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1994 Fiscal Year Final Research Report Summary

Development of Charge-up Free lon lmplantation by Using Negative lon Beam

Research Project

Project/Area Number 05555008
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 表面界面物性
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

ISHIKAWA Junzo  Kyoto University, Electronics, Professor, 工学部, 教授 (80026278)

Co-Investigator(Kenkyū-buntansha) SAKAI Shigeki  Nissin Electric Co., Ltd., R&D Head Office, Researcher, 研究開発本部, 研究員
MATSUDA Kouji  Nissin Electric Co., Ltd., R&D Head Office, Vice-Head Director, 研究開発本部, 副本部長
GOTOH Yasuhito  Kyoto University, Electronics, Assistant, 工学部, 助手 (00225666)
TSUJI Hiroshi  Kyoto University, Electronics, Assistant, 工学部, 助手 (20127103)
Project Period (FY) 1993 – 1994
KeywordsNegative-Ion Implantation / Charge-up / Reduction of Charging / Secondary Electron Emission Yield / Electron Energy Distribution / Negative-Ion Source / Negative-Ion Beam Transport / Gate Oxide Layr
Research Abstract

This research has been accomplished with following results : (1) It was found that negative-ion implantation makes it remarkably low the charge-up voltage of the implanted surface, and (2) the large possibillity was obtained to put the negative-ion implantation to practical use in the LSI fabrication process and as a charge-up free ion implantation technique. Five main subjects of the research and obtained results are described as follows.
1.Development of High Current Negative Ion Source for Negative-Ion Implantation
RF plamsa-sputter-type heavy negative-ion source has been developed which was able to deliver several mA negative-ion current of boron, phosphorus and silicon elements desired in negative-ion implantation for the semiconductor fabrication process.
2.Development of the Mesuring System of Charg-up Potential of Insulators during Negative-Ion Implantation
The method for measuring charge-up potential of insulators during implantation has been developed by using secondary-electron- … More energy analysis. Charge-up potential of negative-ion implantated insulators was revealed to be within only several volts of negative-polarity.
3.Analytical Research of Charging Mechanism in Negative-Ion Implantation
The charging mechanism of isolated electrode during negative-ion implantation has been revealed, where the charging voltage was determined by two factors of secondary-electron-emission yield and electron-energy distribution. As for the insulators, the charging mechanism of insulators is not made clear yet, but we have presented a model of electric-double-layr formed in near surface of insulator.
4.Development of Negative-Ion Beam Transport System for a Large Area Implantation
For negative-ion implanter, the beam transport system has been developed for a large silicon substrate of 6 inch in diameter.
5.Evaluation of Negative-Ion Implanted Device
The test devices (TEG : test element group) for testing gate oxide layr were implanted with negative-ion beam, and as a result, almost all devices performed well after the negative-ion implantation without any external apparatus for charge-up compensation. Less

  • Research Products

    (78 results)

All Other

All Publications (78 results)

