1993 Fiscal Year Final Research Report Summary

Stereochemical Controle for Functonal Metal Complexes

Research Project

Project/Area Number	04303005
Research Category	Grant-in-Aid for Co-operative Research (A)
Allocation Type	Single-year Grants
Research Field	無機・錯塩・放射化学
Research Institution	KYUSYU UNIVERSITY
Principal Investigator	OKAWA Hisashi Kyusyu Univ., Fac.Sci., Prof., 理学部, 教授 (00037219)
Co-Investigator(Kenkyū-buntansha)	MIYAMOTO Takeshi Tokyo Univ., Fac.Sci., Prof., 理学部, 助教授 (30011604) MUNAKATA Megumu Kinki Univ., Fac.Sci.Tech., Prof., 理工学部, 教授 (80090942) TATSUMI Kazuyuki Osaka Univ., Fac.Tech., Ast.Prof., 基礎工学部, 助教授 (10155096) UEHARA Akira Kanazawa Univ., Fac.Sci., Prof., 理学部, 教授 (30019484) ITO Tasuku Tohoku Univ., Fac.Sci., Prof., 理学部, 教授 (90007328)
Project Period (FY)	1992 – 1993
Keywords	O_2 Adduct / Ferromagnet / CO_2 Reduction / Metal Porpyrine / Chromotropism / Prototropy / Carcogenide / Supramolecule
Research Abstract	1. Stereochemical Controle of Mononuclear Complexes : Prof.Ueyama studied the redox potential controle of thiolato-Mo complexes as Mo-enzyme models by means of intramolecular hydrogen bonds. Prof.Kaizaki studied geometrical isomerization of dinuclear Cr(III) complexes, controled by intramolecular hydrogen bond. Prof.Tanaka realized the deduction of CO_2 using ruthenium(II) complexes. Prof.Kimura reported a Ni(II)-O_2 complex of a designed macrocycle. Prof.Sasaki found a reversible Mo(IV)-O_2 carrier of porpyrine ligand. 2. Stereochemical Controle of Oligomeric Complexes : Prof.Uehara prepared stable O_2-adducts of dinuclear Fe(II) and Cu(I) complexes of designed dinucleating ligands. Prof.Nishida studied activation of molecular dioxygen by means of dinuclear Fe(II) complexes. Prof.Haga realized a redox-switching system based on prototropy of dinuclear benzimidazolato Ru complexes. Prof.Fukuda found a chromotropism based on dinuclear Ni(II) complexes. Prof.Yano studied hemegythrine analogs of Ru(II) ion. Prof.Ogino reported new silylene-bridged Fe complexes and their photo-induced isomerization. 3. Stereochemical Controle of Complex Clusters and Complex Assemblies : Prof.Ito prepared metal-complex assemblies composed of a mu-oxo-hexa(carboxylato)M_3 and metal-porpyrines. Prof.Tatsumi found a new synthetic way for carcogenido-Ta clusters based on a trinuclear Ta complex. Prof.Ohtaki studied superionic conducting glasses of the system such as AgI-Ag_2O-CrO_3. Prof.Okawa reported 3-dimensional bimetallic assemblies exhibiting spontaneous magnetization. Prof.Munakata studied supramolecular assemblies of metal complexes of a graphite-like network.

Research Products

(72 results)

All Other

All Publications (72 results)

