1993 Fiscal Year Annual Research Report

溶液の非平衡過程の分子論的アプローチに関する総合解析

Research Project

Project/Area Number	04215104
Research Institution	Ritsumeikan University
Principal Investigator	大瀧仁志立命館大学, 理工学部, 教授 (80022549)
Co-Investigator(Kenkyū-buntansha)	山寺秀雄大同工業大学, 化学教室, 教授 (70022499) 斉藤一夫国際基督教大学, 理学研究科, 教授 (70004231) 舟橋重信名古屋大学, 理学部, 教授 (30022700) 中原勝京都大学, 理学部, 助教授 (20025480) 野村浩康名古屋大学, 工学部, 教授 (50023081)
Keywords	溶液の非平衡過程 / ミクロ集合滞のゆらぎ / 拡散過程 / 反応活性種の構造
Research Abstract	平成2年度から4年度の3年間にわたる本重点領域研究「溶液の非平衡」の成果取りまとめを行うと同時に本研究で生じた新たな問題点を整理した。総括班会議を中心に各班長が班員とも密接に連絡をとり研究成果を取りまとめた。研究成果報告書には重点領域研究で行われたいくつかのワークショップで議論された問題に付いても整理し報告書にまとめた。成果報告書は、「溶液の非平衡」に関する研究を将来へつなげるため関連分野の研究者に配付した。また、本重点領域研究研究参画者は学会誌等に成果を公表するとともに国内だけでなく国際学会にも参加し研究成果を広く公表した。本重点領域に関連した分野の研究交流を深めるため、国内外から多数の研究者を招き平成6年12月に山田科学振興財団の援助による山田コンファレンス「溶液の構造・ゆらぎ・緩和」(Structure,Fluctuation,Relaxation in Solutions)の開催を総括班員が中心に企画した。溶液化学の分野の底辺の活性化を高めるため大学院生を対象とする溶液化学の最近の進歩を踏まえた教科書を班長が中心となり作成することとし数回の拡大総括班会議を開催した。さらに、今回の重点領域で浮き彫りにされた中距離程度の相互作用を持つ協同運動の解明を中心に、1.溶媒和と局所構造の動的分子論の構築、2.局所フォノンモードの伝搬と散逸、3.局所構造の伝搬と組織化、4.大きな分子と溶媒モードの相関ダイナミクスを主題とし「局所分子場における溶液のダイナミクス」を計画し重点領域研究を申請した。

Research Products

(38 results)

All Other

All Publications (38 results)

