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1993 Fiscal Year Final Research Report Summary

Research of the First Order Diffusionless Phase Transformations on Atomic and Microscopic Scales

Research Project

Project/Area Number 04044032
Research Category

Grant-in-Aid for international Scientific Research

Allocation TypeSingle-year Grants
SectionJoint Research
Research InstitutionUniversity of Tsukuba

Principal Investigator

OTSUKA Kazuhiro  Institute of Materials Science, Univ.of Tsukuba, Professor, 物質工学系, 教授 (50029881)

Co-Investigator(Kenkyū-buntansha) WILKINS S.W.  Div.of Materials Sci.& Technology, CSIRO, 材料科学部, 主席研究官
FINLAYSON T.R.  Dept.of Physics, Monash University, 物理学科, 準教授
DUNNE D.P.  Dept.of Materials Eng., Univ.of Wollongong, 材料科学部, 教授
MORTON A.J.  Div.of Materials Sci.& Technology, CSIRO, 材料科学部, 上級主席研究官
HARA Toru  Dept.of Materials Science, Teikyo University, 理工学部, 助手 (70238161)
OHBA Takuya  Dept.of Materials Science, Teikyo University, 理工学部, 助教授 (00211110)
ODA Katsuro  Institute of Materials Science, Univ.of Tsukuba, 物質工学系, 講師 (80177229)
OHSHIMA Kenichi  Institute of Applied Physics, Univ.of Tsukuba, 物理工学系, 助教授 (70109271)
SUZUKI Tetsuro  Institute of Applied Physics, Univ.of Tsukuba, 物理工学系, 教授 (70045988)
Project Period (FY) 1992 – 1993
Keywords1st Order Diffusionless Phase Transformations / Martensitic Transformations / Crystallography of Phase Transformations / Nucleation / Rubber-like Behavior / Aging Effect / Burgers vector / Pretransformation Phenomena
Research Abstract

A workshop on the 1st Order Diffusionless Phase Transformations was held near Melbourne from March 17 to 19, 1994, to summarize and assess the results of our joint research. A brief report on each theme is given below.
1)From the x-ray diffuse scattering measurements of In-Tl and Na crystals as a function of temperature, it was found that there is no pretransformation phenomenon prior to the martensitic transformation. When specimens are held at a temperature above Ms, the incubation periods were found for the first time. The observations will be very important for the further development of transformation kinetics.
2) By carrying out 2-dimensional computer simulations of martensite nucleation, easy visualization of the results was possible, and important results were obtained such as the introduction of twins in the nucleation process, and the role of vacancies in the nucleation process etc.
3)For the beta 2*zeta 2'(trigonal) transformation in the Au-49.5at%Cd alloy, for which the crystallography of the transformation remains unsolved for 40 years, the phenomenological crystallographic theory was successfully applied, and the big discrepancies between different investigators on the presence or absence of the lattice invariant shear was resolved.
4)The mechanism of the rubber-like behavior remains unsolved over 50 years, but two mechanisms were proposed by Lieberman and Tadaki. By carrying out accurate measurements of several diffraction intensities with aging time, the integrated intensities were found essentially not to change with time. The results deny the change of average structure, thus denying the mechanisms of Lieberman and Tadaki, and suggests the local change due to vacancy migrations etc.
The above results show that many of the fundamental problems on the 1st order diffusionless phase transformations have been solved.

