1992 Fiscal Year Annual Research Report

分子性固体場の創造ー分子システム

Research Project

Project/Area Number	04353001
Research Institution	Okazaki National Research Institutes
Principal Investigator	丸山有成岡崎国立共同研究機構, 分子科学研究所, 教授 (40013479)
Co-Investigator(Kenkyū-buntansha)	相原正樹山口大学, 教養部, 教授 (70091163) 十倉好紀東京大学, 理学部, 助教授 (30143382) 関一彦名古屋大学, 理学部, 教授 (80124220) 三谷忠興岡崎国立共同研究機構, 分子科学研究所, 助教授 (50010939) 国府田隆夫東京大学, 工学部, 教授 (50010715)
Keywords	分子性固体場 / 分子システム / 低次元物質 / 水素結合糸 / 炭素クラスター / 有機超伝導体 / 機能性分子
Research Abstract	本年度も2回の研究会を開催した。それぞれ特徴いる研究会で、第1回は平成4年9月20、21日に行われ、我々が興味を持っている物質系の物性に非常に近い領域で仕事をしている5名の理論研究者を外部より招待し、充分時間をかけて講演及び議論をして頂いた。これは各班員のそれぞれの研究をより深め進展させるのに大変有効であったばかりでなく、分子性固体場の概念を深化させかつ明確化するには大変有益であった。第2回の研究会は平成5年2月28日、3月1日に行われた。これは本総合研究の一応のしめくくりの会として実施したので、出席した班員全員から“分子性固体場"という立場からそれぞれの研究成果、見通しなどを報告して頂いた。有機超伝導体のグループでは、固体場という概念を通して新しい物質系の構築が報告され、着実な進展がはかられている。又、水素結合物質系でも、本研究中に新しい機能をもった物質系が開発されその研究の展開が報告された。さらに、C_<60>に代表される炭素クラスター固体の世界は、正に分子性固体場を具現したものであり、新しい考え方での研究の進展が着実に展開されている。又その理論的取扱いにも、新しい概念が取り込まれようとしている。光誘起電子相相転移(一次元性物質)の発見も本研究の間になされたもので、今後の展開が期待されている。主として研究会での3年間の討論を通じての“分子性固体場"の概念の理解は、それぞれの立場で若干の差異はあり得るが、ほぼ共通のイメージを持ち得るところまできたと思われる。今後は、もう少し焦点を絞った形で研究を深化させて、“分子性固体場"の概念の明確化と具現化を進めることが期待される。

Research Products
(31 results)

All Other

All Publications (31 results)