[Publications] H.Ohtaki: "Dissolution and Nucleation Phenomena of Salts in Water.Nolexular Dynamic Approaches and Supporting Solution X-Ray Diffraction Measurements" Pure&Appl.Chem.65. 203-211 (1993)
[Publications] S.Patnaik: "A Structural on AgI-Ag_2-O-C_rO_3 Glass" J.Phys.Soc.Jpn.62. 536-543 (1993)
[Publications] H.Ohtaki: "Structure and Dynamics of Hydrated Ions" Chem.Rev.93. 1157-1204 (1993)
[Publications] H.Ohtaki: "Molecular Dynamics Simu Lations for Dissolution and Nucleation Processes of Alkali Halide Crystals in Water" Computer Aided Innovation of New Materials II. 265-268 (1993)
[Publications] K.Waizumi: "Density Functional Calculations on the Geometries and Dissociation Energies of[M(H_2O)_6]^<2+> and [MCl_2(H_2O)];M^<2+>=Cr^<2+>,Mn^<2+>,Fe^<2+>,Co^<2+>,Ni^<2+>,Cu^<2+>,Zn^<2+>" Computer Aided Innovation of New Materials II. 861-864 (1993)
[Publications] H.Ohtaki: "A Rapid Direct Analysis of the Structure of Reaction Intermediates by the EXAFS Method Combined with a Stopped-Flow Technique" Pure&Appl.Chem.65. 2589-2592 (1993)
[Publications] S.Patnaik: "An X-Ray RDF Study on the Glass 50AgI-25Ag_2O-25MoO_3" Bull.Chem.Soc.Jpn.67. 326-331 (1994)
[Publications] Y.Inada: "Absorption Fine Structure Apparatus in the Dispersive Mode for Determination of the Structure of Short-Lived Intermediates" Rev.Sci.Insrum.65. 18-24 (1993)
[Publications] H.Ohtaki: "Direct Structural Determination of the Short-Lived Intermediate Formed in Dynamic Processes of the Copper(II) Incorporation into Mercury(II)Porphyrin by the Newly Developed Stopped Flow…" J.Chem.Soc.Chem.Commum. (印刷中). (1994)
[Publications] H.Hirakawa: "Sedimentational Measurement of Alkali Chlorides in Water and Meghanol Containing 18-Crown-6" Denki Kagaku. 61. 936-937 (1993)
[Publications] S.Koda: "Characterizetion of Polyvinylchloride and Polycarbonate by Means of Sound Velocity and Longitudenal Modulus Measurements" Jpn.J.Appl.Phys. 35. 119-122 (1993)
[Publications] S.Koda: "Ultrasonic Degradation of Water-Soluble Polymer" Polymer. 35. 30-34 (1994)
[Publications] S.Koda: "Raman Spectroscopic Studies on the Interaction between Counterions and Polyphosphate Ion" Polymer J.(印刷中). (1994)
[Publications] K.Yasuda: "Dynamics of V_2O_5-Sol by Measurement of Ultrasonically Induced Birefringence" Jpn.J.Appl.Phys. (印刷中). (1994)
[Publications] M.Nakahara: "Effect of Dielectric Friction on the Perpendicular Reorientation of the Nittate Ion in Water and Organic Solvents" J.Chem.Phys.99. 5418-5425 (1993)
[Publications] C.Wakai: "Pressure Dependences of Rotational,Translational,and Viscous Friction Coefficients in Water-d2,Acetonitrile-d3,Acetonitrile,Chloroform,and Benzen." J.Chem.Phys.(印刷中). (1994)
[Publications] 中原勝: "電解質溶液の現状と展望" 電気化学および工業物理化学. 61. 30-34 (1993)
[Publications] 中原勝: "高圧力と有機反応" 高圧の科学と技術. 2. 93-96 (1993)
[Publications] 中原勝: "非水溶液化学への高分解能NMR分光法によるアプローチ" 電気化学および工業物理化学. 62. 108-113 (1994)
[Publications] 中原勝: "溶液構造の解析にNMRはどのように役だっているか" 化学. 49(印刷中). (1994)
[Publications] 中原勝: "溶液の非平衡過程の分子論的アプローチ・拡散過程のダイナミックス" 学術月報. 47(印刷中). (1993)
[Publications] S.Funahashi: "High-Pressure Stopped-Flow Nuclear Magnetic Resonance Apparatus for the Study of Fast Reactions in Solution" Rev.Sci.Instrum.64. 130-134 (1993)
[Publications] S.Aizawa: "Synthesis,Structural Characterization,and Metalation of N-o-Tolyl-5,10,15,20-tetra-phenylporphine:Deformation Effect Due to aBulky N-substituent Group" Inotg.Chem.32. 1119-1123 (1993)
[Publications] Y.Inada: "Structure of Copper(II) Ehlenediamine Comlexes in Aqueous and Neat Ethlenediamine Solutions and Solvent-Exchange Kinetics of the Copper(II) Ion in Ethlenediamine as Studies by……" Inorg.Chem.32. 3010-3014 (1993)
[Publications] S.Aizawa: "Dissociative Path Promoted by Ion-Pair Formation for Acetonitrile Exchange Reaction oh the Palladium(II) Complex with Dictylenetriamine" Chem.Lett.1607-1610 (1993)
[Publications] S.Aizawa: "Variable-Temperature and-Pressure Multinuclear Magnetic Rasonance Studies on Solvent Exchange of Cobalt(II),Iron(II),and Manganese(II)Ions in Ethylenediamine" Inorg.Chem.(印刷中). (1993)
[Publications] Y.Inada: "Solvation Structures of Manganese(II),Iron(II),Cobalt(II),Nickel(II),Copper(II),Zinc(II),Cadmium(II),and INdium(III)Ions in 1,1,3,3-Tetramethylurea as Suudied by……" Inorg.Chem.(印刷中). (1993)
[Publications] S.Aizawa: "Variable-temparature and Variable-Pressure Sodium-23 NMR Study on Dissociation Reacion of Sodium(I)Cryptates in Ethylenediamine" Bull.Chem.Soc.Ipn.(印刷中). (1993)
[Publications] N.Kagayama: "Mechanistic Study on the Reaction of L-Ascorbic Acid with hexacyanometallate(III)of Iron(III),Ruthenium(III)and Osmium(III)Ions in Aqueous Acidic Solution at Elebated Pressures" Inorg.Chem.(印刷中). (1993)
[Publications] M.Inamo: "Axial Substitution Reaction of Substituted Pyridine on Chloro(5,10,15,20-tetraphenylporphinato)chromium(III)in Toluene with Special Reference to the Substituent Effect" Inorg.Chem.(印刷中). (1993)
[Publications] T.Natsume: "Hydrolysis,Plymerization,and Structure of Dimethyltin(IV)in Aqueous Solution.Molecular Structure of Polymer of{(CH_3)_2Sn}_2(OH)_3ClO_4" J.Chem.Soc.,Dalton Trans.(印刷中). (1993)
[Publications] S.Kagawa: "Kinetic Study on Comlexation of Boric Acid with 4-Isopropyltropolone in Nonaqueous Solvents" Inorg.Chem.Acta.(印刷中). (1993)
[Publications] H.K.Tanaka: "Enviromental Effect on Photoquenching Reaction Hexamolybdenum(II)Clusters Capped by Chloride with Hexachliroiridate(IV)in Solution." Inorg.Chem.Acta.210. 63-70 (1993)
[Publications] 野村浩康: "液体および溶液の音波物性" 名古屋大学出版会, 295 (1994)
[Publications] 中原勝: "第4版実験化学講座11“反応と速度"" 丸善, 20 (1993)
[Publications] 中原勝: "改訂第4版化便覧基礎編" 丸善, 17 (1993)
[Publications] 中原勝: "溶液の分子論的描像" 学会出版センター(印刷中), (1994)
[Publications] S.Funahashi: "High-Pressure Multinuclear Magnetic Resonance Studies of Solvent Exchange of First Transition Metal(II)Ions in Acctic Acid,…….in“HiPressure Liquid and Solution"" Elsevier(印刷中), (1994)

