1991 Fiscal Year Annual Research Report

分子認識場の設計

Research Project

Project/Area Number	03214106
Research Institution	Kyushu University
Principal Investigator	新海征治九州大学, 工学部, 教授 (20038045)
Co-Investigator(Kenkyū-buntansha)	中辻洋司大阪大学, 工学部, 助教授 (00127268) 戸田芙三夫愛媛大学, 工学部, 教授 (50036232) 古賀憲司東京大学, 薬学部, 教授 (10012600) 笠井暢民大阪大学, 工学部, 教授 (50028958) 稲津孝彦九州大学, 理学部, 教授 (60037207)
Keywords	カリックスアレ-ン / デオキシコ-ル酸 / クラウンエ-テル / シクロファン / シクロデキストリン / 分子認識 / 包接化合物 / 光学分割
Research Abstract	カリックスアレ-ンの自己組織化能を利用することにより,ゲスト分子の識別を分子集合体の変化で読み出す新しいセンシングシステムを開発した(新海)。デオキシコ-ル酸骨格を巧みに利用してC_3対称性を有する疎水空孔の開発に成功し,有機ゲストをピンセット的に取り込む試みを行なった(稲津)。金属を包接したカリックスアレ-ンの構造的特性をX線構造解析により明らかにし,そのカルボニル基の配向が錯化により著しく変化することを明らかにした(笠井)。ジフェニルメタン骨格を有するシクロファンを合成し,静電相互作用を利用した基質選択性を新しい方法論として例示した(古賀)。ヒドロキシホスト化学物を用いる結晶中の分子認識作用について研究し,画期的な光学分割能力を有することが明らかにされた(戸田)。カルボン酸側鎖を持つ18ークラウンー6誘導体を用いて人工液膜輸送を行ない,pH勾配を利用してNa^+とK^+の対向輸送が可能なことを初めて示した(中辻)。レゾルシノ-ル四量体を用いて糖類の識別を行う方法論を開発し,その認識の由来について一般化することに成功した(青山)。合成二分子膜を反応場とする系で高選択性の人工酵素系を組み立てることに成功し,その理論的評価を行なった(大久保)。ジペプチド固相系でCHーπ相互作用が存在することを立証し,その作用を利用して高度の分子識別が可能なことを示した(小倉)。コンホメ-ションが固定されたカリックスアレ-ン類縁体を合成し,そのゲスト認識能が著しく改良されることを明らかにした(西村)。アミノ化シクロデキストリンと無機アニオンの相互作用をNMRで検討し,硫酸イオンと特異的に錯体を形成することを明らかにした(松井)。以上の研究の結果,多種多様の分子認識場が開発され,分子認識化学の新しい方法論を例示することができた。

Research Products
(62 results)

All Other

All Publications (62 results)

