1994 Fiscal Year Annual Research Report

電子移動反応の分子場制御

Research Project

Project/Area Number	06353015
Research Institution	Nagoya University
Principal Investigator	垣谷俊昭名古屋大学, 理学部, 教授 (90027350)
Co-Investigator(Kenkyū-buntansha)	今村詮広島大学, 理学部, 教授 (70076991) 坂田祥光大阪大学, 産業科学研究所, 教授 (60029874) 伊藤繁岡崎国立共同研究機構, 基礎生物学研究所, 助教授 (40108634) 三木邦夫京都大学, 理学部, 教授 (10116105) 豊島喜則京都大学, 大学院・人間・環境学研究科, 教授 (60013166)
Keywords	電子移動 / 第3ステージ / 電子因子 / 核因子 / 多成分電子移動系 / 生体電子移動系 / 界面 / 分子設計
Research Abstract	電子移動は非常に高いポテンシャリィティを有している。生物は30億年の進化の過程においてこれを見事に利用し、高効率な電子移動ナノデバイスを構築してきた。しかし、人類はこの高いポテンシャリィティを十分に活用できないでいる。本総合研究(B)ではこれまでの電子移動研究を総括すると共に将来の電子移動研究を展望し、重点領域として次の課題を設定することにした。電子移動を自由自在にコントロールし、十分に活用する第3ステージの電子移動研究を世界に先駆けて行う。すなわち、電子トンネル過程における電子因子、核因子、媒体のダイナミクスの各要素の制御及び電子移動素反応の組織化を通じて、電子移動経路と速度を意のままに調節し、電子移動を駆動力とする分子機械、仕事をする作用分子系を創製する。この目的のため、多成分電子移動系の開発、新しい生体電子移動系の創製、界面のミクロ分子場構築及び新電子移動現象の探索を行う。理論及びコンピュータを駆使した解析を通じて、電子移動現象の深い理解に迫り、分子設計のための理論的指針を与える。このような調査・企画にもとづいて、重点領域「第3ステージの電子移動-創造と探索-」を申請することにした。経費は1回の全体会議(35名出席)と1回のミニシンポジウム(10名出席)と6回の代表者会議(5〜7名出席)を開いた旅費にあてた。また企画調査書にも使用した。全体会議・シンボジウムには若年も参加し、将来の展望をもつのに役立てた。

Research Products

(73 results)

All Other

All Publications (73 results)

