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1993 Fiscal Year Final Research Report Summary

Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups

Research Project

Project/Area Number 04303002
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 有機化学一般
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

SUZUKI Hitomi  Kyoto Univ. Dept. Chem. Professor, 理学部, 教授 (50025342)

Co-Investigator(Kenkyū-buntansha) KIRA Mitsuo  Tohoku Univ. Dept. Chem. Associate Professor, 理学部, 助教授 (40004452)
OKU Akira  Kyoto Inst. Tech. Dept. Chem. Professor, 工芸学部, 教授 (50027885)
TAKEUCHI Kenichi  Kyoto Univ. Dept. Chem. Professor, 工学部, 教授 (50026358)
OKUYAMA Tadashi  Osaka Univ. Dept. Chem., Associate Professor, 基礎工学部, 助教授 (40029484)
TOMIOKA Hideo  Mie Univ. Dept. Chem., Professor, 工学部, 教授 (20024599)
Project Period (FY) 1992 – 1993
KeywordsSubstituent effect / Heteroatom Compounds / Stereochemistry / Asymmetric Synthesis / Kinetics / Photochemical reaction / Electron transfer / Reaction intermediate
Research Abstract

Specificity in organic reactions, one of the most important research subjects of current organic chemistry, has been investigated systematically under the name of the title joint project by twenty-eight chemists of a wide variety of speciality backgrounds. The selected experts were devided into three project teams of comparative size ; the first team was mainly concerned with the problems on the enhancement of specificity and reactivity by organic functional groups ; the second one was devoted to the analysis of the relationship between reactivity and electronic requirements, and the last one dealt with the high specificity arising from some functionalized reactive intermediate. The project has brought a great success, more than 460 original papers being published in prestigeous international journals during the given period of the joint studies. Major part of the fruitful results has been presented by the members of each team at two open meetings held in Kyoto on Dec. 4-5, 1993 and Dec. 17-18, 1994.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N,N-Dimethylamino Group.X-Ray Structure Analysis,Asymmetric Induction at Bismuth Centre and Dynamic Behaviour in Solution" J.Chem.Soc.,Perkin Trans.1. 1169-1175 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hideo Tomioka: "Formation of Heptafulvene in Reaction of [(Methoxycarbonyl)]phenylcarbene in the Gas Phases" J.Am.Chem.Soc.58. 4196-4197 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tadashi Okuyama: "Dual Reactivity of Methoxymethyl Benzenesulfinate in Nucleophilic Substitution" Bull.Chem.Soc.Jpn.65. 2672-2683 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Ken'ichi Takeuchi: "Quantitative Treatment of Rate Enhancement due to F-Strain in the Solvolysis of(Z)-2-Ethylidene-1-adamantyl Mesylate and Halides" Tetrahedron Lett.34. 3335-3338 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Akira Oku: "Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles.A Three-component Coupling Reaction" Acta Chem.Scand.47. 391-397 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Mitsuo Kira: "p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates" Chem.Lett.1859-1862 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N, N-Dimethylamino Group. X-Ray Structure Analysis, Asymmetric Induction at Bismuth Center and Dynamic Behavior in Solution" J.Chem. Soc. Perkin Trans.1. 1169-1175 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hideo Tomioka: "Formation of Heptafulvene in Reaction of (Methoxycarbonyl) phenyl carbene in the Gas Phases" J.Am. Chem. Soc.58. 4196-4197 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tadashi Okuyama: "Dual Reactivity of Methoxymethyl Benzenesulfinate in Nucliophilic Substituion" Bull. Chem. Soc. Jpn. 65. 2672-2783 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kenichi Takeuchi: "Quantitative Treatment of Rate Enhancement due to F-Strain in the Solbolysis of (z) -2-Ethylidene-1-adamantyl Mesylate and Halides" Tetrahedron. 34. 3335-3338 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akira Oku: "Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles. A Three-component Coupling Reaction" Acta Chem. Scand. 47. 391-397 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Mitso Kira: "p-and m-phenylenebis (tri-fluoro (phenyl) silicates) and related Monosilicates" Chem. Lett.1859-1862 (1993)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1995-03-27  

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