1994 Fiscal Year Final Research Report Summary
Evaluation of Solvent Effects in Chemical Processes in Solutions and between Different Phases
| Project/Area Number |
05303004
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| Research Category |
Grant-in-Aid for Co-operative Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
分離・精製・検出法
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| Research Institution | Shinshu University |
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Principal Investigator |
IZUTSU Kosuke Shinshu Univ., Fac.of Science, Professor, 理学部, 教授 (70025336)
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| Co-Investigator(Kenkyū-buntansha) |
WATARAI Hitoshi Osaka Univ., Fac.of Science, Professor, 理学部, 教授 (30091771)
MATSUI Masakazu Kyoto Univ., Chemistry Institute, Professor, 化学研究所, 教授 (90027037)
FUNAHASI Sigenobu Nagoya Univ., Fac.of Science, Professor, 理学部, 教授 (30022700)
SENDA Mitsugi Fukui Pref.Univ., Fac.of Bioresources, Prefessor, 生物資源学部, 教授 (90026419)
AKAIWA Hideo Gunma Univ., Fac, of Engineering, Professor, 工学部, 教授 (60008414)
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| Project Period (FY) |
1993 – 1994
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| Keywords | Nonaqueous solvents / Solvent effect / Solvent evaluation / Solvation / Solute-solvent interaction / Solvent extraction / Ion transfer between immiscible solvents |
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| Research Abstract |
Nonaqueous solvents are often used as media for chemical reactions and for separation and concentration processes. In this research, fifteen investigators co-operated to develop methods for evaluation of solvent effects in the chemical processes in solutions and between different phases.
(1)For chemical processes in solutions, the solvent evaluation methods were studied by IWAMOTO,UMEMOTO,OKAZAKI,SAKAMOTO and IZUTSU by electroanalytical methods(voltammetry, potentiometry and conductometry)and spectrophotometry, and by FUNAHASI and MUNAKATA by NMR and EXAFS.
(2)For chemical processes between different liquid phases, the solvent evaluation methods were studied by AKAIWA,SENDA,TAKEDA,MASUDA,MATSHI and WATARAI by such methods as solvent extraction and voltammetry at the interfaces between immiscible solvents. Hori studied the solvents effects in the processes at solid-liquid interfaces using a co-precipitation method. WATANABE studied the gas-liquid process by photoelectron emmision spectroscopy.
(3)Various methods were developed for the evaluation of solvents effects in various chemical processes. Based on the research results, a guide book for solvent evaluation is now in preparation.
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Research Products
(14 results)
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[Publications] Y.Inada, K.Sugimoto, K.Ozutsumi, S.Funahashi: "Solvent structures of manganese(II), iron(II), cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), and indium(III)ions in 1,1,3,3-tetramethylurea as studied by EXAFS and electronic spectroscopy" Inorg.Chem.33-9. 1875-1880 (1994)
Description
「研究成果報告書概要(欧文)」より
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