[Publications] T.Kakitani: "Relation between four-state delineation and two-state delineation in electron transfer reactions and excitation transfer." Inor.Chim.Acta. 225. 185-190 (1994)
[Publications] N.Matsuda et al.: "Examination of the Biability of Collins-Kimball model and numerical calculation of the time-dependent energy gap law of photoinduced charge separation in polar solution." Chem.Phys.190. 83-95 (1995)
[Publications] Akira Imamura,Yuriko Aoki,Kazushi Nishimoto,Youji Kurihara…: "Calculations of the Electronic Structure of Various Aperiodic Polymers by an Elongation Method" International Journal of Quantum Chemistry. 52. 309-319 (1994)
[Publications] Masaki Mitani,Akira Imamura: "Application of the elengation method to the calcalation of electronic structures of the interface and the local defect states in a polymer:An analysis of the periodicity in the electronic states of a nonperiodic poiymer by using the cluster-series calculation" J.Chem.Phys.,. 101. 7712-7728 (1994)
[Publications] Yuriko Aoki,Sandor Suhai,Akira Imamura: "An efficient cluster elongation method in density functional theory and its application to poly-hydrogen-bonding molecules" J.Chem.Phys.,. 101. 10808-10823 (1994)
[Publications] Kazuyoshi Heda,Hiroshi Ochiai,Akira Imamura,Setsuko Nakagawa: "An Investigation of the Conformation of β-Carrageenan by Molecular Mechanics and Molecular Dynamics Simulations" Bull.Chem.Soc.Jpn.,. 68. 95-106 (1995)
[Publications] Masaki Mitani,Yuriko Aoki,Akira Imamura: "Model Calealations of Molecular Extension and Crystal Growth by Using the Elongation Method" Int.J.Auantum Chem.,. in press. (1995)
[Publications] H.Nagae,M.Kuki,R.J.Cogdell and Y.Koyama: "Shifts of the ^1Ag^-→^1Bu^+ electronic absorption of carotenoids in nonpolar and polar solvents" J.Chem.Phys.101. 6750-6765 (1994)
[Publications] T.Yamato et al.: "Topographical metric to analyze the thermal fluctuations of protein conformation." Chem.Phys.Letters. 219. 155-159 (1994)
[Publications] K.Morikami et al.: "Molecular dynamics study on the stability of ions around human lysozyme in the crystal condition." Chem.Phys.Letters. 225. 196-201 (1994)
[Publications] M.Saito: "Molecular dynamics simulations of proteins in solution Artifacts caused by the cutoff approsimation." J.Chem.Phys.101. 4055-4061 (1994)
[Publications] H.Suda et al.: "Molecular dynamics simulations for actin monomers in solution." J.Theor.Biol.171. 347-349 (1994)
[Publications] P.Jewsbury et al.: "The Proximal residue largely determines the CO distortion in carbonmonoxy globin proteins.An as initio study of a heam prosthetic unit." J.Amer.Chem.Soc.116. 11586-11587 (1994)
[Publications] H.Sumi: "Rigorous Formula for the Mean Lifetime of Diffusion-Controlled Second-Order Reactions in Solution." J.Chem.Phys.100. 8825-8840 (1994)
[Publications] T.Asano et al.: "Two-Step Mechanism in Single-Step Isomerization.Kinetics in Highly Viscous Liquid Phase." J.Am.Chem.Soc.116. 5545-5550 (1994)
[Publications] S.Higai et al.: "Two Types of Self-Trapped States for Excitons in One Dimension." J.Phys.Soc.Jpn. 63. 4489-4498 (1994)
[Publications] H.Sumi: "Dynamical Effects of Diffusion on Rates of Second-Order Reactions in Solvents." AIP Conf.Proc.Ser.298. 485-495 (1994)
[Publications] T.Akiyama: "Preparation of Molecular Assemblies of Porphyrin-Linked Alkanechiol on Gold Sarface and Their Redox Properties" Chem.Lett.1994. 1447-1450 (1994)
[Publications] Y.Sakata: "Effect of Donor-Acceptor Orientation on Ultrafast Photoinduced Electron Transfer and Dark Charge Recombination in Porphyrin-Quinone Molecules" J.Am.Chem.Soc.116. 6904-6909 (1994)
[Publications] K.Naemura: "The Synchesis of Azophenolic Crown Elter of Cs Symmetry Incorporating Cis-1-Phenyleyclo hexane-1,2-diol Residnes and Diastereotopic Face Selectirity in Complexation of Erhanolamine by Their Diasfereotopic Faces" J.Chem.Soc.,Chem.Commun.1994. 711-712 (1994)
[Publications] M.V.An.Kin: "Observation of Conformational Relaxation Hindrance in the Siglet Excited State for Porphyrin Incorporated in a Lipid Membrane" Chem.Phys.Lett.226. 337-343 (1994)
[Publications] H.Imahori: "Synrhesis and Properties of Conjugated Porphyrins with a Diacetylene Spacer." Bull.Chem.Soc.Jpn.67. 2500-2506 (1994)
[Publications] H.Tsue: "Synthesis of Rigid Porphyrin-Quinone Compounds for Studying Mutual Orientation Effeds on Electron Transfer and Their Photophysical Properties" Bull Chem.Soc.Jpn.67. 3067-3075 (1994)
[Publications] G.V.Ponomarev: "Cis-Trans Isomerization and Atropismerizm of Octaethyl 1,2-Bis-(coproporphyrinyl)ethylene Ester" J.Chem.Soc.,Chem.Commun.1994. 1927-1928 (1994)