[Publications] 丸山有成: "Novel Molecular System C_<60>Fallerites and Fu6lerides" Mol Cryst Liq.Crust.218. 297-298 (1992)
[Publications] 稲辺保: "Electronic Structure of Alkali Metal Doped C_<60>Derived from Thormoelectric Power Measurements" Phys.Rev.Lett. 69. 3797-3800 (1992)
[Publications] 野上隆: "Synthesis of Multi-Sulfur TTF Derivatives and Conducting Organic Salts" Synth.Met.
[Publications] 十倉好紀: "Photo-Induced Bidirectional phase Transitions in Single Crystals of Polydiacetylenes" Syhth.Met. 50. 675 (1992)
[Publications] 十倉好紀: "Photo-Induced Phase Transitions in Quasi-one-Dimensional Molecular Systems" Mol.Cryst.Lig.Cryst.216. 3 (1992)
[Publications] 稲辺保: "Proton Transfer in N-Salicylideneanilines-Effect of Charge-Transfer Interaction" Mol.Cryst.Lig.Cryst.216. 229-234 (1992)
[Publications] 谷俊朗: "Excited state proton transfer and persistent hole formation processos in hydroxgantraquinone deivatives" Mol.Cryst.Lig.Cryst.216-218. 247-252 (1992)
[Publications] 国府田隆夫: "Nolinear Electronic Phenomens in Low Dimensional Organic Solids" Mol.Cryst.Lig.Cryst.217. 139-145 (1992)
[Publications] 岩佐義宏: "Two-step Neutal-ionic Phase Transition in Organie charge-Transfer Compounds:Possible Staging Effect" Phys.Rev.B. 47. 2920-2923 (1993)
[Publications] 那須奎一郎: "Superconductivities,metal-insulator transitions,and Strong enharcement and reduction of isotope effects in anhormonic peierls-Hubbard modol" J.Phys.Condens.Matter. 4. 3793-3811 (1992)
[Publications] 那須奎一郎: "励起子緩和現象の新しい局面:非線形格子緩和過程" 日本物理学会誌. 47. 462-469 (1992)
[Publications] 武田定: "NMR Study of Proton Dynamics in the Hydrogen Bouds in the Thermochrommic Crystals of N-Salieylideneaniline Derivatives" Mol.Cryst.Lig.Cryst.216. 235-240 (1992)
[Publications] 武田定: "Evidence of Quantum Correlation in the H/D Transfer Dynamics in the hydrogen Bonds in Partially Denterated Berzoic Acid Crystals" Chem.Phys.Lett.198. 316-320 (1992)
[Publications] 斎藤軍治: "Design of Organic Superconductors based on BEDT-TTF" Mat.Res.Symp.Proc.247. 483-494 (1992)
[Publications] 櫛田孝司: "Spectral Characteristics and Hole Burning in Myoglobin" Mol.Cryst.Lig.Cryst.217. 171-176 (1992)
[Publications] 櫛田孝司: "Site-Selective Spectroscopy of Myoglobin" Proc.4th Intern.Conf.on Laser Appl.in Life Sci.
[Publications] 阿波賀邦夫: "Ferromgnetic and Antiferromagnetic Interactions in the Two-Dimensional Triangular lattice of an α-Nitrong/Nitroxide Catien Rodical." Chem.Phys.Lett.195. 21-24 (1992)
[Publications] 関一彦: "UPS and XANES studios of Photopolymerization of Long-chain diacetylene Compounds" Mol.Cryst.Lig.Cryst.218. 85-90 (1992)
[Publications] 福留秀雄: "Resonating Hartree-Fock Theory of the One-Dimensional Hubbard Model II.Beather Fluctuations in the Strong Comelotion膈Regime" J.Phys.SOc.Jpn.61. 3209-3219 (1992)
[Publications] 村田恵三: "Hall Effect under Pressure in Low Dimensional Organic Superconductors" Jpn.J.Appl.Phys. 32. 306-309 (1992)
[Publications] 村田恵三: "β-(BEDT-TTF)_2I_3の20K転移" 固体物理. 28. 191 (1993)
[Publications] 薬師久彌: "Struture and Solid State Properties of Conductive(Phthalocyanine)cobalt Salt,CoPc(A_5F_6)_<0.5>" Synth.Met.
[Publications] 森健彦: "Structural and Physical Properties of a New Organic Superconductor,(BEDT-TTF)_4Pα(CN)_4H_2O" Solid State Commun.82. 177 (1992)
[Publications] 森健彦: "Synthesis of Tetrathiafulvalene Derivatives by the Use of Drganc-aluminium Reagents" Chem.Lett.1873 (1992)
[Publications] 中筋一弘: "Cooperative Proton-Electron Transfer(PET)Systems as New Molecular Systems" Mol.Cryst.Lig.Cryst.216. 213-216 (1992)
[Publications] 鈴木敏泰: "Dihydrofulleroid H_2C_<61>:Synthesis and Properties of the Smallest Fulleroid" J.Am.Chem.Soc.114. 7301-7302 (1992)
[Publications] 鈴木敏泰: "Systematic Inflation of Buckminsterfullerene C_<60>Syntesis of Dipheny /Fulleroids C_<61>to C_<66>" Science. 254. 1186 (1991)
[Publications] 相原正樹: "Time-resolved vibrational spectroscopy" Springer-Verlag, (1992)
[Publications] 斎藤軍治: "New Matterials" Narosa Pub.House, 21 (1992)
[Publications] 斎藤軍治: "大学院物理化学下(電子物性)" 講談社, 43 (1992)
[Publications] 関一彦: "Polymer-Solid Interfaces" IOP Publishing, 11 (1992)

