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1996 Fiscal Year Final Research Report Summary

Design of Reactions in Crystals

Research Project

Project/Area Number 06242104
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionEhime University

Principal Investigator

TODA Fumio  Ehime University, Applied Chemistry, Professor, 工学部, 教授 (50036232)

Co-Investigator(Kenkyū-buntansha) TANAKA Koichi  Ehime University, Applied Chemistry, Assistant Professor, 工学部, 助教授 (10116949)
KAI Yasushi  Osaka University, Applied Chemistry, Professor, 工学部, 教授 (40029236)
OKAMOTO Yoshio  Nagoya University, Applied Chemistry, Professor, 工学部, 教授 (60029501)
OHASHI Yuji  Tokyo Institute of Technology, Chemistry, Professor, 理学部, 教授 (40016118)
Project Period (FY) 1994 – 1997
Keywordsorganic solid state chemistry / solid state reaction / enantioselective reaction / crystal chemistry / molecular movement in crystal / solid state photoreaction
Research Abstract

During the research period, 1994-1996, two symposiums were held a year. In some symposiums, special guest speakers were invited to give lectures. In some cases, we organized panel discussions on topics. In order to announce widely these symposiums and panel discussions, news letters including programs and abstracts of these events have been published at least twice a year. In these news letters, research results of all members, papers, reviews and books, have been printed. In final year 1996, all research results cumulated through three years were published in a news letter.
We also checked carefully the application form of the research grant presented by many applicants every year, and adopted some good proposals. Our research group is consisted of three research groups. We made many efforts to be able to collaborate efficiently each other among these groups. Through many collaboration works among these research groups, very many fruitful research results were produced and published as papers, reviews and books.

  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] F.Toda,H.Liu,I.Miyahara and K.Hirotsu: "Design of new host compounds,1,1-bis(diarylhydroxymethyl)ferrocenes" J.Chem.Soc.,Perkin Trans.2. 85-88 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Toda,H.Miyamoto,S.Kikuchi,R.Kuroda and F.Nagami: "Enantioselective Photocyclization of 2-Arythio-3-methylcyclohexen-1-ones to Dihydro-benzothiophene Derivatives in an Inclusion Crystal with an Optically Active Host" J.Am.Chem.Soc.118. 11315-11316 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.Kaupp,J.Schmeyers,F.Toda,H.Takumi and H.Koshima: "Mechanism of Solid-Solid Resolution of Pantolactone" J.Phys.Org.Chem.9. 795-800 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.R.Caira,A.Coetzee,L.R.Nassimbeni and F.Toda: "Inclusion of Dioxolane by a Tricyclic Diol Host:Structure and Kinetics" J.Chem.Research(s). 280-281 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Toda,H.Takumi and K.Tanaka: "A Simple Preparative Method for Optically Active Glycidic Esters" Tetrahedron:Asymmetry. 6・5. 1059-1062 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Toda and N.Imai: "Ylide Reaction in the Solid State:a simple procedure for the Synthesis of Cyclopropanes,Oxiranes and Aziridines" J.Chem.Soc.,Perkin Trans.1. 2673-2674 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Fumio Toda: "Comprehensive Supramolecular Chemistry:Volume 6,Solid-State Supramolecular Chemistry:Crystal Engineering,"Diol,Bisphenol,and Diamide Host Compounds"" Pergamon, 966 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Tanaka and F.Toda: "Comprehensive Supramolecular Chemistry:Volume 6,Solid-State Supramolecular Chemistry:Crystal Engineering,"Onium Salt Hosts"" Pergamon, 966 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Toda, H.Liu, I.Miyahara and K.Hirotsu: "Design of new host compounds, 1,1-bis (diarylhydroxymethyl) ferrocenes" J.Chem.Soc., Perkin Trans.2. 85-88 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F.Toda, H.Miyamoto, S.Kikuchi, R.Kuroda and F.Nagami: "Enantioselective Photocyclization of 2-Arylthio-3-methylcyclohexen-1-ones to Dihydrobenzothiophene Derivatives in an Inclusion Crystal with an Optically Active Host" J.Am.Chem.Soc.118. 11315-11316 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] G.Kaupp, J.Schmeyers, F.Toda, H.Takumi and H.Koshima: "Mechanism of Solid-Solid Resolution of Pantolactone" J.Phys.Org.Chem.9. 795-800 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.R.Caira, A.Coetzee, L.R.Nassimbeni and F.Toda: "Inclusion of Dioxolane by a Tricyclic Diol Host : Structure and Kinetics" J.Chem.Research (s). 280-281 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F.Toda, H.Takumi and K.Tanaka: "A Simple Preparative Method for Optically Active Glycidic Esters" Tetrahedron : Asymmetry. 6 (5). 1059-1062 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] F.Toda and N.Imai: "Ylide Reaction in the Solid State : a simple procedure for the Synthesis of Cyclopropanes, Oxiranes and Aziridines" J.Chem.Soc., Perkin Trans.1. 2673-2674 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Fimio Toda: Diol, Bisphenol, and Diamide Host Compounds in "Comprehensive Supramolecular Chemistry : Volume 6, Solid-State Supramolecular Chemistry : Crystal Engineering". Pergamon, 465-516 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Tanaka and F.Toda: Onium Salt Hosts in "Comprehensive Supramolecular Chemistry : Volume 6, Solid-State Supramolecular Chemistry : Crystal Engineering". Pergamon, 517-534 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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