[Publications] K.Sugiura: "Interaction of Two Porphyrin Rings" Proc.Indian Acad.Sci.106. 735-742 (1994)
[Publications] A.A.Grivkov: "Synphesis of Rigidly Linked Triadic Molocules on the Basis of Octaalkylporphyrin Capable to Multistep Electron Transfer" Heterocycl.Compounds. 1994. 2500-2506 (1994)
[Publications] Iida,K.et al.: "Electron Transfer on Electrode Modified with Keratin Membranes Containing Manganese Porphyrins." Chem.Lett.753-756 (1994)
[Publications] Dewa,T.et al.: "Electron Transfar Catalyzed by Manganese Tetratolylporphynate across Poly (n-methyl-L-qlutamate) membrane." Macromol.Chem.Phys.195. 1031-1041 (1994)
[Publications] Iida,K.et al.: "Trasmembrane Electron Transfer across a Keratin Membranes and Lipid Bilayers catalyzed by Manganese Porphyrin Dimers." Chem.Lett.1157-1160 (1994)
[Publications] Iida,K.et al.: "Ring Hydroxylation of Aromatic Amino Acid Derovatives and Toluene by Rydrogen Peroxide Catalyzed by Manganese Halogenated Porphyrins in CH_2Cl_2/H_2O_2 and Lipid Bilayers." Chem.Lett.1307-1310 (1994)
[Publications] T.Dewa,et al.: "Effect of Axial Ligands on the Electron Transfer Catalyzed by Manganese Tetrapentafluorophenylporphyrin Poly (-methyl-L-glutama" Macromol.Chem.Phys.195. 2917-2929 (1994)
[Publications] K.A.Meadows,et al.: "Enzymatic and Chemical Cleavage of the Core Light-Harvesting Polypeptides of Photosynthetic bacteria: Toward the Determination" Biochemistry. (1994)
[Publications] S.Yamada et al.: "In-Situ Observation of Second Harmonic Lights from Amphiphilic Ruthenium (II) Tris (2,2^<1)>-biphridine) Complex at Glass/Liquid" Chem.Lett. 5. 937-940 (1994)
[Publications] S.Yamada et al.: "Second-Order Nonlinear Optical Effects in Stacked Assemblies of Ultrathin Films with Amphiphilic Ruthenium Complex." J.Phys.Chem. 98. 3573-3574 (1994)
[Publications] S.Yamada et al.: "Second Harmonic Generation from Langmuir-Blodgett Monolayers of Amphiphilic Ruthenium (II) Complexes:" Thin Solid Films. 245. 196-201 (1994)
[Publications] H.Sakaguchi et al.: "Novel Second Harmonic Generation from Intermolecular Charge-Transfer Complexes of Styrylpyridinium Salts in the Crystalline St" Mol.Cryst.Liq.Cryst.255. 121-129 (1994)
[Publications] H.Yonemura et al.: "Stereoselective Formationof a 2:1 Molecular Complex between - Cyclodextrin and Carbazole-Viologen Linked Compound with a long" Chem.Lett.11. 2097-2100 (1994)
[Publications] Y.Mizutani,S.Tokutomi,T.Kitagawa: "Resonance Raman spectra of the photointernediate in phytochrone phototransfornation: Deprotonation of the chronophore in thee bleached intervediate." Biochemistry. 33. 153-158 (1994)
[Publications] Y.Mizutani,Y.Watanabe,T.Kitagawa: "Resonance Raman cheracterization of Iron(III) Porphyrin N-Oxide:Evidence for an Fe-O-N Bridged structure" Journel of the American Chemicel Society. 116. 1683-1689 (1994)
[Publications] S.Kamineke,Y-X.Zhon,A.Thuneshige T.Yonetani,T.Kitagawa: "Seqnontiel changes of the Fe-histidinz bond upon ligaed binding to liemoglobins:Resonance Raman study of αα-crosslinbed Co-Fe by brid Hbs" Journel of the American Chemicel Society. 116. 3439-3441 (1994)
[Publications] T.Kitagawa,Y.Mizutani: "Resonance Raman spectra of highly oxidized metollopaphyrins and heme protens." Coordiration Chemistry Reviens. 135. 685-735 (1994)
[Publications] S.Nakashima,T.Kitagawa: "Recombinotion interneslistcs of photodisseciated CO myoglobin st anbiant tenpratares detetid by tine-rosolved resonince Raman spectroscopy" Journel of the American Chemicel Society. 116. 10318-10319 (1994)
[Publications] K.Miki,S.Sogabe,…and M.Miki: "Application of Automatic Molecular Replacement Procedure to Crystal Structure Analysis of Cytochrome c2 from Rhodopseudomonas viridis" Acta Crystallogr.D50. 271-275 (1994)
[Publications] S.Sogabe,T.Ezoe,…and K.Miki: "Structural Similarity of Cytochrome c2 from Rhodopseudomonas viridos to Mitochondrial Cytochromes c Revealed by Its Crystal Structure at 2.7 A Resolution" FEBS Lett.345. 5-8 (1994)
[Publications] K.Katayama,…and K.Miki: "Preliminary X-ray Crystallographic Studies of Photosynthetic Reaction Center from a Thermophilic Sulfur Bacterium,Chromatium tepidum" FEBS Lett.348. 158-160 (1994)
[Publications] A.Kita,S.Kasai …and K.Miki: "Crystal Structure Determination of a Flavoprotein FP390 from a Luminescent Bacterium,Photobacterium phosphoreeum" J.Biochem.(印刷中). (1995)
[Publications] H.Nishida,K.Inaka,…and K.Miki: "Crystal Structure of NADH-Cytochrome b5 Reductase from Pig Liver at 2.4 A Resolution" Biochemistry. (印刷中). (1995)
[Publications] T.Noguchi,T.Mitsuka and Y.Inoue: "“Fourier transform infrured spectrum of the radical cation of B-carotene photoinduced in photosystem II"" FEBS Letters. 356. 179-182 (1994)