1993 Fiscal Year Annual Research Report

溶液の非平衡過程の分子論的アプローチに関する総合解析

Principal Investigator

大瀧 仁志 立命館大学, 理工学部, 教授 (80022549)

Research Products

[Publications] H.Ohtaki: "Dissolution and Nucleation Phenomena of Salts in Water.Nolexular Dynamic Approaches and Supporting Solution X-Ray Diffraction Measurements" Pure&Appl.Chem.65. 203-211 (1993)

[Publications] S.Patnaik: "A Structural on AgI-Ag_2-O-C_rO_3 Glass" J.Phys.Soc.Jpn.62. 536-543 (1993)

[Publications] H.Ohtaki: "Structure and Dynamics of Hydrated Ions" Chem.Rev.93. 1157-1204 (1993)

[Publications] H.Ohtaki: "Molecular Dynamics Simu Lations for Dissolution and Nucleation Processes of Alkali Halide Crystals in Water" Computer Aided Innovation of New Materials II. 265-268 (1993)

[Publications] K.Waizumi: "Density Functional Calculations on the Geometries and Dissociation Energies of[M(H_2O)_6]^<2+> and [MCl_2(H_2O)];M^<2+>=Cr^<2+>,Mn^<2+>,Fe^<2+>,Co^<2+>,Ni^<2+>,Cu^<2+>,Zn^<2+>" Computer Aided Innovation of New Materials II. 861-864 (1993)