  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] T.Ohba,Y.Emura and K.Otsuka: "Structure Determination of the ζ_2' Martensite and the Mechanism of β_2'→ζ_2' Transformation in a Au-49.5at%Cd Alloy" Materials Trans.JIM. 33. 29-37 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Murakami,K.Otsuka,S.Hanada and S.Watanabe: "Crystallography of Stress-induced B2→7R Martensitic Transformation in a Ni-37.0at%Al Alloy" Materials Trans.JIM. 33. 282-288 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hara,T.Ohba,S.Miyazaki and K.Otsuka: "Electron Microscopy Study of Type II Twins in γ_1' Cu-Al-Ni Martensite" Materials Trans.JIM. 33. 1105-1113 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Emura,T.Ohba and K.Otsuka: "Crystal Structure of ζ_2' Martensite in Au-49.5at%Cd Alloy" MRS Symp.Proc.246. 73-78 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Otsuka,T.Ohba,M.Tokonami and C.M.Wayman: "New Description of Long Period Stacking Order Structures of Martensites in β-phase Alloys" Scripta Met.29. 1359-1364 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Otsuka and T.Ohba: "Recent Works on Crystal Structure Determination of Martensites" Proc.ICOMAT-92. 221-232 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Morii,S.Miyazaki and K.Otsuka: "Shape Memory Effect Associated with β_2→ζ_2' Martensitic Transformation in a Au-49.5at%Cd Alloy" Proc.ICOMAT-92. 1125-1130 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hara,T.Ohba,K.Otsuka,Y.Bando and S.Nenno: "High Resolution Electron Microscopy Observation of Twin Interfacesin γ_1' Cu-Al-Ni and γ_2' Au-Cd Martensite" Proc.ICOMAT-92. 257-262 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Murakami,K.Otsuka,S.Hanada and S.Watanabe: "Mechanism of Self-accommodation of 7R Martensite in a Ni-37.0at%Al Alloy" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Morito,T.Inoue,K.Oda and K.Otsuka: "Electron Microscopy Observations of 15R and 12 Layers Martensites in Ni_<50>Al_xMn_<50-x> Alloys" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Inoue,S.Morito,Y.Murakami,K.Oda and K.Otsuka: "New Martensite Structures and Composition dependence of Martensitic Transformations in Ni_<50>Al_xMn_<50-x> Alloys" Materials Letters. (in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Suzuki and K.Takahashi: "Nucleation Process of Martensite in Small Particles" Materials Trans.JIM. 33. 184-190 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Inohara,M.Tanaka,M.Hashimoto and T.Suzuki: "Measurement of Elastic Moduli by Rectangular Parallelepiped Resonance Method" Jpn.J.Appl.Phys.Supl.31-1. 31. 41-43 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Inohara and T.Suzuki: "Measurement of Elastic Moduli by Rectangular Rarallelepiped Resonance Method II" Jpn.J.Appl.Phys.32. 2238-2242 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Suzuki and K.Osuka: "Role of Higher-Order Elastic Moduli in Large Elastic Finite Deformation" Jpn.J.Appl.Phys.32. 2252-2255 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Abe,K.Ohshima,S.Hoshino and K.Kakurai: "Neutron-Scattering Study of Metallic Sodium" Phys.Rev.B. 49. 3739-3745 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Toyoshima,K.Harada,H.Abe,K.Ohshima,T.Suzuki,M.Wuttig and T.R.Finlayson: "X-ray Diffraction Study of Martensitic Phase Transition in In-23at%Tl Alloy" J.Phys.Soc.Jpn.63(in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hara,T.Ohba,S.Nenno and K.Otsuka: "Structure Study of the R-Phase in a Ti-Ni-Fe Alloy by Electron Microscopy" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ohba,T.Hara,S.Sasaki,M.Takata and Y.Komura: "Separation of Two Subsystems Nd_<13>Fe_<46>B_<41> Composite Crystal Utilizing Synchrotron Radiation" Jpn.J.Appl.Phys.32. L1553-L1555 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hara,T.Ohba,Y.Bando and K.Otsuka: "On the Structure of Twin Interfaces in γ_1' Cu-Al-Ni Martensite" Acta Crys.Suppl.C-386. A46. (1990)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.F.Smith and T.R.Finlayson: "Thermal Expansion Studies of Pre-Transformation Behaviour" Thermochimica Acta. 218. 135-144 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Liu,T.R.Finlayson and T.F.Smith: "Thermal Expansion of Martensitic In-Tl:Stress-Induced Microstructure and Pre-Martensite State" Phys.Rev.B. 48. 3009-3015 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Liu,T.R.Finlayson and T.F.Smith: "Low-Temperature Thermal Expansion Anomalies in Indium and its Solid-Solution Alloys with Thallium" Australian Journal of Physics. 46. 695-706 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.F.Smith and T.R.Finlayson: "Superconductivity and the FCT-FCC Transformation in Indium-Thallium Alloys as a Function of Pressure" Phys.Rev.B. (in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ohba, Y.Emura and K.Otsuka: "Structure Determination of the zeta_2' Martensite and the Mechanism of beta_2*zeta_2' Transformation in a Au-49.5at%Cd Alloy" Materials Trans.JIM. 33. 