[Publications] T.Noguchi,T.Ono and Y.Inoue: "“Direct detection of a carboxylate bridge between Mn and Ca^<2+> in the photosynthetic oxygen-evoluing center by means of Fourier transform in frared spectross" Biochimica et Biophysica Acta. (in press).
[Publications] T.Noguchi,J.Honda,T.Nagamune,H.Sasabe,Y.Inoue and I.Endo: "“Photosensitiue nitrile hydratase intrinsically possesses nitrlc oxide to the non-heme iron center:Evidence" FEBS Letters. (in press).
[Publications] T.Hibino et al.: "Role of Transit Peptide Sequence of Plastocyanin for Its Expressior Processing,and Copper Binding Activity in Escherichia." coli,J.Biochem.116. 826-832 (1994)
[Publications] T.Hibino et al.: "Expression and Characterization of Met92Gln Mutant Plastocyanin from Silene Pratensis." J.Biochem.117. 101-106 (1994)
[Publications] Iwaki,M.: "Reaction of reconstituted acceptor quinone and dynamic equilibration of electron transfer in the photosystem I reaction center" Plant Cell Physiol.35(7). 983-993 (1994)
[Publications] Kumazaki,S.: "Rates of primary electron transfer reactions in the photosystem I reactio center reconstituted with different quinones as the secondary acceptor" J.Phys.Chem.98. 11220-11225 (1994)
[Publications] Nozawa,T.: "Magnetic circular dicroism investigation on chromophores in reaction centers of photosystem I and II of green plant photosynthesis" Spectrochimica Acta. 51. 125-134 (1995)
[Publications] 伊藤繁: "地球を変えた光合成反応:明らかになりつつある光合成系の起源" 遺伝. 49. 12-17 (1995)
[Publications] Matsuura,K.: "Comparative and evolutionary aspects of the photosynthetic electron transfer system of purple bacteria." J.Plant Res.107. 191-200 (1994)
[Publications] Okumura,N.Matsuura,K.他: "Photo-oxidation of membrane-bound and soluble cytochrome c in the green sulfur bacterium Chlorobium tepidum." Photosynthesis Res.41. 125-134 (1994)
[Publications] Mimuro,M.,Matsuura,K.他: "Molecular organization of bacteriochlorophyll in chlorosomes of the green photosynthetic bacterium Chloroflexus aurantiacus:Studies of fluorescence depolarization accompanied by energy transfer processes." Photosynthesis Res.41. 181-191 (1994)
[Publications] Yamazaki,T.,Matsuura,K.他: "Energy migration in allophycocyanin-B trimer with a linker polypeptide:Analysis by the principal multi-component spectral estimation (PMSE) method." FBES Lett.353. 43-47 (1994)
[Publications] Hanada,S.,Matsuura,K.他: "Isolation of Chloroflexus aurantiacus and reiated thermophilic phototrophic bacteria from Japanese not springs using an improved isolation procedure." J.General and Applied Microbiology. 印刷中. (1995)
[Publications] K.Nakayama et al.: "Chlorophyll forms and light energy transfer in light-harvesting chlorophyll a/b protein complexes from the siphonous gree alga Bryopsis maxima." Biochim.Biophys.Acta. 1184. 103-110 (1994)
[Publications] H.Kandori et al.: "Direct determination of a lifetime of the S_2 state of B-carotene by femtosecond time-resolved fluorescence spectroscopy." J.Am.Chem.Soc.116. 2671-2672 (1994)
[Publications] M.Mimuro et al.: "Presence and significance of minor antenna components in the energy transfer seguence of a green photosynthetic bacterium chloroflexus aurantiacus." FEBS Lett.340. 167-172 (1994)
[Publications] M.Mimuro et al.: "Molecular organization of bacteriochlorophylls in chlorosomes of the green photosynthetic. bacterium Chloroflexus aurantiacus:" Photosynthe.Res.41. 181-191 (1994)
[Publications] K.Uehara,et al.: "The formation and characterization of the in vitro polymeric aggregates of bacteriochlorophyll c homologs from chlorobium…" Photosynthe.Res.41. 235-243 (1994)
[Publications] T.Yamazaki,et al: "Energy Migration in allophycocyanin B trimer with linker;Abalysis by principal multicomponenet spectral Energy migration in." FEBS Lett.353. 43-47 (1994)
[Publications] K.Nakayama et al.: "Kinetic analysis of energy transfer processes in LHC II Isolated from a siphonous gree alga Bryopsis masima with use of a picosecond" Biochim.Biophys.Acta. 1188. 117-124 (1994)
[Publications] T.Ogata et al: "A novel peridinin-chlorophyll a protein (PCP) isolated from the dinoflagellate Alexandorium cohorticula:" FEBS Lett.356. 367-371 (1994)
[Publications] T.Nozawa et al.: "Magnetic circular dichroism invesgigation on chromophores in reaction centers of photosystem I and II of green plant photosynthe" Spectrochim.Acta. 51A. 125-134 (1995)
[Publications] A.A.Demidov et al.: "Deconvolution of C-Phycocyamin B-84 and B-155 chromophore absorpsic and fluorescence spectra of cyanobacterium mastigocladus laminosus." Biophys.J.(1995)
[Publications] 三室守: "もっと光を!光を集めるアンテナ色素系の進化" 遺伝. 49. 37-42 (1995)
[Publications] 三木邦夫(共同執筆): "錯体化学-基礎と最近の話題" 講談社, 220 (1994)