[Publications] H.Ohtaki: "A Rapid Direct Analysis of the Structure of Reaction Intermediates by the EXAFS Method Combined with a Stopped-Flow Technique" Pure&Appl.Chem.65. 2589-2592 (1993)

[Publications] S.Patnaik: "An X-Ray RDF Study on the Glass 50AgI-25Ag_2O-25MoO_3" Bull.Chem.Soc.Jpn.67. 326-331 (1994)

[Publications] Y.Inada: "Absorption Fine Structure Apparatus in the Dispersive Mode for Determination of the Structure of Short-Lived Intermediates" Rev.Sci.Insrum.65. 18-24 (1993)

[Publications] H.Ohtaki: "Direct Structural Determination of the Short-Lived Intermediate Formed in Dynamic Processes of the Copper(II) Incorporation into Mercury(II)Porphyrin by the Newly Developed Stopped Flow…" J.Chem.Soc.Chem.Commum. (印刷中). (1994)

[Publications] H.Hirakawa: "Sedimentational Measurement of Alkali Chlorides in Water and Meghanol Containing 18-Crown-6" Denki Kagaku. 61. 936-937 (1993)

[Publications] S.Koda: "Characterizetion of Polyvinylchloride and Polycarbonate by Means of Sound Velocity and Longitudenal Modulus Measurements" Jpn.J.Appl.Phys. 35. 119-122 (1993)

[Publications] S.Koda: "Ultrasonic Degradation of Water-Soluble Polymer" Polymer. 35. 30-34 (1994)

[Publications] S.Koda: "Raman Spectroscopic Studies on the Interaction between Counterions and Polyphosphate Ion" Polymer J.(印刷中). (1994)

[Publications] K.Yasuda: "Dynamics of V_2O_5-Sol by Measurement of Ultrasonically Induced Birefringence" Jpn.J.Appl.Phys. (印刷中). (1994)

[Publications] M.Nakahara: "Effect of Dielectric Friction on the Perpendicular Reorientation of the Nittate Ion in Water and Organic Solvents" J.Chem.Phys.99. 5418-5425 (1993)

[Publications] C.Wakai: "Pressure Dependences of Rotational,Translational,and Viscous Friction Coefficients in Water-d2,Acetonitrile-d3,Acetonitrile,Chloroform,and Benzen." J.Chem.Phys.(印刷中). (1994)

[Publications] 中原 勝: "電解質溶液の現状と展望" 電気化学および工業物理化学. 61. 30-34 (1993)

[Publications] 中原 勝: "高圧力と有機反応" 高圧の科学と技術. 2. 93-96 (1993)

[Publications] 中原 勝: "非水溶液化学への高分解能NMR分光法によるアプローチ" 電気化学および工業物理化学. 62. 108-113 (1994)

[Publications] 中原 勝: "溶液構造の解析にNMRはどのように役だっているか" 化学. 49(印刷中). (1994)

[Publications] 中原 勝: "溶液の非平衡過程の分子論的アプローチ・拡散過程のダイナミックス" 学術月報. 47(印刷中). (1993)

[Publications] S.Funahashi: "High-Pressure Stopped-Flow Nuclear Magnetic Resonance Apparatus for the Study of Fast Reactions in Solution" Rev.Sci.Instrum.64. 130-134 (1993)

[Publications] S.Aizawa: "Synthesis,Structural Characterization,and Metalation of N-o-Tolyl-5,10,15,20-tetra-phenylporphine:Deformation Effect Due to aBulky N-substituent Group" Inotg.Chem.32. 1119-1123 (1993)

[Publications] Y.Inada: "Structure of Copper(II) Ehlenediamine Comlexes in Aqueous and Neat Ethlenediamine Solutions and Solvent-Exchange Kinetics of the Copper(II) Ion in Ethlenediamine as Studies by……" Inorg.Chem.32. 3010-3014 (1993)

[Publications] S.Aizawa: "Dissociative Path Promoted by Ion-Pair Formation for Acetonitrile Exchange Reaction oh the Palladium(II) Complex with Dictylenetriamine" Chem.Lett.1607-1610 (1993)