1992 Fiscal Year Annual Research Report

分子性固体場の創造ー分子システム

Principal Investigator

丸山 有成 岡崎国立共同研究機構, 分子科学研究所, 教授 (40013479)

Research Products

[Publications] 丸山 有成: "Novel Molecular System C_<60>Fallerites and Fu6lerides" Mol Cryst Liq.Crust.218. 297-298 (1992)

[Publications] 稲辺 保: "Electronic Structure of Alkali Metal Doped C_<60>Derived from Thormoelectric Power Measurements" Phys.Rev.Lett. 69. 3797-3800 (1992)

[Publications] 野上 隆: "Synthesis of Multi-Sulfur TTF Derivatives and Conducting Organic Salts" Synth.Met.

[Publications] 十倉 好紀: "Photo-Induced Bidirectional phase Transitions in Single Crystals of Polydiacetylenes" Syhth.Met. 50. 675 (1992)

[Publications] 十倉 好紀: "Photo-Induced Phase Transitions in Quasi-one-Dimensional Molecular Systems" Mol.Cryst.Lig.Cryst.216. 3 (1992)

[Publications] 稲辺 保: "Proton Transfer in N-Salicylideneanilines-Effect of Charge-Transfer Interaction" Mol.Cryst.Lig.Cryst.216. 229-234 (1992)

[Publications] 谷 俊朗: "Excited state proton transfer and persistent hole formation processos in hydroxgantraquinone deivatives" Mol.Cryst.Lig.Cryst.216-218. 247-252 (1992)

[Publications] 国府田 隆夫: "Nolinear Electronic Phenomens in Low Dimensional Organic Solids" Mol.Cryst.Lig.Cryst.217. 139-145 (1992)

[Publications] 岩佐 義宏: "Two-step Neutal-ionic Phase Transition in Organie charge-Transfer Compounds:Possible Staging Effect" Phys.Rev.B. 47. 2920-2923 (1993)

[Publications] 那須 奎一郎: "Superconductivities,metal-insulator transitions,and Strong enharcement and reduction of isotope effects in anhormonic peierls-Hubbard modol" J.Phys.Condens.Matter. 4. 3793-3811 (1992)

[Publications] 那須 奎一郎: "励起子緩和現象の新しい局面:非線形格子緩和過程" 日本物理学会誌. 47. 462-469 (1992)

[Publications] 武田 定: "NMR Study of Proton Dynamics in the Hydrogen Bouds in the Thermochrommic Crystals of N-Salieylideneaniline Derivatives" Mol.Cryst.Lig.Cryst.216. 235-240 (1992)

[Publications] 武田 定: "Evidence of Quantum Correlation in the H/D Transfer Dynamics in the hydrogen Bonds in Partially Denterated Berzoic Acid Crystals" Chem.Phys.Lett.198. 316-320 (1992)

[Publications] 斎藤 軍治: "Design of Organic Superconductors based on BEDT-TTF" Mat.Res.Symp.Proc.247. 483-494 (1992)

[Publications] 櫛田 孝司: "Spectral Characteristics and Hole Burning in Myoglobin" Mol.Cryst.Lig.Cryst.217. 171-176 (1992)

[Publications] 櫛田 孝司: "Site-Selective Spectroscopy of Myoglobin" Proc.4th Intern.Conf.on Laser Appl.in Life Sci.