1994 Fiscal Year Annual Research Report

電子移動反応の分子場制御

Principal Investigator

垣谷 俊昭 名古屋大学, 理学部, 教授 (90027350)

Research Products

[Publications] T.Kakitani: "Relation between four-state delineation and two-state delineation in electron transfer reactions and excitation transfer." Inor.Chim.Acta. 225. 185-190 (1994)

[Publications] N.Matsuda et al.: "Examination of the Biability of Collins-Kimball model and numerical calculation of the time-dependent energy gap law of photoinduced charge separation in polar solution." Chem.Phys.190. 83-95 (1995)

[Publications] Akira Imamura,Yuriko Aoki,Kazushi Nishimoto,Youji Kurihara…: "Calculations of the Electronic Structure of Various Aperiodic Polymers by an Elongation Method" International Journal of Quantum Chemistry. 52. 309-319 (1994)

[Publications] Yuriko Aoki,Sandor Suhai,Akira Imamura: "An efficient cluster elongation method in density functional theory and its application to poly-hydrogen-bonding molecules" J.Chem.Phys.,. 101. 10808-10823 (1994)

[Publications] Kazuyoshi Heda,Hiroshi Ochiai,Akira Imamura,Setsuko Nakagawa: "An Investigation of the Conformation of β-Carrageenan by Molecular Mechanics and Molecular Dynamics Simulations" Bull.Chem.Soc.Jpn.,. 68. 95-106 (1995)

[Publications] Masaki Mitani,Yuriko Aoki,Akira Imamura: "Model Calealations of Molecular Extension and Crystal Growth by Using the Elongation Method" Int.J.Auantum Chem.,. in press. (1995)

[Publications] H.Nagae,M.Kuki,R.J.Cogdell and Y.Koyama: "Shifts of the ^1Ag^-→^1Bu^+ electronic absorption of carotenoids in nonpolar and polar solvents" J.Chem.Phys.101. 6750-6765 (1994)

[Publications] T.Yamato et al.: "Topographical metric to analyze the thermal fluctuations of protein conformation." Chem.Phys.Letters. 219. 155-159 (1994)

[Publications] K.Morikami et al.: "Molecular dynamics study on the stability of ions around human lysozyme in the crystal condition." Chem.Phys.Letters. 225. 196-201 (1994)

[Publications] M.Saito: "Molecular dynamics simulations of proteins in solution Artifacts caused by the cutoff approsimation." J.Chem.Phys.101. 4055-4061 (1994)

[Publications] H.Suda et al.: "Molecular dynamics simulations for actin monomers in solution." J.Theor.Biol.171. 347-349 (1994)

[Publications] P.Jewsbury et al.: "The Proximal residue largely determines the CO distortion in carbonmonoxy globin proteins.An as initio study of a heam prosthetic unit." J.Amer.Chem.Soc.116. 11586-11587 (1994)

[Publications] H.Sumi: "Rigorous Formula for the Mean Lifetime of Diffusion-Controlled Second-Order Reactions in Solution." J.Chem.Phys.100. 8825-8840 (1994)

[Publications] T.Asano et al.: "Two-Step Mechanism in Single-Step Isomerization.Kinetics in Highly Viscous Liquid Phase." J.Am.Chem.Soc.116. 5545-5550 (1994)

[Publications] S.Higai et al.: "Two Types of Self-Trapped States for Excitons in One Dimension." J.Phys.Soc.Jpn. 63. 4489-4498 (1994)