  • [Publications] Junzo.Ishikawa: "Carbon Negative-Ion Implantation into Silicon" Nuclear Instruments and Methods in Physics Research B. B74. 118-122 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Shigeki Sakai,: "Comparison of Charge-up Phenomena between Negative-and Positive-Ion Implantation" Ion Implantation 92 (Elsevier Science Publisher BV). 617-620 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Ishikawa: "Diamond-Like Carbon Films Prepared by Carbon Negative-Ion Beam Deposition" Proceedings of the Third International Symposium on Diamond Materials (The Electrochemical Socity, Pennington, USA). 93-17m. 969-978 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Ishikawa: "Radio Frequency Plasma Sputter-Type Heavy Negative Ion Source" Vacuum. 44. 203-207 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石川順三: "粒子線による原子間結合制御技術" 真空. 36. 833-839 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 酒井滋樹: "絶縁性基板への負イオン注入によるチャージアップの軽減" 真空. 36. 889-892 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石川順三: "極低エネルギーイオンビームによる薄膜形成" 応用物理. 62. 1190-1199 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石川順三: "粒子線技術における運動力結合の重要性" 第4回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1993. BEAMS1993. 1-10 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻博司: "RFプラズマスパッタ型負重イオン源からのmA級Si^-およびB^-負イオン引き出し特性" 第4回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1993. BEAMS1993. 71-74 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻博司: "負イオン注入における絶縁Si基板表面電位の電流密度依存症" 第4回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1993. BEAMS1993. 75-79 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻博司: "二次電子エネルギー分析による負イオン注入時の絶縁物基板帯電測定" 第4回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1993. BEAMS1993. 79-82 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Ishikawa: "Measurement of Heavy Negative Ion Production Probabilities by Sputtering" Proceedings of the 6 th International Symposium on Production and Neutalization of Negative Ions and Beams Amirican Institute of Physics Conf.Proc. No.287; Particlss and Fields 53. AIP Conf.287. 66-75 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hiroshi Tsuji: "RF Plasma Sputter-Type DC-Mode Heavy Negative Ion Source" Proceedings of the 6 th International Symposium on Production and Neutalization of Negative Ions and Beams Amirican Institute of Physics Conf.Proc. No.287; Particlss and Fields 53. AIP Conf.287. 530-539 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Isikawa: "Negative-Ion Source for Implantation and Surface Interaction of Negative-Ion Beams(Invited)" Review of Scientific Instruments. 65. 1290-1294 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Isikawa: "Application of Negative-Ion Beams" Surface and Coating Technology. 65. 64-70 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hirishi Tsuji: "Negative-Ion Production Probability in RF Plasma-Sputter-Type Heavy Negative-Ion Source" Review of Scientific Instruments. Vol.65. 1732-1736 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石川順三: "負イオンビーム技術とその物性応用" アイオニクス. 20. 1-18 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "スパッタリングを用いた二次負イオン放出における負重イオン生成効率の測定" アイオニクス. 20. 19-27 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "連続動作大電流スパッタ型負重イオン源の開発" アイオニクス. 20. 29-39 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "負重イオンビームの電子離脱断面積と二次電子放出比" アイオニクス. 20. 41-50 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "シリコンへの炭素負イオン注入によるSiC層の形成" アイオニクス. 20. 51-56 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "負イオン注入による絶縁電極の帯電電位測定" アイオニクス. 20. 57-64 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 酒井滋樹: "負イオン注入による絶縁された電極の帯電メカニズム解明" アイオニクス. 20. 65-69 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "絶縁物への負イオン注入における表面電位のイオン誘起二次電子分析による測定" アイオニクス. 20. 71-76 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "負イオン注入における絶縁した電極表面の帯電電位のイオン電流密度依存性" 真空. 37. 135-138 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "イオン誘起二次電子による負イオン注入時の絶縁物基板の帯電測定" 真空. 37. 139-142 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 酒井滋樹: "200kV中電流負イオン注入装置の開発" 第5回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1994. BEAMS1994. 23-26 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "粉末へのイオン注入による粒子飛散の基礎現象" 第5回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1994. BEAMS1994. 185-188 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻博司: "負イオン注入における孤立電極の帯電電位モデルととその実験的検証" 第5回粒子線の先端的応用技術に関するシンポジウム論文集 BEAMS1994. BEAMS1994. 209-212 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Ishikawa: "Negative-Ion Implantation Technique(Invited)" Nuclear Instruments and Methods B. (to be published). 6 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Shigeki Sakai: "The Charging Mechanism of Insulated Electrode in Negative-Ion Implantation" Nuclear Instruments and Methods B. (to be published). 5 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hiroshi Tsuji: "High-Current RF-Plasma-Sputter-Type Heavyrode in Negative-Ion Source for Negative-Ion Implanter" Ion Implantation Technology 94. (to be published by North-Holland Publisher Inc). 4 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hirishi Tsuji: "Charging Voltage Measurement of an Isolated EIectrpde and Insulators during Negative-Ion Implantation" Ion Implantation Technology 94. (to be published by North-Holland Publisher Inc). 4 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "RFプラズマスパッタ型負重イオン源におけるガス物質の負イオン引き出し" 第4回負イオン源及び負イオンビームとその応用研究会論文集, NIFS Report1995. (to be published). 5 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "高周波プラズマスパッタ型負重イオン源における気体材料の負イオン生成" 真空. 38(to be published). 5 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "イオン誘起二次電子分析による負イオン注入時のレジスト膜の帯電測定" 真空. 38(to be published). 4 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 博司: "負イオン注入における基板帯電モデルとその評価" 真空. 38(to be published). 4 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 酒井滋樹: "微細周期構造にイオン注入したときのチャージアップシミュレーション" 真空. 38(to be published). 4 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Junzo Ishikawa: "Carbon Negative-Ion Implantation into Silicon" Nuclear Instruments and Methods in Physics Research B. Vol.B74. 118-122 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "Comparison of Charge-up Phenomena between Negative- and Positive-Ion Implantation" Ion Implantation 92 (Elsevier Science Publisher BV). 617-620 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Diamond-Like Carbon Films Prepared by Carbon Negative-Ion Beam Deposition" Proceedings of the Third International Symposium on Diamond Materials, 93-17m, (The Electrochemical Society, USA). 969-978 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Radio Frequency Plasma Sputter-Type Heavy Negative Ion Source" Vacuum. Vol.44. 203-207 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Control Technique of Atomic Bonding by Using Particle Beams" Journal of The Vacuum Society of Japan (in Japanese). Vol.36. 833-839 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "Charge-up Reduction of Insulated Substrate by using Negative-Ion Implantation" Journal of The Vacuum Society of Japan (in Japanese). Vol.36. 889-892 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Thin Film Formation by using Ultra-Low Energy Ion Beams" Ouyou Butsuri (in Japanese), (The Japan Society of Applied Physics). Vol.62. 