[Publications] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)
[Publications] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)
[Publications] T.Sugimoto: "Tercalicen und Quatercalicen" Angew.Chem.103. 454-456 (1991)
[Publications] T.Sugimoto: "Biradical Character of a Closed-Shell Heteroaromatic Quinone" J.Am.Chem.Soc.(1991)
[Publications] M.Miyake: "Anionic Cyclophanes as Hosts for Cationic Aromatic Guests" Tetrahedron Lett.32. 7295-7298 (1991)
[Publications] K.Manabe: "Chromatographic Separation of Aromatic Guest Compounds by a Gel-Immobilized Water-Soluble Cyclophane" Chem.Pharm.Bull.
[Publications] Y.Nakatsuji: "Transport of Calcium and Potassium Ions in Opposite Directions in a Liquid Membrane System" J.Inclusion Phenom.Mol.Recog.Chem.10. 379-386 (1991)
[Publications] M Okahara: "Bis(crown ether)s as Na^+-K^+ ATPase Model in a Liquid Membrane" J.Inclusion Phenom.Mol.Recog.Chem.
[Publications] K.Tsukagoshi: "Specific Complexation with Mono- and Disaccharides That Can be Detected by Circular Dichroism." J.Org.Chem.56. 4089-4091 (1991)
[Publications] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)
[Publications] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)
[Publications] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)
[Publications] S.Shinkai: "Molecular Recognition of Mono- and Di-saccharides by Phenylboronic Acids in Solvent Extranction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)
[Publications] T.Nagasaki: "Kinetic-Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)
[Publications] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)
[Publications] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)
[Publications] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)
[Publications] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)
[Publications] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)
[Publications] K.Iwamoto: "Syntheses of New Isomers from p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)
[Publications] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.,Perkin Trans.2. 793-797 (1991)
[Publications] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced Circular Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)
[Publications] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)
[Publications] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)
[Publications] Takahiko Inazu: "Syntheses and Properties of Highly Symmetrical Cage Compounds;Pyridine Analogs of "Hexa-m-xylylenetetramine"." J.Am.Chem.Soc.,. 113. 1323-1331 (1991)
[Publications] Takahiko Inazu: "Synthesis of Triple- and Quadruple-layered[3.3]-Metacyclophanes." J.Org.Chem.
[Publications] Takahiko Inazu: "Synthesis and X-ray Structure Determination of anti-[3.3]Metacyclophane Quinhydrone Dimethyl Ether;anti-15,18-Dimethoxy[3](2,6)-p-benzoquinono[3]-metacyclophane-2,ll-dione." J.Org.Chem.
[Publications] Takahiko Inazu: "An Approach to the Synthesis of Tetraaza[3.3.3.3]-cyclophanes by Alkylation of N-Substituted Trifluoroacet-amide." Synthesis.
[Publications] Takahiko Inazu: "A Conformational Study of [3.3]Metacyclophane through Variable Temperature ^1H NMR Method and Optical Rotation." J.Org.Chem.
[Publications] M.Fujita: "Spectroscopic Observation of Self-Assembly of a Macrocyclic Tetranuclear Complex Composed of Pt^<2+> and 4,4'-Bipyridine" Chem.Lett.1031-1032 (1991)
[Publications] M.Fujita: "Macrocyclic Polynuclear Complexes [(en)Pd(4,4')]_4 (NO_3)_8 (M=Pd or Pt) as "Inorganic Cyclophane."Their Ability for Molecular Recognition" Tetrahedron Lett.32. 5589-5592 (1991)
[Publications] K.Ogura: "Is CH-π Interaction between Methyl and Phenyl Groups Possible?Streoselective Molecular Recognition of Methyl Sulfoxides by Solid (R)-Phenylglycyl-(R)-phehygly"
[Publications] M.Kitamura: "Precipitation Behavior of 1,1-Di(p-hydroxyphenyl)-cyclohexane Clathrate Crystals from Acetone Solutions Containing d-Limonene" J.Inclu.Phenom.and Mol.Recog.In Chem.10. 305-312 (1991)
[Publications] D.R.Bond: "Complexation with Diol Host Compounds.Part 6.Structure and Dynamics of Enclathration by 1,1,6,6-Tetraphenyl-hexa-2,4-diyne-1.6-diol" J.Solid State Chem.92. 68-79 (1991)
[Publications] F.Toda,: "A New Preparative Method for Optically Active Diaryl-carbinols" Tetrahedron.Assym.2. 873-874 (1991)
