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1994 Fiscal Year Final Research Report Summary

SYNTHESIS AND FUNCTION OF CHEMICAL MODIFIED NEW AROMATIC SYSTEMS

Research Project

Project/Area Number 05453131
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 有機工業化学
Research InstitutionKINKI UNIVERSITY

Principal Investigator

YOSHIDA Zenichi  Faculty of Science and Engineering, Kinki University, Professor, 理工学部, 教授 (60025814)

Co-Investigator(Kenkyū-buntansha) MAEKAWA Masahiko  Research institute for Science and Engineering, Kinki University, Assistant, 理工学部, 助手 (70229293)
TAKEKUMA Shinichi  Faculty of Science and Engineering, Kinki University, Assistant Professor, 理工学部, 講師 (00171629)
MATSUBARA Yoshio  Faculty of Science and Engineering, Kinki University, Professor, 理工学部, 教授 (80088450)
Project Period (FY) 1993 – 1994
KeywordsAzulenequinone / Methylene-bisazulene / [5] -radialene / Dodeca-penta-radialene / Pyrazoline-fullerene / C_<60>-Ni complex / Indolone, new 8pi aromatic pigment / Photosynthesis of protein
Research Abstract

Important results obtained in this research are as follows :
1.The bicapped C_<60> with gamma-cyclodextrin found to behave as a chemical nitrogenase which fixes nitrogen to produce NH_3.
2.Synthesis of 1,3-dipheny1-2-pyrazoline ring fused C_<60>, interesting system from biological and materials view points, was achieved.
3.Of 10pi aromatic system, 3,5-guaiazulenequinone and [5] radialene substituted with 1,3-dithiol groups were synthisized. Some biological property for the former, and electrochemical and physical propaties for the latter were elucidated.
4.Indolone, new 8pi aromatic pigment was discovered to exist as chromoprotein in a mushroom. It plays a very important role in protein photosynthesis.

  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] Z.Yoshida et al: "Investigation of Hydrogenation of C_<60> Using Theoretical Calculations21GC01:Chem.Phys.Lett." 201. 481-484 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Yoshida et al.: "Molecular Recognition of C_<60> with γ-Cyclodextrin" Angw.Chem.Int.Ed.Engl.23. 1597-1598 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Yoshida et al.: "Novel Redox Behavior of[5]Radialenes Substituted with 1,3-Dithiol Groups" J.Phy.Chem.95. 252-258 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takekuma et al.: "A Novel Mushroom Pigment:Isolation and Characterization" J.Am.Chem.Soc.116. 8849-8850 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Matsubara et al.: "Synthesis of Pyrazoline Ring-Fused C_<60> Using 1,3-Dipolar Addition" JSPS 116 Committee Report. 46. 4-7 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Takekuma et al.: "A Unique Pigment Component of Pleurotus Salmoneostramineus L.Vass and its Photosynthetic Function" JSPS 116 Committee Report. 46. 105-108 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 吉田善一、城田靖彦: "Chemistry of Functional Dyes" 三田出版, 330 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.Yoshida, I.Dogane, H.Ikehara, T.Endo: "Investigation of Hydrogenation of C_<60> Using Theoretical Calculations" Chem.Phys.Lett.201. 481 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.Yoshida, H.Takekuma, S.Takekuma, T.Matsbara: "Molecular Recognition of C_<60> with gamma-Cyclodextrin" Angw.Chem.Int.Ed.Engl.23. 1597 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.Yoshida, H.Takekuma, S.Takekuma, Y.Matsbara: "Fixation of Nitrogen by Bicapped C_<60>" Nature. (to be published). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Matsubara, H.Tada, Z.Yoshida: "Synthesis of Pyrazoline Ring-Fused C_<60> Using 1,3-Dipolar Addition" JSPS 116 Committee Report. (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Matsubara, H.Tada, S.Noagase, Z.Yoshida: "Reaction of C_<60> with Nitrileimne as a 1,3-Dipole. Synthesis of the First Stable C_<60>-Dinitrogen Heterocycle." J.Am.Chem.Soc.to be published. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takekuma, H.Takekuma, Y.Matsubara, Z.Yoshida: "A Novel Mushroom Pigment : Isolation and Characterization" J.Am.Chem.Soc.116. 8849 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.Yoshida, H.Takekuma, S.Takekuma, K.Inaba, Y.Matsubara: "A Unique Pigment Component of Pleurotus Salmoneostramineus L.Vass and its Photosynthetic Function" JSPS 116 Committee Report. 46. 96 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.Yoshida, H.Takekuma, S.Takekuma, K.Inaba, Y.Matsubara: "A New Photosynthetic System in Mushroom" Nature. to be published. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Kano, T.Sugimoto, Y.Misaki, Z.Yoshida: "Novel Redox Behavior of [5] Radialenes Substituted with 1,3-Dithiol Groups" J.Phy.Chem.95. 252 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Matsubara, K.Kitano, M.Yoshihara, T.Maeshima: "Crystal and Molecular Structure of 2-Ethylthio 3-Phenyl-1,3,4-Thiadiazolium Tetrafluororate" Bull.Chem.Soc.Jpn.66. 3525 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Matsubara, K.Kitano, M.Yoshihara, T.Maeshima: "A Novel Method for Preparation of 5,5' -Substituted-4-Phenyl-4H-1,3,4-Thiadiazoles Using Triethysilyl Chloride" Chem.Pharm.Bull.42. 373 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Matsubara, K.Kitano, M.Yoshihara, T.Maeshima: "Preparation of 2,3-Dihydro-3-Phenyl-1,3,4-Thiadiazoles" Chem.Pharm.Bull.42. 1912 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Takekuma, H.Takekuma, Y.Matsubara, H.Yamamoto, Y.Nozoe: "The Crystal Structure of 1,7-Guaiazulenequinone and the Structures of Two New 1,7-Guaiazulenequinone Derivative" Chem.Lett.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Maekawa, M.Munakata, T.Kuroda-Sowa, K.Hachiya: " Synthesis and Crystal Structure of Tetranuclear Nickel (0) Complex with 1,4-Diphenylbutadiyne in the eta^2, eta^2-Bridging Mode" Inorg.Chem.Acta. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1996-04-15  

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