[Publications] 阿波賀 邦夫: "Ferromgnetic and Antiferromagnetic Interactions in the Two-Dimensional Triangular lattice of an α-Nitrong/Nitroxide Catien Rodical." Chem.Phys.Lett.195. 21-24 (1992)

[Publications] 関 一彦: "UPS and XANES studios of Photopolymerization of Long-chain diacetylene Compounds" Mol.Cryst.Lig.Cryst.218. 85-90 (1992)

[Publications] 福留 秀雄: "Resonating Hartree-Fock Theory of the One-Dimensional Hubbard Model II.Beather Fluctuations in the Strong Comelotion膈Regime" J.Phys.SOc.Jpn.61. 3209-3219 (1992)

[Publications] 村田 恵三: "Hall Effect under Pressure in Low Dimensional Organic Superconductors" Jpn.J.Appl.Phys. 32. 306-309 (1992)

[Publications] 村田 恵三: "β-(BEDT-TTF)_2I_3の20K転移" 固体物理. 28. 191 (1993)

[Publications] 薬師 久彌: "Struture and Solid State Properties of Conductive(Phthalocyanine)cobalt Salt,CoPc(A_5F_6)_<0.5>" Synth.Met.

[Publications] 森 健彦: "Structural and Physical Properties of a New Organic Superconductor,(BEDT-TTF)_4Pα(CN)_4H_2O" Solid State Commun.82. 177 (1992)

[Publications] 森 健彦: "Synthesis of Tetrathiafulvalene Derivatives by the Use of Drganc-aluminium Reagents" Chem.Lett.1873 (1992)

[Publications] 中筋 一弘: "Cooperative Proton-Electron Transfer(PET)Systems as New Molecular Systems" Mol.Cryst.Lig.Cryst.216. 213-216 (1992)

[Publications] 鈴木 敏泰: "Dihydrofulleroid H_2C_<61>:Synthesis and Properties of the Smallest Fulleroid" J.Am.Chem.Soc.114. 7301-7302 (1992)

[Publications] 鈴木 敏泰: "Systematic Inflation of Buckminsterfullerene C_<60>Syntesis of Dipheny /Fulleroids C_<61>to C_<66>" Science. 254. 1186 (1991)

[Publications] 相原 正樹: "Time-resolved vibrational spectroscopy" Springer-Verlag, (1992)

[Publications] 斎藤 軍治: "New Matterials" Narosa Pub.House, 21 (1992)

[Publications] 斎藤 軍治: "大学院物理化学下(電子物性)" 講談社, 43 (1992)

[Publications] 関 一彦: "Polymer-Solid Interfaces" IOP Publishing, 11 (1992)

丸山有成岡崎国立共同研究機構, 分子科学研究所, 教授 (40013479)

[Publications] 丸山有成: "Novel Molecular System C_<60>Fallerites and Fu6lerides" Mol Cryst Liq.Crust.218. 297-298 (1992)

[Publications] 稲辺保: "Electronic Structure of Alkali Metal Doped C_<60>Derived from Thormoelectric Power Measurements" Phys.Rev.Lett. 69. 3797-3800 (1992)

[Publications] 野上隆: "Synthesis of Multi-Sulfur TTF Derivatives and Conducting Organic Salts" Synth.Met.

[Publications] 十倉好紀: "Photo-Induced Bidirectional phase Transitions in Single Crystals of Polydiacetylenes" Syhth.Met. 50. 675 (1992)

[Publications] 十倉好紀: "Photo-Induced Phase Transitions in Quasi-one-Dimensional Molecular Systems" Mol.Cryst.Lig.Cryst.216. 3 (1992)

[Publications] 稲辺保: "Proton Transfer in N-Salicylideneanilines-Effect of Charge-Transfer Interaction" Mol.Cryst.Lig.Cryst.216. 229-234 (1992)

[Publications] 谷俊朗: "Excited state proton transfer and persistent hole formation processos in hydroxgantraquinone deivatives" Mol.Cryst.Lig.Cryst.216-218. 247-252 (1992)

[Publications] 国府田隆夫: "Nolinear Electronic Phenomens in Low Dimensional Organic Solids" Mol.Cryst.Lig.Cryst.217. 139-145 (1992)

[Publications] 岩佐義宏: "Two-step Neutal-ionic Phase Transition in Organie charge-Transfer Compounds:Possible Staging Effect" Phys.Rev.B. 47. 2920-2923 (1993)