[Publications] Hiroko TAMAKI: "Design of Metal-Complex Magnet.Synthesis and Magnetic Properties of Mixed-metal Assemblies{NBu_4[MCr(ox)_3]}_x" J.Am.Chem.Soc.114. 6974-6979 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hiroko TAMAKI: "Metal-complex Ferrimagnets with the Formula{NBu_4[MFe(ox)_3]}_x" Chem.Lett.1992. 1974-1978 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Nobutoshi KOMEDA: "Electrochemical Carbon Dioxide Fixation to Thioesters Catalyzed by[Mo_2Fe_6S_8(SEt)_9]^<3->" J.Am.Chem.Soc.114. 3625-3630 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Nobumasa KITAJIMA: "A New Model for Dioxygen Binding in Hemocyanin.A Molecular Structure of μ-η^2;η^2 Peroxo Dinuclear Copper-(II)Complexes" J.Am.Chem.Soc.114. 1278-1291 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Norikazu UEYAMA: "cis-Dioxobis(benzenedithiolato)W(V)and related Monooxo-tungsten(V)and -(IV)Complexes.Model of Tungsten oxydoreductases" J.Am.Chem.Soc.114. 7310-7311 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masatatsu SUZUKI: "(μ-Alkoko)diiron(II,II)Complexes of Tetrakis(2-(6-methylpyridyl)methyl)-1,3-diaminopropane-2-olate and Reversible Formation of O_2-Adducts" Chem.Lett.1992. 91-94 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] S.Patnaik: "A Structural Study on AgI-Ag_2O-CrO_3" J.Phys.Soc.Jpn.62. 536-543 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masahiro EBIHARA: "Synthesis,Structure,and Properties of Oxidized Hexamolybdenum Clusters" Inorg.Chem.31. 1645-1649 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Michiko SATO: "Anion Sensing Electrodes Based on Nickel(II)Mixed Ligand Complexes" Chem.Lett.1992. 399-402 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masayuki KOIKAWA: "Synthesis and Characterization of Fe(III)and Fe(IV)Complexes of N-(o-Hydroxyphenyl)salicylamide and Homologs" Inorg.Chim.Acta. 194. 75-80 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Kenji SHINDO: "A Manganese(III)Complex of 3,5-Bis((salicylideneamino)-methyl)pyrazole:Synthesis,Structure,and Properties" Inorg.Chem.31. 4987-4990 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masaaki OHBA: "Synthesis and Magnetism of Oxamido- and Oxamato-bridged Nickel(II)-Copper(II)Complexes" Bull.Chem.Soc.Jpn.65. 1988-1989 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Megumu MUNAKATA: "Synthesis,Structures and Formation Constants of Cu(I)Complexes with Alkynes and 1,10-Phenanthroline" J.Chem.Soc.Dalton Trans.1992. 2225-2230 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Manabu NAKAHANADA: "Synthesis and Characterization of L-Tartarato Cr(III)Complexes with Acetylacetonate Ions" J.Chem.Soc.Dalton Trans.1992. 3423-3426 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Yuzo NISHIDA: "Reaction between Binuclear Iron(III)Compounds and DMPO(5,5-Dimethyl-3,5-dihydropyrrole N-oxide)" J.Chem.Soc.Chem.Commun.1992. 93-94 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masaaki HAGA: "Photoexcited States of Biruthenium(II)Compounds Bridged by 2,2'-Bis(2-pyridyl)bibenzimidazole" Inorg.Chem.31. 548-555 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Takeshi MIYAMOTO: "Stability and Reactivity of Dihydroxobis(trimethyl-phosphine)platinum(II),an Intermediate Species for the Synthesis of Water-soluble Phosphine Complexes" Bull.Chem.Soc.Jpn.65. 3386-3397 (1992)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hisashi OKAWA: "Dicopper(II,II)and Dicopper(I,II)Complexes of a Series of Dinucleating Macrocycles" J.Chem.Soc.Dalton Trans.1993. 253-258 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hisashi OKAWA: "The Emergence of Trinuclear Constellations at Metallo-biosites" J.Chem.Soc.Dalton Trans.1993. 1349-1357 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hisashi OKAWA: "Heterodinuclear Cu^<II>Pb^<II> and Cu^<II>M^<II>(M=Mn,Fe,Co,Ni,Cu,Zn)Complexes of Macrocycles with Dissimilar 4- and 5-Coordination Sites" Inorg.Chem.32. 