[Publications] S.A.Bourne: "Complexation with Hydroxy Host Compounds.Part.4.Structures and Thermal Stabilities of Inclusion Compounds with Dioxane as the Guest" J.Chem.Soc.Perkin Trans.2. 1707-1713 (1991)
[Publications] F.Toda: "Efficient Resolution of Secondary Alcohols,Cyanohydrins,and Glycerol Acetals by Complexation with the Host Derived form Tartaric Acid" Tetrahedron Assym.2. 983-986 (1991)
[Publications] F.Toda: "Optical Resolution of Amino Acid and Hydroxycarboxylic Acid Esters by Complexation with Optically Active Host Compounds:a Crystallographic Result" J.Chem.Soc.Perkin Trans 2. 1971-1975 (1991)
[Publications] S.Sakaki: "Chiral Recognition of Ferrocytochrome c(II) in Electron-transfer Reactions with Cobalt(III) Complexes" J.Chem.Soc.,Dalton Trans.1143-1148 (1991)
[Publications] K.Ohkubo: "Enantioselective Hydrolysis of N-Acyl Amino Acid Esters by Tripeptide-type L-Histidine Derivative in a Bilayer Vesicular System" Chem.Lett.1723-1726 (1991)
[Publications] T.Sagawa: "Stereoselective Dioxygenolysis of a Tryptophan Derivative Catalyzed by a Manganese Porphyrin Bound to Bovine Serum Albumin" Chem.Lett.2083-2086 (1991)
[Publications] K.Ohkubo: "Enantioselective Photoreduction of Tris(acetylacetonato)cobalt(III) by 1,4-Dihydropyridine Derivatives in the Presence of Molecular Aggregates" J.Chem.Soc.,Perkin Trans.2. 1833-1838 (1991)
[Publications] K.Ohkubo: "Catalytic and Stereoselective Activities of Manganese Achiral and Chiral Porphyrins in Dioxygenation of Tryptophan Derivatives" Inorg.Chem.(1992)
[Publications] K.Yamashita: "Micellar Accelerated Reduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" Bull.Chem.Soc.Jpn.64. 410-415 (1991)
[Publications] K.Yamashita: "Micellar Promoted Photoreduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" J.Chem.Soc.,Perkin Trans.2. 367-372 (1991)
[Publications] K.Yamashita: "Micellar Effects on Photoinduced Electron Transfer from 1,4-Dihydronicotinamide Derivatives to Tris(acetylacetonato)cobalto(III)" J.Phys.Chem.95. 5204-5210 (1991)
[Publications] K.Yamashita: "Photoinduced Electron and Hydrogen-Transfer Reaction in Micellar-Promoted Reaction of vic-Styrene Dibromide with 1-Benzyl-1,4-dihydronicotinamide" Chem.Lett.1637-1640 (1991)
[Publications] S.Sakaki: "New Reduction Catalysis of Metalloporphyrins.Catalytic Reduction of Nitrobenzene to Aniline with Tetraphenylporphyrinato-iron(III) Chloride-NaBH_4 System" Chem.Lett.195-198 (1991)
[Publications] Y.Kikuchi: "Molecular Recognition and Stereoselectivity:Geometrical Requirements for the Multiple Hydrogen-Bonding interaction of Diols with a Multidentate Polyhydroxyl Macto" J.Am.Chem.Soc.113. 1349-1354 (1991)
[Publications] Y.Aoyama: "Molecular Recognition of Qunones:Two-Point Hydrogen-Bonding Strategy for the Construction of Face-to-Face Porphyrin-Quinone Architecture" J.Am.Chem.Soc.113. 6233-6240 (1991)
[Publications] T.Motomura: "Transition-State Stabilization via Dynamic Molecular Recognition:A Concerted Acid-Base Bifunctional Catalysis in Ester Hydrolysis" Tetrahedron Lett.32. 4757-4760 (1991)
[Publications] T.Motomura: "Accumulation OF Hydrogen-Bonding and Electostatic Binding Sites:Satbilization of Salts in Hydroxylic Media via Intramolecular Hydrogen Bonding" J.Org.Chem.56. 7224-7228 (1991)
[Publications] 松井佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)
[Publications] Y.Matsui: "Interactions between modified cyclodextrins and the iodide ion in organic media."
[Publications] Y.Matsui: "Specific interactions between aminated cyclodextrins and the sulfate ion in an acidic aqueous solution."
[Publications] J.Nishimura: "Intramolecular [2+2] Photocycloaddition 10.Conformationally Stable-syn-[2,2]Metacyclophanes" J.Am.Chem.Soc.113. 3485-3489 (1991)
[Publications] Y.Okada: "Synthesis and Structural Analysis of Dimethoxy-[2,n]metacyclophanes" Chem.Lett.1345-1348 (1991)
[Publications] S.Inokuma: "Synthesis of Three-Bridged Cyclophanes via Meta- and Ortho-Cyclophane" Tetrahedron Lett.32. 2367-2370 (1991)
[Publications] F.Toda: "Inclusion Compounds Vol.4" oxford University Press, 511 (1991)
[Publications] S.Shinkai: "Calixarenes:A Versatile Class of Macrocyclic Compounds" Kluwer Academic Publishers, 26 (1991)
[Publications] K.Yoshinaga: "Biomedical Applications of Poly(ethylene glycol) Chemistry 2章「PEGーmodified Protein Hybrid Catalyst」" Plenum Publishing Cooperation, (1992)
[Publications] J.Nishimura: "Chemistry of Three-Dimensional Polycyclic Molecules" Verlag Chemie,