[Publications] 那須奎一郎: "Superconductivities,metal-insulator transitions,and Strong enharcement and reduction of isotope effects in anhormonic peierls-Hubbard modol" J.Phys.Condens.Matter. 4. 3793-3811 (1992)

[Publications] 那須奎一郎: "励起子緩和現象の新しい局面:非線形格子緩和過程" 日本物理学会誌. 47. 462-469 (1992)

[Publications] 武田定: "NMR Study of Proton Dynamics in the Hydrogen Bouds in the Thermochrommic Crystals of N-Salieylideneaniline Derivatives" Mol.Cryst.Lig.Cryst.216. 235-240 (1992)

[Publications] 武田定: "Evidence of Quantum Correlation in the H/D Transfer Dynamics in the hydrogen Bonds in Partially Denterated Berzoic Acid Crystals" Chem.Phys.Lett.198. 316-320 (1992)

[Publications] 斎藤軍治: "Design of Organic Superconductors based on BEDT-TTF" Mat.Res.Symp.Proc.247. 483-494 (1992)

[Publications] 櫛田孝司: "Spectral Characteristics and Hole Burning in Myoglobin" Mol.Cryst.Lig.Cryst.217. 171-176 (1992)

[Publications] 櫛田孝司: "Site-Selective Spectroscopy of Myoglobin" Proc.4th Intern.Conf.on Laser Appl.in Life Sci.

[Publications] 阿波賀邦夫: "Ferromgnetic and Antiferromagnetic Interactions in the Two-Dimensional Triangular lattice of an α-Nitrong/Nitroxide Catien Rodical." Chem.Phys.Lett.195. 21-24 (1992)

[Publications] 関一彦: "UPS and XANES studios of Photopolymerization of Long-chain diacetylene Compounds" Mol.Cryst.Lig.Cryst.218. 85-90 (1992)

[Publications] 福留秀雄: "Resonating Hartree-Fock Theory of the One-Dimensional Hubbard Model II.Beather Fluctuations in the Strong Comelotion膈Regime" J.Phys.SOc.Jpn.61. 3209-3219 (1992)

[Publications] 村田恵三: "Hall Effect under Pressure in Low Dimensional Organic Superconductors" Jpn.J.Appl.Phys. 32. 306-309 (1992)

[Publications] 村田恵三: "β-(BEDT-TTF)_2I_3の20K転移" 固体物理. 28. 191 (1993)

[Publications] 薬師久彌: "Struture and Solid State Properties of Conductive(Phthalocyanine)cobalt Salt,CoPc(A_5F_6)_<0.5>" Synth.Met.

[Publications] 森健彦: "Structural and Physical Properties of a New Organic Superconductor,(BEDT-TTF)_4Pα(CN)_4H_2O" Solid State Commun.82. 177 (1992)

[Publications] 森健彦: "Synthesis of Tetrathiafulvalene Derivatives by the Use of Drganc-aluminium Reagents" Chem.Lett.1873 (1992)

[Publications] 中筋一弘: "Cooperative Proton-Electron Transfer(PET)Systems as New Molecular Systems" Mol.Cryst.Lig.Cryst.216. 213-216 (1992)

[Publications] 鈴木敏泰: "Dihydrofulleroid H_2C_<61>:Synthesis and Properties of the Smallest Fulleroid" J.Am.Chem.Soc.114. 7301-7302 (1992)

[Publications] 鈴木敏泰: "Systematic Inflation of Buckminsterfullerene C_<60>Syntesis of Dipheny /Fulleroids C_<61>to C_<66>" Science. 254. 1186 (1991)

[Publications] 相原正樹: "Time-resolved vibrational spectroscopy" Springer-Verlag, (1992)

[Publications] 斎藤軍治: "New Matterials" Narosa Pub.House, 21 (1992)

[Publications] 斎藤軍治: "大学院物理化学下(電子物性)" 講談社, 43 (1992)

[Publications] 関一彦: "Polymer-Solid Interfaces" IOP Publishing, 11 (1992)