2949-2957 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hiroshi SAKIYAMA: "Macrocyclic Tetranuclear Manganese(II)Complexes of a New Dimer-of-dimers Type.Synthesis,Structure and Magnetism" J.Chem.Soc.Dalton Trans.1993. 2329-2334 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Masaaki OHBA: "Oxalato-bridged Dinuclear Cr(III)-M(II)(M=Cu,Ni,Co,Fe,Mn)Complexes:Synthesis,Structure,and Magnetism" Inorg.Chem.32. 5385-5390 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Minoru MITSUMI: "The Dithiooxalato-bridged Complexes[Cr(C_2O_2S_2)_3(NiL)_3]-(ClO_4)_3(L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraaza-cyclotetradecane):Synthesis,Structure,and Magnetism" J.Chem.Soc.Dalton Trans.1993. 2991-2994 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Naohide MATSUMOTO: "Ferromagnetic Spin-Coupling of Several Homo- and Mixed-Metal Complexes" Mol.Cryst.Liq.Cryst.1993. 299-308 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Eiichi Kimura: "A New Cyclam with an NH_2-Pendant Donor,6-Amino-1,4,8,11-tetraazacyclotetradecane,ant Its Ni(II)Complex" Inorg.Chem.32. 279-284 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Takaaki Okamura: "The Effect of Strong NH-S Hydrogen Bonds in the Cu(I)Thiolate Complex" J.Chem.Soc.Chem.Commun.1993. 1658-1660 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Kazuyuki Tatsumi: "A New Class of Heterometallic TaM_2 Cluster" Angew.Chem.Int.Ed.Engl.32. 63-65 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Yuzo Nishida: "Interaction between Metal Complexes and Dioxygen in the Presence of Aliphatic Aldehyde" Chem.Lett.1993. 917-920 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Kounosuke Uozumi: "Reactivity of Cu(I)Complexes Containing a Various Tetradentate Tripodal Ligands with Molecular Oxygen" Chem.Lett.1993. 963-966 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Tadashi Yamaguchi: "Tetranuclear Pt(II)Complexes Having Nonbridging Chelate Ligands in the Plane of the Square-planar Cluster Core" Inorg.Chem.32. 4996-4999 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Morio Yashiro: "Regulation of the Ligand Field Strength of a Co(III)Complex by Methyl Substitution on a Tetramine Ligand:An Important Factor for the Dissociation・・・" Inorg.Chem.32. 4166-4167 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Yasuo Suzuki: "(1,1-Cyclobutanedicarboxylato-0,0)bis(trimethylphosphine-P)platinum(II)Monohydrate" Acta Cryst.C49. 1315-1317 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Kasumi Yamada: "Synthesis and Crystal Structure of the Binuclear Ni(II)Complex μ-Oxalatobis((acetylacetonato)(N,N,N',N'-tetra-methylethylenediamine))nickel(II)" Bull.Chem.Soc.Jpn.66. 2758-2761 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Manabu Nakahanada: "Synthesis and Characterization of Novel Binuclear Cr(III)Complexes Bridged by Aromatic Heterocyclic Compounds" J.Chem.Soc.Dalton Trans.1993. 3681-3684 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hisako Hashimoto: "Synthesis of 1,2,3,4-Tetramethylfulvene-bridged Diiron Complex and Its Reaction with Phosphines" Organometal.12. 2182-2187 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] Hitoshi Ohtaki: "Dissolution and Nucleation Phenomena of Salts in Water.Molecular Dynamics Approach and Supporting Solution・・・・" Pure Appl.Chem.65. 203-211 (1993)
- Description
  「研究成果報告書概要(和文)」より
[Publications] H.Tamaki, Z.J.Zhong, N.Matsumoto, S.Kida, M.Koikawa, N.Achiwa, Y.Hashimoto, and H.Okawa: "Design of Metal-complex Magnets. Synthesis and Magnetic Properties of Mixed-metal Assmblies {NBu_4[MCr(ox)_3]}_x" J.Am.Chem.Soc.114. 6974-6979 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Tamaki, M.Mitsumi, K.Nakamura, N.Matsumoto, S.Kida, H.Okawa, and S.Iijima: "Metal-Complex Ferrimagnets with the Formula {NBu_4[M^<II>Fe^<III>(ox)_3]}_x" Chem.Lett.1974-1978 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] N.Komeda, H.Nagao, T.Matsui, G.Adachi, and K.Tanaka: "Electrochemical Carbon Dioxide Fixation to Thioesters Catalyzed by [Mo_2Fe_6S_8(SEt)_9]^<3->" J.Am.Chem.Soc.114. 