1190-1199 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Importance of "Kinetic Bonding" Process in Beam Engineering" Proceedings of the Forth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1993. 1-10 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Milliampere Class Si- or B- Negative Ion Extraction from RF Plasma-Sputter-Type Heavy Negative-Ion Source" Proceedings of the Forth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1993. 71-74 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Surface Potential versus Current Density Characteristics in Negative-Ion Implantation into Insulated Silicon Substrate" Proceedings of the Forth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1993. 75-78 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of Insulators in Negative-Ion Implantation" Proceedings of the Forth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1993. 79-82 (1933)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "Simulation of Charging Phenomena in Ion Implatation in to the Micro Structure Pattern" Proceedings of the Forth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1993. 83-86 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Diamond-Like Amorphous Carbon Films Prepared by Carbon Negative-Ion Beam Deposition" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.l. 77-83 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Negative-Ion Current Density Depoendence of the, Surface Potential of Insulated Electrode during Negative-Ion Implantation" Journal of The Vacuum Society of Japan (in Japanese). Vol.37. 135-138 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of the Insulator with Secondary Electron Caused by Negative-Ion Implantation" Journal of The Vacuum Society of Japan (in Japanese). Vol.37. 139-142 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "Development of 200kV Medium Current Negative-Ion Implanter" Proceedings of the Fifth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1994. 23-26 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Fundamental Study on Powder Scattering during Ion Implantation" Proceedings of the Fifth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1994. 185-188 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Charging Voltage Model and Its Experimental Evaluation of Isolated Electrode in Negative-Ion Implantation" Proceedings of the Fifth Symposium on Beam Engineering of Advanced Material Syntheses, (in Japanese). BEAMS1994. 209-212 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikwa: "Negative-Ion Implantation Technique (Invited)" Nuclear Instruments and Methods in Physics Research B. (to be published)6 pages, 1995.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "The Charging Mechanism of Insulated Electrode in Negative-Ion Implantation" Nuclear Instruments and Methods in Physics Research B. (to be published). 5 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "High-Current RF-Plasma-Sputter-Type Heavyrode in Negative-Ion Source for Negative-Ion Implanter" Ion Implantation Technology 94. (to be published by North-Holland Inc). 4 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Charging Voltage Measurement of an Isolated Electrpde and Insulators during Negative-Ion Implantation" Ion Implantation Technology 94. (to be published by North-Holland Inc). 4 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Negative-Ion Beam Extraction Propety of Gas Materials from RF Plasma-Sputter-Tire Heavy Negative Ion Source" NIFS Report (National Institute for Fusion Science, in Japanese). NIFS Report 1995. 5 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Negative-Ion Production of Gas Material in RF Plasma-Sputter-Tire Heavy Negative-Ion Source" Journal of The Vacuum Society of Japan (in Japanese). Vol.38 (to be published). 5 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Measurement of Heavy Negative Ion Production Probabilities by Sputtering" Proceedings of the 6 th International Symposium on Production and Neutalization of Negative Ion and Beams AIP Conf.Proc.No.287. 66-75 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "RF Plasma Sputter-Type DC-Mode Heavy Negative Ion Source" Proceedings of the 6 th International Symposium on Production and Neutalization of Negative Ion and Beams AIP Conf.Proc.No.287. 530-539 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Negative-Ion Source for Implantation and Surface Interaction of Negative-Ion Beams (Invited)" Review of Scientific Instruments. Vol.65. 1290-1294 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Application of Negative-Ion Beams" Surface and Coating Technology. Vol.65. 64-70 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Negative-Ion Production Probability in RF Plasma-Sputter-Type Heavy Negative-Ion Source" Review of Scientific Instruments. Vol.65. 1732-1736 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Junzo Ishikawa: "Negative-Ion Beam Technology and Its Application to Materials Science" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 1-18 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Measurement of Heavy Negative Ion Production Efficiencies in Secondary Negative Ion Emission by Sputtering" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 19-27 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Development of Intense Sputter-Type Heavy Negative-Ion Sources in DC Operation" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 29-39 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Electron Detachment Cross-Sections and Secondary-Electron Emission Factors for Heavy Negative-Ion Beams" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 41-50 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "SiC Formation by Carbon Negative-Ion Implantation into Silicon Substrate" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 51-56 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of Insulated Electrode by Negative-Ion Implantation" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 57-64 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "The Charging Measurement of Insulated Electrode in Negative-Ion Implantation" Ionics (Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 65-69 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of Negative-Ion-Implanted Insulators by Analysing Secondary Electron Energy Distribution" Ionics(Journal of Ion Science and Technology, in Japanese). Vol.20, No.1. 71-76 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Charging Potential Measurement of Photoresist-Layr Surface during Negative-Ion Implantation form Ion-Induced Secondary Electron Energy Analysis" Journal of The Vacuum Society of Japan (in Japanese). Vol.38 (to be published). 4 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Tsuji: "Evaluation of Charging Modei in Negative-Ion Implantation" Journal of The Vacuum Society of Japan(in Japanese). Vol.38 (to be published). 4 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeki Sakai: "Charg-up Simulation of Ion Implanted Periodic Micro Structure Pattern" Journal of The Vacuum Society of Japan (in Japanese). Vol.38 (to be published). 4 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1996-04-15  

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