1995 Fiscal Year Annual Research Report

金属錯体における立体化学の新しい展開

Research Project

Project/Area Number	06303004
Research Institution	Okazaki National Research Institute
Principal Investigator	吉川雄三岡崎国立共同研究機構, 分子科学研究所, 教授 (30022643)
Co-Investigator(Kenkyū-buntansha)	中村晃大阪大学, 理学部, 教授 (80029404) 安井隆次高知大学, 理学部, 教授 (20028161) 宇津野峻司静岡大学, 理学部, 教授 (40021935) 福田豊お茶の水女子大学, 理学部, 教授 (30021950) 海崎純男大阪大学, 理学部, 教授 (20089874)
Keywords	金属錯体 / 立体化学 / 機能性 / 立体規制 / 酵素モデル
Research Abstract	最終年度である今年度は、7月22〜23日にセミナーを開催し、「錯体化学とは?錯体化学研究所はいかにあるべきか」についてディスカッションを行い錯体化学における研究推進への意識を高めることができた。 11月21、22日には研究発表のかたちでシンポジウムを開催し、班員それぞれの2年間にわたる研究成果が示され、全体で討議した。それらの研究主題を分担者名と共に以下に列挙する。「複核錯体の配位立体構造制御とサーモクロミズム」(福田豊)、「非プロトン性極性溶媒中でのクロム(III)アミノ酸錯体の異性化」(沖久也)、「複数のキラル中心を有する金属化合物の立体化学的研究」(岡本健一)、「7配位チタン(III)-edta及び-eddadp錯体の構造」(三吉克彦)、「遷移金属とリン間に二重結合をもつ錯体の合成・構造・反応性」(中沢浩)、「直線型マンガン三核錯体の合成および性質」(吉川雄三)、「異節縮合環をキレート環とする遷移金属錯体の合成と反応性」(後藤正文)、「シッフ塩基銅(II)錯体のジアステレオ異性体単離と結晶構造」(久司佳彦)、「四置換フタロシアニンの構造異性体の選択的合成と特性」(春日邦宣)、「高歪亜鉛錯体の配位立体化学と反応性」(藤井有起)、「二核鉄(III)/酸化水素系におけるアルカン類の酸素化反応における立体化学的効果」(西田雄三)、「軸性キラリティーを有する金属錯体」(仲野義晴)、「アンミンニトロコバルト(III)錯体におけるアトロプ異性現象」(宇津野峻司)、「光照射によるコバルト(III)錯体の脱硫黄反応」(小島正明)、「キラルな含硫錯体の光異性化と多核化反応について」(安井隆次)、「光学活性硫黄架橋クラスター錯体」(柴原隆志)、「二核錯体における分子内相互作用と立体化学」(海崎純男)、「直線型に結合した混合金属四核錯体の合成と構造」(中村晃). これらの詳細は、研究発表要旨(集)および各々の発表論文により知ることができる。

Research Products

(34 results)

All Other

All Publications (34 results)