3625-3630 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] N.Kitajima, K.Fujisawa, C.Fujimoto, Y.Morooka, S.Hashimoto, T.Kitagawa, K.Toriumi, K.Tatsumi, and A.Nakamura: "A New Model for Dioxygen Binding in Hemocyanin. Synthesis, Characterization, and Molecular Structure of Peroxo Dinuclear Copper(II) Compleses" J.Am.Chem.Soc.114. 1277-1291 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] N.Ueyama, H.Oku, and A.Nakamura: "cis-Dioxobis(benzene-dithiolato)tungsten(VI) and Related Monooxotungsten(V) and -(IV) Complexes. Models of Tungsten Oxidoreductase" J.Am.Chem.Soc.114. 7310-7311 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] Y.Hayashi, M.Suzuki, A.Uehara, Y.Mizutani, and T.Kitagawa: "(mu-Alkoxo)diiron(II,II)Complexes of diaminopropane-2-olate and the Reversible Formation of O_2-Adducts" Chem.Lett.91-94 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Ebihara, K.Isobe, Y.Sasaki, and K.Saito: "Synthesis, Structure, and Properities of Oxidized Hexamolybdenum Clusters" Inorg.Chem.31. 1644-1649 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] N.Sato and Y.Fukuda: "Anion-Sensing Electrodes Based on Nickel(II) Mixed Ligand Complexes" Chem.Lett.399-402 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Koikawa, H.Okawa, Y.Maeda, and S.Kida: "Synthesis and Characterization of Fe(III) and Fe(IV) Complexes of N-(2-Hydroxyphenyl)salicylamide and Homologs" Inorg.Chim.Acta.194. 75-80 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] K.Shindo, Y.Mori, K.Motoda, H.Sakiyama, N.Matsumoto, and H.Okawa: "A Mn(III) Complex of 3.5-Bis[(salicylideneamino)methyl]pyrazole : Synthesis, Strucutre, and Properties" Inorg.Chem.31. 4987-4990 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Ohba, N.Matsumoto, and H.Okawa: "Synthesis and Magnetism of Oxamido- and Mxamato-bridged Ni(II) cU(II) Complexes" Bull.Chem.Soc.Jpn.65. 1988-1989 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Munakata, S.Kitagawa, I.Kawada, M.Maekawa, and H.Shimono: "Synthesis, Formation Constants and Structures of Ternary Cu(I) Complexes with 1,10-Phenanthroline and Alkynes" J.Chem.Soc.Dalton Trans.2225-2230 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Nakahanada, T.Fujihara, N.Koine, and S.Kaizaki: "Synthesis and Characterization of L-Tartarato Cr(III) Complexes with Acetylacetonate Ions" J.Chem.Soc.Dalton Trans.3423-3426 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] Y.Nishida, M.Nasu, and T.Akamatsu: "Reaction between Binuclear Fe(III) Compounds and DMPO (5,5-Dimethyl-3,4-dihydropyrrole N-Oxide)" J.Chem.Soc.Chem.Commun.93-94 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] T.Ohno, K.Nozaki, and M.Haga: "Photoexcited States of Biruthenium(II) Compounds Bridged by 2.2'-Bis(2-pyridyl)bibenzimidazole" Inorg.Chem.31. 548-555 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] K.Miyamoto, Y.Suzuki, and H.Ichida: "Stability and Reactivity of Dikydroxobis(trimethylphosphine)Pt(II), an Intermediate Species for the Synthesis of Water soluble Phosphine Complexes" Bull.Chem.Soc.Jpn.65. 3386-3387 (1992)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Okawa, M.Tadokoro, Y.Aratake, M.Ohba, K.Shindo, M.Mitsumi, M.Koikawa, M.Tomono, and D.E.Fenton: "Dicopper(II,II) and Dicopper(I,II) Complexes of a Series of Dinucleating Macrocycles" J.Chem.Soc.Dalton Trans.243-258 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] D.E.Fenton and H.Okawa: "The Emergence of Trinuclear Constellations at Metallobiosites" J.Chem.Soc.Dalton. 1349-1357 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Okawa, J.Nishio, M.Ohba, M.Tadokoro, N.Matsumoto, M.Koikawa, S.Kida, and D.E.Fenton: "Heterodinuclear Cu^<II>Pb^<II> and Cu^<II>M^<II> (M=Mn, Fe, Co, Ni, Cu, Zn) Complexes of Macrocycles with Dissimilar 4- and 5- Coordination Sites" Inorg.Chem.32. 2949-2955 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Sakiyama, K.Tokunaga, Y.Matsumura, and H.Okawa: "Macrocyclic Tetranuclear Manganese(II) Complexes of a New Dimer-of-Dimers Type : Synthesis, Structure, and Magnetism" J.Chem.Soc.Dalton Trans.2329-2334 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Ohba, H.Tamaki, N.Matsumoto, and H.Okawa: "Oxalato-Bridged Dinuclear Cr(III)-M(II) (M=Cu, Ni, Co, Fe, Mn) Complexes : Synthesis, Structure, and Magnetims" Inorg.Chem.32. 