1991 Fiscal Year Annual Research Report

分子認識場の設計

Principal Investigator

新海 征治 九州大学, 工学部, 教授 (20038045)

Research Products

[Publications] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)

[Publications] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)

[Publications] T.Sugimoto: "Tercalicen und Quatercalicen" Angew.Chem.103. 454-456 (1991)

[Publications] T.Sugimoto: "Biradical Character of a Closed-Shell Heteroaromatic Quinone" J.Am.Chem.Soc.(1991)

[Publications] M.Miyake: "Anionic Cyclophanes as Hosts for Cationic Aromatic Guests" Tetrahedron Lett.32. 7295-7298 (1991)

[Publications] K.Manabe: "Chromatographic Separation of Aromatic Guest Compounds by a Gel-Immobilized Water-Soluble Cyclophane" Chem.Pharm.Bull.

[Publications] Y.Nakatsuji: "Transport of Calcium and Potassium Ions in Opposite Directions in a Liquid Membrane System" J.Inclusion Phenom.Mol.Recog.Chem.10. 379-386 (1991)

[Publications] M Okahara: "Bis(crown ether)s as Na^+-K^+ ATPase Model in a Liquid Membrane" J.Inclusion Phenom.Mol.Recog.Chem.

[Publications] K.Tsukagoshi: "Specific Complexation with Mono- and Disaccharides That Can be Detected by Circular Dichroism." J.Org.Chem.56. 4089-4091 (1991)

[Publications] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)

[Publications] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)

[Publications] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)

[Publications] S.Shinkai: "Molecular Recognition of Mono- and Di-saccharides by Phenylboronic Acids in Solvent Extranction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)

[Publications] T.Nagasaki: "Kinetic-Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)

[Publications] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)

[Publications] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)

[Publications] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)

[Publications] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)

[Publications] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)

[Publications] K.Iwamoto: "Syntheses of New Isomers from p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)

[Publications] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.,Perkin Trans.2. 793-797 (1991)

[Publications] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced Circular Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)

[Publications] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)

[Publications] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)

[Publications] Takahiko Inazu: "Syntheses and Properties of Highly Symmetrical Cage Compounds;Pyridine Analogs of "Hexa-m-xylylenetetramine"." J.Am.Chem.Soc.,. 113. 1323-1331 (1991)

[Publications] Takahiko Inazu: "Synthesis of Triple- and Quadruple-layered[3.3]-Metacyclophanes." J.Org.Chem.

[Publications] Takahiko Inazu: "Synthesis and X-ray Structure Determination of anti-[3.3]Metacyclophane Quinhydrone Dimethyl Ether;anti-15,18-Dimethoxy[3](2,6)-p-benzoquinono[3]-metacyclophane-2,ll-dione." J.Org.Chem.

[Publications] Takahiko Inazu: "An Approach to the Synthesis of Tetraaza[3.3.3.3]-cyclophanes by Alkylation of N-Substituted Trifluoroacet-amide." Synthesis.

[Publications] Takahiko Inazu: "A Conformational Study of [3.3]Metacyclophane through Variable Temperature ^1H NMR Method and Optical Rotation." J.Org.Chem.

[Publications] M.Fujita: "Spectroscopic Observation of Self-Assembly of a Macrocyclic Tetranuclear Complex Composed of Pt^<2+> and 4,4'-Bipyridine" Chem.Lett.1031-1032 (1991)

[Publications] M.Fujita: "Macrocyclic Polynuclear Complexes [(en)Pd(4,4')]_4 (NO_3)_8 (M=Pd or Pt) as "Inorganic Cyclophane."Their Ability for Molecular Recognition" Tetrahedron Lett.32. 5589-5592 (1991)

[Publications] K.Ogura: "Is CH-π Interaction between Methyl and Phenyl Groups Possible?Streoselective Molecular Recognition of Methyl Sulfoxides by Solid (R)-Phenylglycyl-(R)-phehygly"

[Publications] M.Kitamura: "Precipitation Behavior of 1,1-Di(p-hydroxyphenyl)-cyclohexane Clathrate Crystals from Acetone Solutions Containing d-Limonene" J.Inclu.Phenom.and Mol.Recog.In Chem.10. 305-312 (1991)

[Publications] D.R.Bond: "Complexation with Diol Host Compounds.Part 6.Structure and Dynamics of Enclathration by 1,1,6,6-Tetraphenyl-hexa-2,4-diyne-1.6-diol" J.Solid State Chem.92. 68-79 (1991)

[Publications] F.Toda,: "A New Preparative Method for Optically Active Diaryl-carbinols" Tetrahedron.Assym.2. 873-874 (1991)

[Publications] S.A.Bourne: "Complexation with Hydroxy Host Compounds.Part.4.Structures and Thermal Stabilities of Inclusion Compounds with Dioxane as the Guest" J.Chem.Soc.Perkin Trans.2. 1707-1713 (1991)

[Publications] F.Toda: "Efficient Resolution of Secondary Alcohols,Cyanohydrins,and Glycerol Acetals by Complexation with the Host Derived form Tartaric Acid" Tetrahedron Assym.2. 983-986 (1991)

[Publications] F.Toda: "Optical Resolution of Amino Acid and Hydroxycarboxylic Acid Esters by Complexation with Optically Active Host Compounds:a Crystallographic Result" J.Chem.Soc.Perkin Trans 2. 1971-1975 (1991)

[Publications] S.Sakaki: "Chiral Recognition of Ferrocytochrome c(II) in Electron-transfer Reactions with Cobalt(III) Complexes" J.Chem.Soc.,Dalton Trans.1143-1148 (1991)