[Publications] M.Kojima: "Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base-Oxovanadium(IV)Complex and Interconversion between These Species" Proc.Japan Academy. B71. 175-178 (1995)
[Publications] M.Hirotsu: "Manganese(III)Complexes Containing Optically Active Tetradentate Schiff Base Ligands.Effect of Phenyl Substituents" Inorg.Chem.34. 6173-6178 (1995)
[Publications] K.Nakajima: "Chiral Recognition in the Electron-Transfer Reaction between Optically Active Schiff Base-Oxovanadium(IV)and-Oxovanadium(V)Complexes" Chem.Lett.1995. 1017-1018 (1995)
[Publications] F.MD.Akhter: "Photochemistry of Cobalt(III)Complexes Containing a Sulfinate-S Ligand,Linkage and Geometrical Isomerization" Bull.Chem.Soc.Jpn.,. 69(in press).
[Publications] F.Jalilehvand: "Copper(II)Mixed Ligand Complex with an N-Alkylated Diamine and a New β-Diketonate" Chem.Lett.1995. 743-744 (1995)
[Publications] K.Harada: "d-f Interaction through Fe-CN-Ln Bridging between Dicyanobis-(1,10-phenanthroline)iron(II)Complex and LnCl_321GC06:Chem.Lett." 1995. 887-889 (1995)
[Publications] T.Fujihara: "New Hetero-and Homometallic Dihydroxo-Bridged Dinuclear Complexes of Cobalt(III)and Chromium(III):Synthesis,Spectroscopy and Crystal Structures" J.Chem.Soc.,Dalton Trans.1995. 1813-1821 (1995)
[Publications] T.Fujihara: "Base Hydrolysis in Homometallic Dinuclear Chromium(III)Complexs Bridged by Hydroxide and Carboxylate" J.Chem.Soc.,Dalton Trans.1995. 1823-1831 (1995)
[Publications] S.Utsu: "Solid-State Circular Dichroism Spectra of trans-Diamminetetranitrocobaltate(III)Salts and mer-Trinitrotriamminecobalt(III)" Inorg.Chim.Acta,. (in press(1996)).
[Publications] T.Yamada: "Substitutions of Tris(2,2'-bipyridine)cobalt(III)by Carbonate Ion" J.Coord.Chem.,. (in press(1996)).
[Publications] Y.Fujiii: "Effect of Triamine Ligands(L)on the Acidity of L-Zn-OH_2 as a Model Compound of CA and AP" Chem.Lett.1995. 305-306 (1995)
[Publications] R.Nakata: "Application of Numerical Integration and Least-squares Metod with Simplex Optimization to the Evalution of Rate constats in the Sterochemical Rearrangement Reaction Svstem of(L-isoleucinato)chromiun(III)Complexes" J.Chem.Software. 2. 149-158 (1995)
[Publications] Y.Nishida: "Iron(III)Compounds with Hydrogen Peroxide Which Can Descriminate Two Reaction Types;Oxidation and Oxygenation Reactions" Z.Naturforsch. 50C. 205-208 (1995)
[Publications] Y.Nishida: "Novel Reactivity of Dioxygen Molecule in the Presence of a Manganese(II)Complex and Reducing Agents" Inorg.Chem.34. 3616-3620 (1995)
[Publications] M.Handa: "Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III)Complex" Bull.Chem.Soc.Jpn.68. 1647-1653 (1995)
[Publications] K.Kasuga: "Photoreduction of Methylviologen Catalysed by Tri-or Tetra Sulphophthalocyaninatozinc(II)in Aqueous Solutions" Polyhedron. 14. 1675-1679 (1995)
[Publications] K.Kanamori: "Preperation and Structure of Dinuclear Vanadium(III)Complexes Triply Bridged by Three Different Groups" Chem.Lett.1995. 105-106 (1995)
[Publications] T.Konno: "Novel S-Bridged Tetranuclear Cobalt Complexes with 2-Aminoethanethiolate Formed by Ligand Transfer from Nickel(II)to Cobalt(III)" Chem.Lett.1995. 675-676 (1995)
[Publications] K.Kanamori: "Syntheses Characterization and Properties of Vanadium(III)Complexes Containing Tripodal Tetradentate Ligands with Single Pyridyl Groups" Bull.Chem.Soc.Jpn.68. 2581-2589 (1995)
[Publications] M.Handa: "Linear Chain Compounds of Molybdenum(II)Acetate Linked by Pyradine" Bull.Chem.Soc.Jpn.68. 2567-2572 (1995)
[Publications] K.Kasuga: "Reaction of Carbon Dioxide with Tetra-t-butylphthalocyaninatoaluminium(III)-ethylate or -ethoxide" Inorg.Chim.Acta. 244. 137-139 (1996)
[Publications] T.Mizuta: "Steric Trans Influence of Aminomethane Ligand in trans-Aminomethane-chlorobis(1,2-diaminoethane)cobalt(III)" Bull.Chem.Soc.Jpn.68. 2263-2269 (1995)
[Publications] T.Mizuta: "P-C Bond Cleavage of Phosphorus-Bridged[1]Ferrocenophane Coordinating to [Cp(CO)_2Fe]_+ Fragment" Organometallics,. (in press(1996)).
[Publications] K.Kashiwabara: "Crystal Structure of Cobalt(III)-Methyldiphenylphosphine Complexes Co(III)-P Bound Lengths and Their Cleavages" Bull.Chem.Soc.Jpn.68. 883-888 (1995)
[Publications] K.Kashiwabara: "Synthesis and Crystal Structure of Bis(1,1,1-tris(dimethylphosphinom ethyl)ethane)iron(II)Tetrafluoroborate Dihydrate" Bull.Chem.Soc.Jpn.68. 3453-3457 (1995)
[Publications] H.Kurosaki: "The First Trigonal-bipyramidal Structure of Zinc(II)Complex of a Bleomycin Model" Chem.Lett.1995. 691-692 (1995)
[Publications] M.Haga: "Self-assembled Dinuclear Platinum(II)Complexes with 6,6-bis(1-methylbenzimidazol-2-yl)-2,2'-bipyridine Synthesis,X-Ray Structure and Solution Benaviors" Chem.Lett.1995. 1143-1144 (1995)
[Publications] T.Daniel: "Norbornadiene(bipyridyl)molybdenum(II)Complexes:Synthesis,Structure and Reactivity of [Mo(CO)(C_7H_8)(C_<10>H_6R_2N_2)X_2](X=1,Br)" Chem.Ber.128. 1007-1013 (1995)
[Publications] H.Oku: "Thiolato-Activated Oxo-Metal Bond Features in Molybdenum and Tungsten Oxidoreductase Models As Revealed by Raman Spectroscopy" Inorg.Chem. 34. 3667-3676 (1995)
[Publications] S.Okeya: "Di-,Tri-,and Tetra nucear Palladium(II)Complexes with Ureido Bridging Groups" J.Chem.Soc.,Chem.Commun.1995. 2123-2124 (1995)
[Publications] G.Sakane: "The Hexagonal Prism Shaped Cluster W_2Ag_4S_8(AsPh_3)_4:Synthesis, crystal Structure,and Non Linear Optical Properties" Inorg.Chem.34. 4785-4786 (1995)
[Publications] T.Kawamoto: "Pd…H-C Interaction Preparation and Structure of Orthometallated Tetranuclear Complexes of Palladium(II)and Platium(II)" Inorg.Chem.,. (in press(1996)).
[Publications] G.Sakane: "Discrete Variational (DV)-Xq Calculations of Incomplete Cubane-Type Molybdenum Clusters[Mo_3X_4(H_2O)_9]^<4+>(X=O,S)" J.Cluster Science. 6. 503-521 (1995)
[Publications] 春日邦宣: "Phthalocyanines" C.C Leznoff,A.B.P.Lever(VCH), 10 (1996)