5385-5390 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Mitsumi, H.Okawa, H.Sakiyama, M.Ohba, N.Matsumoto, T.Kurisaki, and H.Wakita: "The Dithiooxalato-bridged Complex [Cr(C_2O_2S_2)_3(NiL)_3](ClO_4)_3 (L=5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetrazacyclotetradecane) : Synthesis, Crystal Structure, and Magnetism" J.Chem.Soc.Dalton Trans.2991-2994 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] E.Kimura, M.Haruta, T.Koike, M.Shinoya, K.Takenouchi, and Y.IITAKA: "A New Cyclam with an NH_2-Pendant Donor, 6-Amino-1,4,8,11-tetraazacyclotetradecane, and Its Nickel(II) Complexs" Inorg.Chem.32. 279-284 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] T.Okamura, N.Ueyama, A.Nakamura, E.W.Ainscough, A.M.Brodie, and J.M.Waters: "The Effect of Strong NH-S Hydrogen Bonds in the Cu(I) Thiolate Complex" J.Chem.Soc.Chem.Commun.1658-1660 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] K.Tatsumi, H.Kawaguchi, Y.Inoue, A.Nakamura, R.E.Cramer, and J.A.Golen: "[Cp*TsS_3{Rh(cod)}_2] and [Cp*TaS_3{RuH(PPh_3)_2}_2] : A New Clas of Heterometallic TaM_2 Clusters" Angew.Chem.Int.Ed.Engl.32. 63-65 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] Y.Nishida, S.Takahashi, and I.Watanabe: "Interaction between Metal Compounds and Dioxygen Molecule in the Presence of Aliphatic Aldehyde" Chem.Lett.917-920 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] K.Uozumi, Y.Hayashi, M.Suzuki, and A.Uehara: "Reactivity of Cu(I) Complexes Containing Various Tetradentate Tripodal Ligands with Molecular Oxygen" Chem.Lett.963-966 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] T.Yamaguchi, T.Ueno, and T.Ito: "Tetranuclear Pt(II) Complexes Having Nonbridging Chelate Ligands in the Plane of the Square-Planar Cluster Core" Inorg.Chem.32. 4996-4999 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Yashiro, S.Yoshikawa, and S.Yano: "Regulation of the Ligand Field Strength of a Co(III) Complex by Metyl Substitutions on a Tetramine Ligand : An Important Factor for the Dissociation of a Generally Inert Chelated Amino Acidata Ligand from a Co(III) Complex" Inorg.Chem.32. 4166-4169 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] Y.Suzuki, T.K.Miyamoto, and H.Ichida: "(1,1-Cyclobutanedicarboxylato-0,0)bis(trimethylphosphine-P)-platinum(II) Monohydrate" Acta Cryst.C49. 1315-1317 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] K.Yamada, Y.Fukuda, T.Kawamoto, Y.Kushi, W.Mori, and K.Unoura: "Synthesis and Crystal Structure of the Binuclear Ni(II) Complex, mu-Oxalato-bis[(acetyl-acetonato)(N,N,N', N'-tetramethylethylenediamine)-nickes(II)]" Bull.Chem.Soc.Jpn.66. 2758-2761 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Nishida, T.Suzuki, and E.Tsuchida: "Oxygen Dissolution and Transport in Cobaltporphyrin-bound Membranes" Polymer Adv.Tech.4. 17-20 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Hashimoto, H.Tobita, and H.Ogino: "Synthesis of 1,2,3,4-Tetramethylfulvene-bridged Diiron Complex and Its Reactions with Phosphines" Organometllics. 12. 2182-2187 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] M.Nakahanada, K.Ito, and S.Kaizaki: "Synthesis and Characterization of Novel Binuclear Cr(III) Complexes Bridged by Aromatic Heterocyvclic Compounds" J.Chem.Soc.Dalton Trans.3681-3684 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Ohtaki: "Dissolution and Nucleation Phenomena of Salts in Water. Molecular Dynamics Approach and Supporting Solution X-Ray Diffraction Measurements" Pure Appl.Chem.65. 203-211 (1993)
- Description
  「研究成果報告書概要(欧文)」より
[Publications] H.Tanaka, B.-C.Tzeng, H.Nagao, S.Peng, and K.Tanaka: "Compartive Study on Crystal Structures of [Ru(bpy)_2(CO)_2](PF_6)_2, [Ru(bpy)_2(CO)(CH_3CO_2)]B(C_6H_5)_4 and [Ru(bpy)_2(CO)(mu-CO_2)]3H_2O" Inorg.Chem.32. 1508-1512 (1993)
- Description
  「研究成果報告書概要(欧文)」より