[Publications] S.Aizawa: "Variable-Temperature and-Pressure Multinuclear Magnetic Rasonance Studies on Solvent Exchange of Cobalt(II),Iron(II),and Manganese(II)Ions in Ethylenediamine" Inorg.Chem.(印刷中). (1993)

[Publications] Y.Inada: "Solvation Structures of Manganese(II),Iron(II),Cobalt(II),Nickel(II),Copper(II),Zinc(II),Cadmium(II),and INdium(III)Ions in 1,1,3,3-Tetramethylurea as Suudied by……" Inorg.Chem.(印刷中). (1993)

[Publications] S.Aizawa: "Variable-temparature and Variable-Pressure Sodium-23 NMR Study on Dissociation Reacion of Sodium(I)Cryptates in Ethylenediamine" Bull.Chem.Soc.Ipn.(印刷中). (1993)

[Publications] N.Kagayama: "Mechanistic Study on the Reaction of L-Ascorbic Acid with hexacyanometallate(III)of Iron(III),Ruthenium(III)and Osmium(III)Ions in Aqueous Acidic Solution at Elebated Pressures" Inorg.Chem.(印刷中). (1993)

[Publications] M.Inamo: "Axial Substitution Reaction of Substituted Pyridine on Chloro(5,10,15,20-tetraphenylporphinato)chromium(III)in Toluene with Special Reference to the Substituent Effect" Inorg.Chem.(印刷中). (1993)

[Publications] T.Natsume: "Hydrolysis,Plymerization,and Structure of Dimethyltin(IV)in Aqueous Solution.Molecular Structure of Polymer of{(CH_3)_2Sn}_2(OH)_3ClO_4" J.Chem.Soc.,Dalton Trans.(印刷中). (1993)

[Publications] S.Kagawa: "Kinetic Study on Comlexation of Boric Acid with 4-Isopropyltropolone in Nonaqueous Solvents" Inorg.Chem.Acta.(印刷中). (1993)

[Publications] H.K.Tanaka: "Enviromental Effect on Photoquenching Reaction Hexamolybdenum(II)Clusters Capped by Chloride with Hexachliroiridate(IV)in Solution." Inorg.Chem.Acta.210. 63-70 (1993)

[Publications] 野村 浩康: "液体および溶液の音波物性" 名古屋大学出版会, 295 (1994)

[Publications] 中原 勝: "第4版実験化学講座11“反応と速度"" 丸善, 20 (1993)

[Publications] 中原 勝: "改訂第4版化便覧基礎編" 丸善, 17 (1993)

[Publications] 中原 勝: "溶液の分子論的描像" 学会出版センター(印刷中), (1994)

[Publications] S.Funahashi: "High-Pressure Multinuclear Magnetic Resonance Studies of Solvent Exchange of First Transition Metal(II)Ions in Acctic Acid,…….in“HiPressure Liquid and Solution"" Elsevier(印刷中), (1994)

大瀧仁志立命館大学, 理工学部, 教授 (80022549)

[Publications] 中原勝: "電解質溶液の現状と展望" 電気化学および工業物理化学. 61. 30-34 (1993)

[Publications] 中原勝: "高圧力と有機反応" 高圧の科学と技術. 2. 93-96 (1993)

[Publications] 中原勝: "非水溶液化学への高分解能NMR分光法によるアプローチ" 電気化学および工業物理化学. 62. 108-113 (1994)

[Publications] 中原勝: "溶液構造の解析にNMRはどのように役だっているか" 化学. 49(印刷中). (1994)

[Publications] 中原勝: "溶液の非平衡過程の分子論的アプローチ・拡散過程のダイナミックス" 学術月報. 47(印刷中). (1993)

[Publications] 野村浩康: "液体および溶液の音波物性" 名古屋大学出版会, 295 (1994)

[Publications] 中原勝: "第4版実験化学講座11“反応と速度"" 丸善, 20 (1993)

[Publications] 中原勝: "改訂第4版化便覧基礎編" 丸善, 17 (1993)

[Publications] 中原勝: "溶液の分子論的描像" 学会出版センター(印刷中), (1994)