1995 Fiscal Year Annual Research Report

金属錯体における立体化学の新しい展開

Principal Investigator

吉川 雄三 岡崎国立共同研究機構, 分子科学研究所, 教授 (30022643)

Research Products

[Publications] M.Kojima: "Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base-Oxovanadium(IV)Complex and Interconversion between These Species" Proc.Japan Academy. B71. 175-178 (1995)

[Publications] M.Hirotsu: "Manganese(III)Complexes Containing Optically Active Tetradentate Schiff Base Ligands.Effect of Phenyl Substituents" Inorg.Chem.34. 6173-6178 (1995)

[Publications] K.Nakajima: "Chiral Recognition in the Electron-Transfer Reaction between Optically Active Schiff Base-Oxovanadium(IV)and-Oxovanadium(V)Complexes" Chem.Lett.1995. 1017-1018 (1995)

[Publications] F.MD.Akhter: "Photochemistry of Cobalt(III)Complexes Containing a Sulfinate-S Ligand,Linkage and Geometrical Isomerization" Bull.Chem.Soc.Jpn.,. 69(in press).

[Publications] F.Jalilehvand: "Copper(II)Mixed Ligand Complex with an N-Alkylated Diamine and a New β-Diketonate" Chem.Lett.1995. 743-744 (1995)

[Publications] K.Harada: "d-f Interaction through Fe-CN-Ln Bridging between Dicyanobis-(1,10-phenanthroline)iron(II)Complex and LnCl_321GC06:Chem.Lett." 1995. 887-889 (1995)

[Publications] T.Fujihara: "New Hetero-and Homometallic Dihydroxo-Bridged Dinuclear Complexes of Cobalt(III)and Chromium(III):Synthesis,Spectroscopy and Crystal Structures" J.Chem.Soc.,Dalton Trans.1995. 1813-1821 (1995)

[Publications] T.Fujihara: "Base Hydrolysis in Homometallic Dinuclear Chromium(III)Complexs Bridged by Hydroxide and Carboxylate" J.Chem.Soc.,Dalton Trans.1995. 1823-1831 (1995)

[Publications] S.Utsu: "Solid-State Circular Dichroism Spectra of trans-Diamminetetranitrocobaltate(III)Salts and mer-Trinitrotriamminecobalt(III)" Inorg.Chim.Acta,. (in press(1996)).

[Publications] T.Yamada: "Substitutions of Tris(2,2'-bipyridine)cobalt(III)by Carbonate Ion" J.Coord.Chem.,. (in press(1996)).

[Publications] Y.Fujiii: "Effect of Triamine Ligands(L)on the Acidity of L-Zn-OH_2 as a Model Compound of CA and AP" Chem.Lett.1995. 305-306 (1995)

[Publications] R.Nakata: "Application of Numerical Integration and Least-squares Metod with Simplex Optimization to the Evalution of Rate constats in the Sterochemical Rearrangement Reaction Svstem of(L-isoleucinato)chromiun(III)Complexes" J.Chem.Software. 2. 149-158 (1995)

[Publications] Y.Nishida: "Iron(III)Compounds with Hydrogen Peroxide Which Can Descriminate Two Reaction Types;Oxidation and Oxygenation Reactions" Z.Naturforsch. 50C. 205-208 (1995)

[Publications] Y.Nishida: "Novel Reactivity of Dioxygen Molecule in the Presence of a Manganese(II)Complex and Reducing Agents" Inorg.Chem.34. 3616-3620 (1995)