1993 Fiscal Year Final Research Report Summary

Stereochemical Controle for Functonal Metal Complexes

Principal Investigator

OKAWA Hisashi Kyusyu Univ., Fac.Sci., Prof., 理学部, 教授 (00037219)

Research Products

[Publications] Hiroko TAMAKI: "Design of Metal-Complex Magnet.Synthesis and Magnetic Properties of Mixed-metal Assemblies{NBu_4[MCr(ox)_3]}_x" J.Am.Chem.Soc.114. 6974-6979 (1992)

Description

[Publications] Hiroko TAMAKI: "Metal-complex Ferrimagnets with the Formula{NBu_4[MFe(ox)_3]}_x" Chem.Lett.1992. 1974-1978 (1992)

Description

[Publications] Nobutoshi KOMEDA: "Electrochemical Carbon Dioxide Fixation to Thioesters Catalyzed by[Mo_2Fe_6S_8(SEt)_9]^<3->" J.Am.Chem.Soc.114. 3625-3630 (1992)

Description

[Publications] Nobumasa KITAJIMA: "A New Model for Dioxygen Binding in Hemocyanin.A Molecular Structure of μ-η^2;η^2 Peroxo Dinuclear Copper-(II)Complexes" J.Am.Chem.Soc.114. 1278-1291 (1992)

Description

[Publications] Norikazu UEYAMA: "cis-Dioxobis(benzenedithiolato)W(V)and related Monooxo-tungsten(V)and -(IV)Complexes.Model of Tungsten oxydoreductases" J.Am.Chem.Soc.114. 7310-7311 (1992)

Description

[Publications] Masatatsu SUZUKI: "(μ-Alkoko)diiron(II,II)Complexes of Tetrakis(2-(6-methylpyridyl)methyl)-1,3-diaminopropane-2-olate and Reversible Formation of O_2-Adducts" Chem.Lett.1992. 91-94 (1992)

Description

[Publications] S.Patnaik: "A Structural Study on AgI-Ag_2O-CrO_3" J.Phys.Soc.Jpn.62. 536-543 (1992)

Description

[Publications] Masahiro EBIHARA: "Synthesis,Structure,and Properties of Oxidized Hexamolybdenum Clusters" Inorg.Chem.31. 1645-1649 (1992)