29-37 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Murakami, K.Otsuka, S.Hanada and S.Watanabe: "Crystallography of Stress-induced B2*7R Martensitic Transformation in a Ni-37.0at%Al Alloy" Materials Trans.JIM. 33. 282-288 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hara, T.Ohba, S.Miyazaki and K.Otsuka: "Electron Microscopy Study of Type II Twins in gamma_1' Cu-Al-Ni Martensites" Materials Trans.JIM. 33. 1105-1113 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Emura, T.Ohba and K.Otsuka: "Crystal Strucutre of zeta_2' Martensite in Au-49.5at%Cd Alloy" MRS Symp.Proc.246. 73-78 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Otsuka, T.Ohba, M.Tokonami and C.M.Wayman: "New Description of Long Period Stacking Order Structures of Martensites in beta -phase Alloys" Scripta Met.29. 1359-1364 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Otsuka and T.Ohba: "Recent Works on Crystal Structure Determination of Martensites" Proc.ICOMAT-92. 221-232 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Morii, S.Miyazaki and K.Otsuka: "Shape Memory Effect Associated with beta_2*zeta_2' Martensitic Transformation in a Au-49.5at%Cd Alloy" Proc.ICOMAT-92. 1125-1130 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hara, T.Ohba, K.Otsuka, Y.Bando and S.Nenno: "High Resolution Electron Microscopy Observation of Twin Interfaces in gamma_1' Cu-Al-Ni and gamma_2' Au-Cd Martensite" Proc.ICOMAT-92. 257-262 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Murakami, K.Otsuka, S.Hanada and S.Watanabe: "Mechanism of Self-accommodation of 7R Martensite in a Ni-37.0at%Al Alloy" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Morito, T.Inoue, K.Oda and K.Otsuka: "Electron Microscopy Observations of 15R and 12 Layers Martensites in Ni_<50>Al_XMn_<50-X> Alloys" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Inoue, S.Morito, Y.Murakami, K.Oda and K.Otsuka: "New Martensite Structures and Composition Dependence of Martensitic Transformations in Ni_<50>Al_XMn_<50-X> Alloys" Materials Letters. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Suzuki and K.Takahashi: "Nucleation Process of Martensite in Small Particles" Materials Trans.JIM. 33. 184-190 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Inohara, M.Tanaka, M.Hashimoto and T.Suzuki: "Measurement of Elastic Module by Rectangular Parallelepiped Resonance Method" Jpn.J.Appl.Phys. Suppl.31-1. 31. 41-43 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Inohara and T.Suzuki: "Measurement of Elastic Module by Rectangular Parallelepiped Resonance Method II" Jpn.J.Appl.Phys.32. 2238-2242 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Suzuki and K.Osuka: "Role of High-Order Elastic Module in Elastic Finite Deformation" Jpn.J.Appl.Phys.32. 2252-2255 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Abe, K.Ohshima, T.Suzuki, S.Hoshino and K.Kakurai: "Neutron-Scattering Study of Metallic Sodium" Phys.Rev.B. 49. 3739-3745 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Toyoshima, K.Harada, H.Abe, K.Ohshima, T.Suzuki, M.Wuttig and T.R.Finlayson: "X-ray Diffraction Study of Martensitic Phase Transition in In-23at%Tl Alloy" J.Phys.Soc.Jpn.63(in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hara, T.Ohba, S.Nenno and K.Otsuka: "Structure Study of the R-Phase in a Ti-Ni-Fe Alloy by Electron Microscopy" Proc.IUMRS Int.Conf.on Advanced Materials. 9(in press). (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ohba, T.Hara, S.Sasaki, M.Takata and Y.Komura: "Separation of Two Subsystems in Nd_<13>Fe_<46>B_<41> Composite Crystal Utilizing Synchrotron Radiation" Jpn.J.Appl.Phys.32. L1553-L1555 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hara, T.Ohba, Y.Bando and K.Otsuka: "On the Structure of Twin Interfaces in gamma_1' Cu-Al-Ni Martensite" Acta Crys. Suppl.C-386. A46. (1990)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.F.Smith and T.R.Finlayson: "Thermal Expansion Studies of Pre-Transformation Behavior" Thermochimica. 218. 135-144 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Liu, T.R.Finlayson and T.F.Smith: "Thermal.Expansion of Martensitic In-Tl : Stress-Induced Microstructure and Pre-Martensite State" Phys.Rev. B. 48. 3009-3015 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Liu, T.R.Finlayson and T.F.Smith: "Low-Temperature Thermal Expansion Anomalies in Indium and its Solid-Solution Alloys with Thallium" Australian Journal of Physics. 46. 695-706 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.F.Smith and T.R.Finlayson: "Superconductivity and the FCT-FCC Transformation in Indium-Thallium" Phys.Rev.B. (in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1995-02-07  

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