintered diamond anvil for synchrotron radiation use." High Pressure Research in Mineral Physics:Application to Earth and Planetary Sciences.TERRAPUB/AGU. (1992)

[Publications] W.Utsumi: "High pressure and high temperature generation using sintered diamond anvils." High Pressure Research in Mineral Physics: Application to Earth and Planetary Sciences,TERRAPUB/AGU. (1992)

[Publications] T.Yagi: "Laser heating system for diamond anvil using CO_2 laser." High Pressure Research in Mineral Physics:Application to Earth and Planetary Sciences,TERRAPUB/AGU. (1992)

[Publications] S.Sato: "IR study on the photochemistry and adsorption states of iron carbonyls adsorbed on alumina." J.Phys.chem.95. 7778-7781 (1991)

[Publications] Y.Ukisu: "Photochemistry of iron pentacarbonyls adsorbed on titanium oxide." Appl.Organomet.chem.5. 243-246 (1991)

[Publications] Y.Ukisu: "Surface isocyanate intermediate formed during the catalytic reduction of nitrogen oxide in the pressure of oxigen and propylene." Catal.Lett.11. 177-182 (1991)

[Publications] 佐藤 真理: "半導体粉末による水の完全光分解" 触媒. 33. 209-214 (1991)

[Publications] 若槻 雅男: "実験化学講座4,「熱・圧力」(日本化学会編)11.4節(1)項“ダイヤモンドと窒化ホウ素の合成"を担当,PP.490ー497" 丸善, 534 (1992)

[Publications] Y.Osada: "Plasma Polymerization Process" Elsevier Pub.,

若槻雅男筑波大学, 物質工学系, 教授 (50114153)

[Publications] 土居正晶: "Nd_2Fe_<14>BのFeサイトの置換効果" 日本応用磁気学会誌. 15. 233-236 (1991)

[Publications] 三谷誠司: "原子間隔制御による強磁性FCCーFeの飽和磁化" 日本応用磁気学会誌. 16. (1992)

[Publications] 長田義仁: "チタン含有プラズマ重合膜の導電率と有機ガス応答特性" 日本化学会誌. (1992)

[Publications] 佐藤真理: "半導体粉末による水の完全光分解" 触媒. 33. 209-214 (1991)

[Publications] 若槻雅男: "実験化学講座4,「熱・圧力」(日本化学会編)11.4節(1)項“ダイヤモンドと窒化ホウ素の合成"を担当,PP.490ー497" 丸善, 534 (1992)