[Publications] H.Sumi: "Dynamical Effects of Diffusion on Rates of Second-Order Reactions in Solvents." AIP Conf.Proc.Ser.298. 485-495 (1994)

[Publications] T.Akiyama: "Preparation of Molecular Assemblies of Porphyrin-Linked Alkanechiol on Gold Sarface and Their Redox Properties" Chem.Lett.1994. 1447-1450 (1994)

[Publications] Y.Sakata: "Effect of Donor-Acceptor Orientation on Ultrafast Photoinduced Electron Transfer and Dark Charge Recombination in Porphyrin-Quinone Molecules" J.Am.Chem.Soc.116. 6904-6909 (1994)

[Publications] K.Naemura: "The Synchesis of Azophenolic Crown Elter of Cs Symmetry Incorporating Cis-1-Phenyleyclo hexane-1,2-diol Residnes and Diastereotopic Face Selectirity in Complexation of Erhanolamine by Their Diasfereotopic Faces" J.Chem.Soc.,Chem.Commun.1994. 711-712 (1994)

[Publications] M.V.An.Kin: "Observation of Conformational Relaxation Hindrance in the Siglet Excited State for Porphyrin Incorporated in a Lipid Membrane" Chem.Phys.Lett.226. 337-343 (1994)

[Publications] H.Imahori: "Synrhesis and Properties of Conjugated Porphyrins with a Diacetylene Spacer." Bull.Chem.Soc.Jpn.67. 2500-2506 (1994)

[Publications] H.Tsue: "Synthesis of Rigid Porphyrin-Quinone Compounds for Studying Mutual Orientation Effeds on Electron Transfer and Their Photophysical Properties" Bull Chem.Soc.Jpn.67. 3067-3075 (1994)

[Publications] G.V.Ponomarev: "Cis-Trans Isomerization and Atropismerizm of Octaethyl 1,2-Bis-(coproporphyrinyl)ethylene Ester" J.Chem.Soc.,Chem.Commun.1994. 1927-1928 (1994)

[Publications] K.Sugiura: "Interaction of Two Porphyrin Rings" Proc.Indian Acad.Sci.106. 735-742 (1994)

[Publications] A.A.Grivkov: "Synphesis of Rigidly Linked Triadic Molocules on the Basis of Octaalkylporphyrin Capable to Multistep Electron Transfer" Heterocycl.Compounds. 1994. 2500-2506 (1994)

[Publications] Iida,K.et al.: "Electron Transfer on Electrode Modified with Keratin Membranes Containing Manganese Porphyrins." Chem.Lett.753-756 (1994)

[Publications] Dewa,T.et al.: "Electron Transfar Catalyzed by Manganese Tetratolylporphynate across Poly (n-methyl-L-qlutamate) membrane." Macromol.Chem.Phys.195. 1031-1041 (1994)

[Publications] Iida,K.et al.: "Trasmembrane Electron Transfer across a Keratin Membranes and Lipid Bilayers catalyzed by Manganese Porphyrin Dimers." Chem.Lett.1157-1160 (1994)

[Publications] Iida,K.et al.: "Ring Hydroxylation of Aromatic Amino Acid Derovatives and Toluene by Rydrogen Peroxide Catalyzed by Manganese Halogenated Porphyrins in CH_2Cl_2/H_2O_2 and Lipid Bilayers." Chem.Lett.1307-1310 (1994)

[Publications] T.Dewa,et al.: "Effect of Axial Ligands on the Electron Transfer Catalyzed by Manganese Tetrapentafluorophenylporphyrin Poly (-methyl-L-glutama" Macromol.Chem.Phys.195. 2917-2929 (1994)

[Publications] K.A.Meadows,et al.: "Enzymatic and Chemical Cleavage of the Core Light-Harvesting Polypeptides of Photosynthetic bacteria: Toward the Determination" Biochemistry. (1994)

[Publications] S.Yamada et al.: "In-Situ Observation of Second Harmonic Lights from Amphiphilic Ruthenium (II) Tris (2,2^<1)>-biphridine) Complex at Glass/Liquid" Chem.Lett. 5. 937-940 (1994)

[Publications] S.Yamada et al.: "Second-Order Nonlinear Optical Effects in Stacked Assemblies of Ultrathin Films with Amphiphilic Ruthenium Complex." J.Phys.Chem. 98. 3573-3574 (1994)

[Publications] S.Yamada et al.: "Second Harmonic Generation from Langmuir-Blodgett Monolayers of Amphiphilic Ruthenium (II) Complexes:" Thin Solid Films. 245. 196-201 (1994)