[Publications] K.Ohkubo: "Enantioselective Hydrolysis of N-Acyl Amino Acid Esters by Tripeptide-type L-Histidine Derivative in a Bilayer Vesicular System" Chem.Lett.1723-1726 (1991)

[Publications] T.Sagawa: "Stereoselective Dioxygenolysis of a Tryptophan Derivative Catalyzed by a Manganese Porphyrin Bound to Bovine Serum Albumin" Chem.Lett.2083-2086 (1991)

[Publications] K.Ohkubo: "Enantioselective Photoreduction of Tris(acetylacetonato)cobalt(III) by 1,4-Dihydropyridine Derivatives in the Presence of Molecular Aggregates" J.Chem.Soc.,Perkin Trans.2. 1833-1838 (1991)

[Publications] K.Ohkubo: "Catalytic and Stereoselective Activities of Manganese Achiral and Chiral Porphyrins in Dioxygenation of Tryptophan Derivatives" Inorg.Chem.(1992)

[Publications] K.Yamashita: "Micellar Accelerated Reduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" Bull.Chem.Soc.Jpn.64. 410-415 (1991)

[Publications] K.Yamashita: "Micellar Promoted Photoreduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" J.Chem.Soc.,Perkin Trans.2. 367-372 (1991)

[Publications] K.Yamashita: "Micellar Effects on Photoinduced Electron Transfer from 1,4-Dihydronicotinamide Derivatives to Tris(acetylacetonato)cobalto(III)" J.Phys.Chem.95. 5204-5210 (1991)

[Publications] K.Yamashita: "Photoinduced Electron and Hydrogen-Transfer Reaction in Micellar-Promoted Reaction of vic-Styrene Dibromide with 1-Benzyl-1,4-dihydronicotinamide" Chem.Lett.1637-1640 (1991)

[Publications] S.Sakaki: "New Reduction Catalysis of Metalloporphyrins.Catalytic Reduction of Nitrobenzene to Aniline with Tetraphenylporphyrinato-iron(III) Chloride-NaBH_4 System" Chem.Lett.195-198 (1991)

[Publications] Y.Kikuchi: "Molecular Recognition and Stereoselectivity:Geometrical Requirements for the Multiple Hydrogen-Bonding interaction of Diols with a Multidentate Polyhydroxyl Macto" J.Am.Chem.Soc.113. 1349-1354 (1991)

[Publications] Y.Aoyama: "Molecular Recognition of Qunones:Two-Point Hydrogen-Bonding Strategy for the Construction of Face-to-Face Porphyrin-Quinone Architecture" J.Am.Chem.Soc.113. 6233-6240 (1991)

[Publications] T.Motomura: "Transition-State Stabilization via Dynamic Molecular Recognition:A Concerted Acid-Base Bifunctional Catalysis in Ester Hydrolysis" Tetrahedron Lett.32. 4757-4760 (1991)

[Publications] T.Motomura: "Accumulation OF Hydrogen-Bonding and Electostatic Binding Sites:Satbilization of Salts in Hydroxylic Media via Intramolecular Hydrogen Bonding" J.Org.Chem.56. 7224-7228 (1991)

[Publications] 松井 佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)

[Publications] Y.Matsui: "Interactions between modified cyclodextrins and the iodide ion in organic media."

[Publications] Y.Matsui: "Specific interactions between aminated cyclodextrins and the sulfate ion in an acidic aqueous solution."

[Publications] J.Nishimura: "Intramolecular [2+2] Photocycloaddition 10.Conformationally Stable-syn-[2,2]Metacyclophanes" J.Am.Chem.Soc.113. 3485-3489 (1991)

[Publications] Y.Okada: "Synthesis and Structural Analysis of Dimethoxy-[2,n]metacyclophanes" Chem.Lett.1345-1348 (1991)

[Publications] S.Inokuma: "Synthesis of Three-Bridged Cyclophanes via Meta- and Ortho-Cyclophane" Tetrahedron Lett.32. 2367-2370 (1991)

[Publications] F.Toda: "Inclusion Compounds Vol.4" oxford University Press, 511 (1991)

[Publications] S.Shinkai: "Calixarenes:A Versatile Class of Macrocyclic Compounds" Kluwer Academic Publishers, 26 (1991)

[Publications] K.Yoshinaga: "Biomedical Applications of Poly(ethylene glycol) Chemistry 2章「PEGーmodified Protein Hybrid Catalyst」" Plenum Publishing Cooperation, (1992)

[Publications] J.Nishimura: "Chemistry of Three-Dimensional Polycyclic Molecules" Verlag Chemie,

新海征治九州大学, 工学部, 教授 (20038045)

[Publications] 松井佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)