Description

[Publications] Michiko SATO: "Anion Sensing Electrodes Based on Nickel(II)Mixed Ligand Complexes" Chem.Lett.1992. 399-402 (1992)

Description

[Publications] Masayuki KOIKAWA: "Synthesis and Characterization of Fe(III)and Fe(IV)Complexes of N-(o-Hydroxyphenyl)salicylamide and Homologs" Inorg.Chim.Acta. 194. 75-80 (1992)

Description

[Publications] Kenji SHINDO: "A Manganese(III)Complex of 3,5-Bis((salicylideneamino)-methyl)pyrazole:Synthesis,Structure,and Properties" Inorg.Chem.31. 4987-4990 (1992)

Description

[Publications] Masaaki OHBA: "Synthesis and Magnetism of Oxamido- and Oxamato-bridged Nickel(II)-Copper(II)Complexes" Bull.Chem.Soc.Jpn.65. 1988-1989 (1992)

Description

[Publications] Megumu MUNAKATA: "Synthesis,Structures and Formation Constants of Cu(I)Complexes with Alkynes and 1,10-Phenanthroline" J.Chem.Soc.Dalton Trans.1992. 2225-2230 (1992)

Description

[Publications] Manabu NAKAHANADA: "Synthesis and Characterization of L-Tartarato Cr(III)Complexes with Acetylacetonate Ions" J.Chem.Soc.Dalton Trans.1992. 3423-3426 (1992)

Description

[Publications] Yuzo NISHIDA: "Reaction between Binuclear Iron(III)Compounds and DMPO(5,5-Dimethyl-3,5-dihydropyrrole N-oxide)" J.Chem.Soc.Chem.Commun.1992. 93-94 (1992)

Description

[Publications] Masaaki HAGA: "Photoexcited States of Biruthenium(II)Compounds Bridged by 2,2'-Bis(2-pyridyl)bibenzimidazole" Inorg.Chem.31. 548-555 (1992)

Description

[Publications] Takeshi MIYAMOTO: "Stability and Reactivity of Dihydroxobis(trimethyl-phosphine)platinum(II),an Intermediate Species for the Synthesis of Water-soluble Phosphine Complexes" Bull.Chem.Soc.Jpn.65. 3386-3397 (1992)

Description

[Publications] Hisashi OKAWA: "Dicopper(II,II)and Dicopper(I,II)Complexes of a Series of Dinucleating Macrocycles" J.Chem.Soc.Dalton Trans.1993. 253-258 (1993)

Description

[Publications] Hisashi OKAWA: "The Emergence of Trinuclear Constellations at Metallo-biosites" J.Chem.Soc.Dalton Trans.1993. 1349-1357 (1993)

Description

[Publications] Hisashi OKAWA: "Heterodinuclear Cu^<II>Pb^<II> and Cu^<II>M^<II>(M=Mn,Fe,Co,Ni,Cu,Zn)Complexes of Macrocycles with Dissimilar 4- and 5-Coordination Sites" Inorg.Chem.32. 2949-2957 (1993)

Description

[Publications] Hiroshi SAKIYAMA: "Macrocyclic Tetranuclear Manganese(II)Complexes of a New Dimer-of-dimers Type.Synthesis,Structure and Magnetism" J.Chem.Soc.Dalton Trans.1993. 2329-2334 (1993)

Description

[Publications] Masaaki OHBA: "Oxalato-bridged Dinuclear Cr(III)-M(II)(M=Cu,Ni,Co,Fe,Mn)Complexes:Synthesis,Structure,and Magnetism" Inorg.Chem.32. 5385-5390 (1993)

Description

[Publications] Minoru MITSUMI: "The Dithiooxalato-bridged Complexes[Cr(C_2O_2S_2)_3(NiL)_3]-(ClO_4)_3(L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraaza-cyclotetradecane):Synthesis,Structure,and Magnetism" J.Chem.Soc.Dalton Trans.1993. 2991-2994 (1993)

Description

[Publications] Naohide MATSUMOTO: "Ferromagnetic Spin-Coupling of Several Homo- and Mixed-Metal Complexes" Mol.Cryst.Liq.Cryst.1993. 299-308 (1993)

