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1995 Fiscal Year Final Research Report Summary

Research for carbon recycling by waste heat with Ferrites

Research Project

Project/Area Number 06403030
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field エネルギー学一般・原子力学
Research InstitutionTOKYO INSTITUTE OF TECHNOLOGY

Principal Investigator

TAMAURA Yutaka  Tokyo Institute of Technology・Research Center for Carbon recycling and Utilization, Professor, 炭素循環素材研究センター, 教授 (00108185)

Co-Investigator(Kenkyū-buntansha) OGUNI Masaharu  Tokyo Institute of Technology・facurity of Sceience, professor, 理学部, 教授 (50144423)
TSUJI Masamichi  Tokyo Institute of Technology・Research Center for Carbon recycling and Utilizati, 炭素循環素材研究センター, 助教授 (20111643)
Project Period (FY) 1994 – 1995
KeywordsCIO-layr / Ni(II)-ferrite / heat / chemical energy conversion / solar energy / O_2 release / ZnO / FeO / Ultra-fine particles
Research Abstract

The chemical analysis, X-ray diffractometry, FT/IR,Mossbauer effect, XPS measurement showed that the metal ions (Fe^<2+>, Ni^<2+>) in the CIO-layr (Carbon bearing iron oxide-layr) on the Ni(II)-ferrite form a kind of carbide-like linkage in the activation step. The CIO-layr is formed as a part of the spinel structure of the bulk Ni(II)-ferrite with a stoichiometric chemical composition. Fe^<2+> ion in the CIO-layr exists in the distorted spinel structure which contains a higher Content of Fe^<2+> ion than the normal spinel structure. The carbon element of the graphite in the CIO-layr can make a bonding with the Fe^<2+> ion in the CIO-layr under a lower partial pressure of O_2 at 300゚C.This would cause the formation of the carbide-like linkage and make it easy for O^2-ion to be released from CIO-layr. This Fe^<2+>-rich structure in the distorted spinel structure can be regarded as a distorted FeO structure, which would cause the O_2 gas evolution in the decomposition of the FeO structur … More e into the spinel phase and metallic phase. This was experimentally confirmed by the O_2 evolution reaction of the FeO/ZnO by-phase system under a lower oxygen partial pressure at 500゚C.Based on these O_2 evolution mechanism, a chemical structure with a higher reactivity of the O_2 release was designed. This offered a new route for developing the materials with a higher efficiency in the heat/chemical energy conversion system. Ultra-fine particles of the CIO-layred Ni(II)-ferrite was found to give an another way for increasing the O_2 evolution efficiency by 3 times. The results on the heat/chemical energy conversion experiment using a device specially designed and made, gave a poor efficiency for the CBNF.Therefore, a new system (combined cycle of 1st- and 2nd- Redox Systems), by which the heat/chemical energy conversion efficiency can be amplified, was designed and proved to be practically worked. This system was further studied to apply to the solar energy conversion into chemical energy at a lower temperature of 400-800゚C.The 2nd-Redox System was found to be used for solar energy/hydrogen energy conversion at the low temperatures. Less

  • Research Products

    (105 results)

All Other

All Publications (105 results)