[Publications] H.Sakaguchi et al.: "Novel Second Harmonic Generation from Intermolecular Charge-Transfer Complexes of Styrylpyridinium Salts in the Crystalline St" Mol.Cryst.Liq.Cryst.255. 121-129 (1994)

[Publications] H.Yonemura et al.: "Stereoselective Formationof a 2:1 Molecular Complex between - Cyclodextrin and Carbazole-Viologen Linked Compound with a long" Chem.Lett.11. 2097-2100 (1994)

[Publications] Y.Mizutani,S.Tokutomi,T.Kitagawa: "Resonance Raman spectra of the photointernediate in phytochrone phototransfornation: Deprotonation of the chronophore in thee bleached intervediate." Biochemistry. 33. 153-158 (1994)

[Publications] Y.Mizutani,Y.Watanabe,T.Kitagawa: "Resonance Raman cheracterization of Iron(III) Porphyrin N-Oxide:Evidence for an Fe-O-N Bridged structure" Journel of the American Chemicel Society. 116. 1683-1689 (1994)

[Publications] S.Kamineke,Y-X.Zhon,A.Thuneshige T.Yonetani,T.Kitagawa: "Seqnontiel changes of the Fe-histidinz bond upon ligaed binding to liemoglobins:Resonance Raman study of αα-crosslinbed Co-Fe by brid Hbs" Journel of the American Chemicel Society. 116. 3439-3441 (1994)

[Publications] T.Kitagawa,Y.Mizutani: "Resonance Raman spectra of highly oxidized metollopaphyrins and heme protens." Coordiration Chemistry Reviens. 135. 685-735 (1994)

[Publications] S.Nakashima,T.Kitagawa: "Recombinotion interneslistcs of photodisseciated CO myoglobin st anbiant tenpratares detetid by tine-rosolved resonince Raman spectroscopy" Journel of the American Chemicel Society. 116. 10318-10319 (1994)

[Publications] K.Miki,S.Sogabe,…and M.Miki: "Application of Automatic Molecular Replacement Procedure to Crystal Structure Analysis of Cytochrome c2 from Rhodopseudomonas viridis" Acta Crystallogr.D50. 271-275 (1994)

[Publications] S.Sogabe,T.Ezoe,…and K.Miki: "Structural Similarity of Cytochrome c2 from Rhodopseudomonas viridos to Mitochondrial Cytochromes c Revealed by Its Crystal Structure at 2.7 A Resolution" FEBS Lett.345. 5-8 (1994)

[Publications] K.Katayama,…and K.Miki: "Preliminary X-ray Crystallographic Studies of Photosynthetic Reaction Center from a Thermophilic Sulfur Bacterium,Chromatium tepidum" FEBS Lett.348. 158-160 (1994)

[Publications] A.Kita,S.Kasai …and K.Miki: "Crystal Structure Determination of a Flavoprotein FP390 from a Luminescent Bacterium,Photobacterium phosphoreeum" J.Biochem.(印刷中). (1995)

[Publications] H.Nishida,K.Inaka,…and K.Miki: "Crystal Structure of NADH-Cytochrome b5 Reductase from Pig Liver at 2.4 A Resolution" Biochemistry. (印刷中). (1995)

[Publications] T.Noguchi,T.Mitsuka and Y.Inoue: "“Fourier transform infrured spectrum of the radical cation of B-carotene photoinduced in photosystem II"" FEBS Letters. 356. 179-182 (1994)

[Publications] T.Noguchi,T.Ono and Y.Inoue: "“Direct detection of a carboxylate bridge between Mn and Ca^<2+> in the photosynthetic oxygen-evoluing center by means of Fourier transform in frared spectross" Biochimica et Biophysica Acta. (in press).

[Publications] T.Noguchi,J.Honda,T.Nagamune,H.Sasabe,Y.Inoue and I.Endo: "“Photosensitiue nitrile hydratase intrinsically possesses nitrlc oxide to the non-heme iron center:Evidence" FEBS Letters. (in press).