Description

[Publications] Eiichi Kimura: "A New Cyclam with an NH_2-Pendant Donor,6-Amino-1,4,8,11-tetraazacyclotetradecane,ant Its Ni(II)Complex" Inorg.Chem.32. 279-284 (1993)

Description

[Publications] Takaaki Okamura: "The Effect of Strong NH-S Hydrogen Bonds in the Cu(I)Thiolate Complex" J.Chem.Soc.Chem.Commun.1993. 1658-1660 (1993)

Description

[Publications] Kazuyuki Tatsumi: "A New Class of Heterometallic TaM_2 Cluster" Angew.Chem.Int.Ed.Engl.32. 63-65 (1993)

Description

[Publications] Yuzo Nishida: "Interaction between Metal Complexes and Dioxygen in the Presence of Aliphatic Aldehyde" Chem.Lett.1993. 917-920 (1993)

Description

[Publications] Kounosuke Uozumi: "Reactivity of Cu(I)Complexes Containing a Various Tetradentate Tripodal Ligands with Molecular Oxygen" Chem.Lett.1993. 963-966 (1993)

Description

[Publications] Tadashi Yamaguchi: "Tetranuclear Pt(II)Complexes Having Nonbridging Chelate Ligands in the Plane of the Square-planar Cluster Core" Inorg.Chem.32. 4996-4999 (1993)

Description

[Publications] Morio Yashiro: "Regulation of the Ligand Field Strength of a Co(III)Complex by Methyl Substitution on a Tetramine Ligand:An Important Factor for the Dissociation・・・" Inorg.Chem.32. 4166-4167 (1993)

Description

[Publications] Yasuo Suzuki: "(1,1-Cyclobutanedicarboxylato-0,0)bis(trimethylphosphine-P)platinum(II)Monohydrate" Acta Cryst.C49. 1315-1317 (1993)

Description

[Publications] Kasumi Yamada: "Synthesis and Crystal Structure of the Binuclear Ni(II)Complex μ-Oxalatobis((acetylacetonato)(N,N,N',N'-tetra-methylethylenediamine))nickel(II)" Bull.Chem.Soc.Jpn.66. 2758-2761 (1993)

Description

[Publications] Manabu Nakahanada: "Synthesis and Characterization of Novel Binuclear Cr(III)Complexes Bridged by Aromatic Heterocyclic Compounds" J.Chem.Soc.Dalton Trans.1993. 3681-3684 (1993)

Description

[Publications] Hisako Hashimoto: "Synthesis of 1,2,3,4-Tetramethylfulvene-bridged Diiron Complex and Its Reaction with Phosphines" Organometal.12. 2182-2187 (1993)

Description

[Publications] Hitoshi Ohtaki: "Dissolution and Nucleation Phenomena of Salts in Water.Molecular Dynamics Approach and Supporting Solution・・・・" Pure Appl.Chem.65. 203-211 (1993)

Description

[Publications] H.Tamaki, Z.J.Zhong, N.Matsumoto, S.Kida, M.Koikawa, N.Achiwa, Y.Hashimoto, and H.Okawa: "Design of Metal-complex Magnets. Synthesis and Magnetic Properties of Mixed-metal Assmblies {NBu_4[MCr(ox)_3]}_x" J.Am.Chem.Soc.114. 6974-6979 (1992)

Description

[Publications] H.Tamaki, M.Mitsumi, K.Nakamura, N.Matsumoto, S.Kida, H.Okawa, and S.Iijima: "Metal-Complex Ferrimagnets with the Formula {NBu_4[M^<II>Fe^<III>(ox)_3]}_x" Chem.Lett.1974-1978 (1992)

[Publications] K.Tatsumi, H.Kawaguchi, Y.Inoue, A.Nakamura, R.E.Cramer, and J.A.Golen: "[CpTsS_3{Rh(cod)}_2] and [CpTaS_3{RuH(PPh_3)_2}_2] : A New Clas of Heterometallic TaM_2 Clusters" Angew.Chem.Int.Ed.Engl.32. 63-65 (1993)