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1992 Fiscal Year Final Research Report Summary

Basic Research for "Molecular Hysteresis"

Research Project

Project/Area Number 03453048
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 無機・錯塩・放射化学
Research InstitutionNagoya University

Principal Investigator

SANO Mitsuru  Nagoya Univ. College of General Edu., 教養部, 助教授 (90144097)

Co-Investigator(Kenkyū-buntansha) TANAKA Masashi  Nagoya Univ. Prof. College of General Educ., 教養部, 教授 (70022639)
MATSUBARA Teruo  Nagoya Univ. Prof. College of General Educ., 教養部, 教授 (50023627)
Project Period (FY) 1991 – 1992
KeywordsMolecular Hysteresis / Molecular Memory / Ruthenium Complexes
Research Abstract

Thermodynamic and kinetic studies have been done on the "molecular hysteresis". We obtained all the parameters as the energy relations, the isomerization energies and rates, and the interconversion rate between the species. The energy difference is 2.1 KJ/mole and the interconversion rate is 0.12 sec^<-1> between the intermediate species. This rate is rather slow, which results in showing the "molecular hysteresis". Then, we completely made clear the mechanism of the "molecular hysteresis".
Further electrochemical study now are continued on the rutheniumpentammine-sulfoxide, where we investigate stabilities of the Ru(III)-SO and Ru(III)-OS, which can correlate with a steric hindrance of a substituted group of the sulfoxides. Then it is possible to control molecular motions by an applied voltage.
We also considered and discussed to generalize the concept of the "molecular hystereis".

  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] M.Sano,H.Taube: "¨Molecular Hysteresis¨" J.Am.Chem.Soc. 113. 2327-2328 (1991)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Sano,S.Komorita,H.Yamatera: "XANES Spectra of Copper(II) Compbis:Correlation of the Iptnsity of the 1s-3d Transitron and the Shope of the Complex" Inog.Chem. 31. 459-463 (4992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Sano,H.Taube: "¨Molecular Hysteresis¨in an Electrochamical System Reviseted" (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.SANO and H.TAUBE: "Molecular Hysteresis" J.Am.Chem.Soc.113. 2327-2328 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.SANO, S.KOMORITA, and H.YAMATERA: "XANES Spectra of Copper(II) Complexes: Correlation of the Intensity of the 1s-3d Transition and the Shape of the Complex." Inorg. Chem.31. 459-463 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.SANO and H.TAUBE: ""Molecular Hysteresis" in an Electrochemical System Revisited." J.Am.Chem.Soc.

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1994-03-24  

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