[Publications] T.Hibino et al.: "Role of Transit Peptide Sequence of Plastocyanin for Its Expressior Processing,and Copper Binding Activity in Escherichia." coli,J.Biochem.116. 826-832 (1994)

[Publications] T.Hibino et al.: "Expression and Characterization of Met92Gln Mutant Plastocyanin from Silene Pratensis." J.Biochem.117. 101-106 (1994)

[Publications] Iwaki,M.: "Reaction of reconstituted acceptor quinone and dynamic equilibration of electron transfer in the photosystem I reaction center" Plant Cell Physiol.35(7). 983-993 (1994)

[Publications] Kumazaki,S.: "Rates of primary electron transfer reactions in the photosystem I reactio center reconstituted with different quinones as the secondary acceptor" J.Phys.Chem.98. 11220-11225 (1994)

[Publications] Nozawa,T.: "Magnetic circular dicroism investigation on chromophores in reaction centers of photosystem I and II of green plant photosynthesis" Spectrochimica Acta. 51. 125-134 (1995)

[Publications] 伊藤繁: "地球を変えた光合成反応:明らかになりつつある光合成系の起源" 遺伝. 49. 12-17 (1995)

[Publications] Matsuura,K.: "Comparative and evolutionary aspects of the photosynthetic electron transfer system of purple bacteria." J.Plant Res.107. 191-200 (1994)

[Publications] Okumura,N.Matsuura,K.他: "Photo-oxidation of membrane-bound and soluble cytochrome c in the green sulfur bacterium Chlorobium tepidum." Photosynthesis Res.41. 125-134 (1994)

[Publications] Mimuro,M.,Matsuura,K.他: "Molecular organization of bacteriochlorophyll in chlorosomes of the green photosynthetic bacterium Chloroflexus aurantiacus:Studies of fluorescence depolarization accompanied by energy transfer processes." Photosynthesis Res.41. 181-191 (1994)

[Publications] Yamazaki,T.,Matsuura,K.他: "Energy migration in allophycocyanin-B trimer with a linker polypeptide:Analysis by the principal multi-component spectral estimation (PMSE) method." FBES Lett.353. 43-47 (1994)

[Publications] Hanada,S.,Matsuura,K.他: "Isolation of Chloroflexus aurantiacus and reiated thermophilic phototrophic bacteria from Japanese not springs using an improved isolation procedure." J.General and Applied Microbiology. 印刷中. (1995)

[Publications] K.Nakayama et al.: "Chlorophyll forms and light energy transfer in light-harvesting chlorophyll a/b protein complexes from the siphonous gree alga Bryopsis maxima." Biochim.Biophys.Acta. 1184. 103-110 (1994)

[Publications] H.Kandori et al.: "Direct determination of a lifetime of the S_2 state of B-carotene by femtosecond time-resolved fluorescence spectroscopy." J.Am.Chem.Soc.116. 2671-2672 (1994)

[Publications] M.Mimuro et al.: "Presence and significance of minor antenna components in the energy transfer seguence of a green photosynthetic bacterium chloroflexus aurantiacus." FEBS Lett.340. 167-172 (1994)

[Publications] M.Mimuro et al.: "Molecular organization of bacteriochlorophylls in chlorosomes of the green photosynthetic. bacterium Chloroflexus aurantiacus:" Photosynthe.Res.41. 181-191 (1994)

[Publications] K.Uehara,et al.: "The formation and characterization of the in vitro polymeric aggregates of bacteriochlorophyll c homologs from chlorobium…" Photosynthe.Res.41. 235-243 (1994)

[Publications] T.Yamazaki,et al: "Energy Migration in allophycocyanin B trimer with linker;Abalysis by principal multicomponenet spectral Energy migration in." FEBS Lett.353. 43-47 (1994)

[Publications] K.Nakayama et al.: "Kinetic analysis of energy transfer processes in LHC II Isolated from a siphonous gree alga Bryopsis masima with use of a picosecond" Biochim.Biophys.Acta. 1188. 117-124 (1994)

[Publications] T.Ogata et al: "A novel peridinin-chlorophyll a protein (PCP) isolated from the dinoflagellate Alexandorium cohorticula:" FEBS Lett.356. 367-371 (1994)

[Publications] T.Nozawa et al.: "Magnetic circular dichroism invesgigation on chromophores in reaction centers of photosystem I and II of green plant photosynthe" Spectrochim.Acta. 51A. 125-134 (1995)

[Publications] A.A.Demidov et al.: "Deconvolution of C-Phycocyamin B-84 and B-155 chromophore absorpsic and fluorescence spectra of cyanobacterium mastigocladus laminosus." Biophys.J.(1995)

[Publications] 三室 守: "もっと光を!光を集めるアンテナ色素系の進化" 遺伝. 49. 37-42 (1995)

[Publications] 三木邦夫(共同執筆): "錯体化学-基礎と最近の話題" 講談社, 220 (1994)

垣谷俊昭名古屋大学, 理学部, 教授 (90027350)

[Publications] 三室守: "もっと光を!光を集めるアンテナ色素系の進化" 遺伝. 49. 37-42 (1995)