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1994 Fiscal Year Final Research Report Summary

magnetic field induced metal-nonmetal transition in organic conductors

Research Project

Project/Area Number 05452061
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionToho University

Principal Investigator

KAJITA Koji  Toho University, Department of Physics, Professor, 理学部, 教授 (50011739)

Co-Investigator(Kenkyū-buntansha) NISHIO Yutaka  Toho University, Department of Physics, Professor, 理学部, 助教授 (20172629)
Project Period (FY) 1993 – 1994
KeywordsOrganic Conductor / Magnetoresistance / Hall effect / Metal-nonmetal Transition
Research Abstract

Two experiments were done in 1994. In the first one we examined if the magnetic field induced metal-nonmetal transition occurs in alpha- (BEDT-TSeF) _2I_3 of which the crystal structure and the electronic energy structure is very similar to those of alpha- (BEDT-TTF) _2I_3. The experimental results indicate that the field induced metal-nonmetal transition takes place in this materials as well as in alpha- (BEDT-TTF) _2I_3. However, the magnetic field strength about one order of magnitude higher was necessary to induce the transition. This may be due to low carrier mobility in this material.
The next problem concems with the transport properties in the metallic region. We measured the conductivity and the Hall effect simultaneously in the temperature region above the metal-nonmetal transition. We found that the carrier density of this material decreases with the decreasing temperature, while the carrier mobility increases. The effect of the change in the carrier density and the mobility just canceled out to give the temperature independent conductivity. This is just the same we observed in alpha- (BEDT-TSeF) _2I_3.
In the second experiment, we reexamined the low temperature Hall effect in alpha-(BEDT-TTF) _2I_3. A very large Hall angle observed at low temperatures suggests the fairly high carrier mobility in this material
Throughout the present project, we come to the conclusion that the magnetic field induced metal-nonmetal transition takes place in alpha- (BEDT-TTF) _2I_3 and alpha- (BEDT-TSeF) _2I_3 placed under high pressures and at low temperatures.

  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] 尾日吏,梶田晃示,西尾豊,小林速男,小林昭子,加藤礼三,家泰弘: "An Anomalms Magnetoresistance in α-(BEDT-TTF)_2I_3 under High Pressure:A Possible New Phase" Physica. B184. 494-497 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 三島孝博,梶田晃示,西尾豊,家泰弘: "Extremely High Mability Carriers in Organic Conductor α-(BEDT-TTF)_2I_3 under High Pressure" Materials Science and Engineering. B25. L1-L5 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 飯森茂,梶田晃示,西尾豊,家泰弘: "Anomalous Metal-Insulator Trausition in α-(BEDT-TTF)_2I_3 under High Pressure" Synthetic Metals. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 西尾豊,手賀俊樹,梶田晃示,小林速男,小林昭子,青沼秀児,澤博,加藤礼三: "Giant Peak in the Specific Heat of Selectively Deuterated (DMe-DCNQI)_2Cu" Synthetic Metals. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 手賀俊樹,西尾豊,梶田晃示,加藤礼三,小林速男: "Magnetic Praperties of (DMe-DCNQI)_2Cu under Uniaxial Stress" Synthetic Metals. 印刷中.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 三島孝博,尾日吏,梶田晃示,西尾豊,家泰弘: "Temperature Independent Conductiuity of,α-(BEDT-TTF)_2I_3-Compensation of the changein the Carrier Density and the Mobility" Synthetic Metals. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Mishima, K.Kajita, Y.Nishio and Y.Iye: ""Extremely High Mobility Carriers in Organic Conductor alpha- (BEDT-TTF) _2I_3 under High Pressure"" Materials Science and Engineering. B25. L1-L5 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Iimori, K.Kajita, Y.Nishio and Y.Iye: ""Anomalous Metal-Insulator Transition in alpha- (BEDT-TTF) _2I_3 under High Pressure"" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Nisho, T.Tega, K.Kajita, H.Kobayashi, S.Aonuma, H.Sawa and R.Kato: ""Giant Peak in the Specific Heat of Selectively Deuterated (DMe-DCNQI) _2Cu"" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Tega, Y.Nishio, K.Kajita, R.Kato and H.Kobayashi: ""Magnetic Properties of (DMe-DCNQI) _2Cu under Uniaxial Stress"" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Mishima, T.Ojiro, K.Kajita, Y.Nishio and Y.Iye": ""Temperature Independent Conductivity of alpha- (BEDT-TTF) _2I_3-Compensation of the Change in the Carrier density and the Mobility-" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1996-04-15  

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