[Publications] M.Handa: "Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III)Complex" Bull.Chem.Soc.Jpn.68. 1647-1653 (1995)

[Publications] K.Kasuga: "Photoreduction of Methylviologen Catalysed by Tri-or Tetra Sulphophthalocyaninatozinc(II)in Aqueous Solutions" Polyhedron. 14. 1675-1679 (1995)

[Publications] K.Kanamori: "Preperation and Structure of Dinuclear Vanadium(III)Complexes Triply Bridged by Three Different Groups" Chem.Lett.1995. 105-106 (1995)

[Publications] T.Konno: "Novel S-Bridged Tetranuclear Cobalt Complexes with 2-Aminoethanethiolate Formed by Ligand Transfer from Nickel(II)to Cobalt(III)" Chem.Lett.1995. 675-676 (1995)

[Publications] K.Kanamori: "Syntheses Characterization and Properties of Vanadium(III)Complexes Containing Tripodal Tetradentate Ligands with Single Pyridyl Groups" Bull.Chem.Soc.Jpn.68. 2581-2589 (1995)

[Publications] M.Handa: "Linear Chain Compounds of Molybdenum(II)Acetate Linked by Pyradine" Bull.Chem.Soc.Jpn.68. 2567-2572 (1995)

[Publications] K.Kasuga: "Reaction of Carbon Dioxide with Tetra-t-butylphthalocyaninatoaluminium(III)-ethylate or -ethoxide" Inorg.Chim.Acta. 244. 137-139 (1996)

[Publications] T.Mizuta: "Steric Trans Influence of Aminomethane Ligand in trans-Aminomethane-chlorobis(1,2-diaminoethane)cobalt(III)" Bull.Chem.Soc.Jpn.68. 2263-2269 (1995)

[Publications] T.Mizuta: "P-C Bond Cleavage of Phosphorus-Bridged[1]Ferrocenophane Coordinating to [Cp(CO)_2Fe]_+ Fragment" Organometallics,. (in press(1996)).

[Publications] K.Kashiwabara: "Crystal Structure of Cobalt(III)-Methyldiphenylphosphine Complexes Co(III)-P Bound Lengths and Their Cleavages" Bull.Chem.Soc.Jpn.68. 883-888 (1995)

[Publications] K.Kashiwabara: "Synthesis and Crystal Structure of Bis(1,1,1-tris(dimethylphosphinom ethyl)ethane)iron(II)Tetrafluoroborate Dihydrate" Bull.Chem.Soc.Jpn.68. 3453-3457 (1995)

[Publications] H.Kurosaki: "The First Trigonal-bipyramidal Structure of Zinc(II)Complex of a Bleomycin Model" Chem.Lett.1995. 691-692 (1995)

[Publications] M.Haga: "Self-assembled Dinuclear Platinum(II)Complexes with 6,6-bis(1-methylbenzimidazol-2-yl)-2,2'-bipyridine Synthesis,X-Ray Structure and Solution Benaviors" Chem.Lett.1995. 1143-1144 (1995)

[Publications] T.Daniel: "Norbornadiene(bipyridyl)molybdenum(II)Complexes:Synthesis,Structure and Reactivity of [Mo(CO)(C_7H_8)(C_<10>H_6R_2N_2)X_2](X=1,Br)" Chem.Ber.128. 1007-1013 (1995)

[Publications] H.Oku: "Thiolato-Activated Oxo-Metal Bond Features in Molybdenum and Tungsten Oxidoreductase Models As Revealed by Raman Spectroscopy" Inorg.Chem. 34. 3667-3676 (1995)

[Publications] S.Okeya: "Di-,Tri-,and Tetra nucear Palladium(II)Complexes with Ureido Bridging Groups" J.Chem.Soc.,Chem.Commun.1995. 2123-2124 (1995)

[Publications] G.Sakane: "The Hexagonal Prism Shaped Cluster W_2Ag_4S_8(AsPh_3)_4:Synthesis, crystal Structure,and Non Linear Optical Properties" Inorg.Chem.34. 4785-4786 (1995)

[Publications] T.Kawamoto: "Pd…H-C Interaction Preparation and Structure of Orthometallated Tetranuclear Complexes of Palladium(II)and Platium(II)" Inorg.Chem.,. (in press(1996)).

[Publications] G.Sakane: "Discrete Variational (DV)-Xq Calculations of Incomplete Cubane-Type Molybdenum Clusters[Mo_3X_4(H_2O)_9]^<4+>(X=O,S)" J.Cluster Science. 6. 503-521 (1995)

[Publications] 春日邦宣: "Phthalocyanines" C.C Leznoff,A.B.P.Lever(VCH), 10 (1996)

吉川雄三岡崎国立共同研究機構, 分子科学研究所, 教授 (30022643)