  • [Publications] K.Nishizawa,H.Kato,K.Mimori,M.Tsuji.T.Yoshida and Y.Tamaura :"Methanation of carbon deposited CO2 directly from CO2 on rhodium-bearing activated magnetite," J.Mater.Sci.,. 29[3]. 768-772 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji.T.Tabata and Y.Tamaura: "CO2 decomposition by oxide ceramics intercalated in layered compound," J.Am.Ceram.Soc.,. 77[1]. 161-164 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tabata,H.Kato,T.Kodama,T.Yoshida M.Tsuji and Y.Tamaura :"CO2 decomposition with manganowustite," J.Mater.Sci.,. 29. 999-1003 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,H.Kato,S.G.Chang,N.Hasegawa,M.Tsuji and Y.Tamaura :"Decomposition of CO2 to carbon by H2-reduced Ni (II)-and Co (II)-bearing ferrites at 300℃," J.Mater.Res.,. 9[2]. 462-467 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Mimori,Y.Wada,N.Hasegawa,M.Tsuji and Y.Tamaura :"A new reversible chemical system for efficient utilization of carbonaceous compounds," Energy,. 19[7]. 771-778 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tabata,K.Akanuma,T.Togawa,M.Tsuji and Y.Tamaura :"Mossbauer study on oxygen-deficient Zn (II)-bearing ferrites (ZnxFe3-xO4,0<x<1) and their reactivity tpward CO2 decomposition to carbon," J.Chem.Soc.Faraday Trans.,. 90[8]. 1171-1175 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Nishizawa H.Kato,K.Mimori,T.Yoshida,N.Hasegawa,M.Tsuji and Y.Tamaura :"Methanation of carbon deposited directly from CO2 on rhodium-bearing activated magnetite ;" J.Mater.Sci.,. 29. 768-772 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,K.Nishizawa,T.Yoshida and Y.Tamaura: "Methanation reactivity of the surface carbon deposited from CO2 on the oxygen-deficient magnetite," J.Mater.Sci.,. 29. 5481-5484 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kato,T.Kodama,M.Tsuji,Y.Tamaura and S.G.Chang :"Decomposition of carbon dioxide to carbon by hydrogen-reduced Ni (II)-bearing ferrite," J.Mater.Sci.,. 29. 5689-5692 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,H.Kato,T.kodama,S.G.Chang,N.Hasegawa and Y.Tamaura: "Methanation of CO2 on H2-reduced Ni (II)-or Co (II)-bearing ferrites at 200℃," J.Mater.Sci.,. 29. 6227-6230 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tamaura,N.Hasegawa,M.Tsuji and K.Akanuma: "Synthesis of carbon-iron (II) oxide layer on the surface of magnetite and its reactivity with H20 for hydrogen generation," J.Mater.Sci.,. 29. 6175-6180 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Togawa,H.Kato,M.Tsuji and Y.Tamaura :"Effect of crystal orientation on formation of oxygen-deficient magnetite." Mater.Res.Soc.Proc.,. 344. 45-50 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Yoshida,T.Togawa,M.Tsuji and Y.Tamaura :"Kinetic study for the formation of the oxygen-deficient magnetite," Mater.Res.Soc.Proc.,. 344. 51-56 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Hasegawa,K.Akanuma,M.Tsuji and Y.Tamaura :"New generation reaction of H2 from H2O over carbon-bearing ferrites at 300℃," Mater.Res.Soc.Proc.,. 344. 57-62 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,T.Sano,S.G.Chang,M.Tsuji and Y.Tamaura :"Decomposition of CO2 to carbon by H2-activated Ni (II)-and Co (II)-bearing ferrites at 300℃," Mater.Res.Soc.Proc.,. 344. 63-68 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Mimori,N,Hasegawa,M.Tsuji and Y.Tamaura :"A new route of generation of CO with a redox system of mixture of metal oxide and carbon," Mater.Res.Soc.Proc.,. 344. 151-156 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,K.Mimori,N.Hasegawa and Y.Tamaura: "A chemical heat pump with an endothermic and reversible chemical system incorporated," Mater.Res.Soc.Proc.,. 344. 301-306 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tabata,H.Kato,M.Tsuji and Y.Tamaura: "Decomposition of CO2 to carbon using oxygen-deficient Zn (II)-bearing ferrite," Mater.Res.Soc.Proc.,. 344. 157-162 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kato,T.Sano,M.Tsuji and Y.Tamaura :"Methanation of CO2 on Ni (II)-bearing ferrite (NixFe3-xO4-δ; x=0.39,δ>0) in flow system," Mater.Res.Soc.Proc.,. 344. 163-168 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akanuma,Y.Wada,M.Tsuji and Y.Tamaura: "Surface characterization of carbon-bearing magnetite (CBM) and carbon-bearing Ni (II)-ferrite (CBNF)," Mater.Res.Soc.Proc.,. 344. 169-175 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji T.Togawa,Y.wada,T.Sano,and Y.Tamaura: "Kinetic study for the formation of cation-excess magnetite," J.Chem.Soc,Faraday Trans.,. 91[10]. 1533-1538 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,Y.Wada,T.Yamamoto,M.Tsuji and Y.Tamaura :"CO2 decomposition to carbon by ultrafine Ni (II)-bearing ferrite," Mater.Res.Bull.,. 30[8]. 1039-1048 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Yamamoto,T.Kodama,N.Hasegawa,M.Tsuji,and Y.Tamaura: "“Synthesis of hydrotalcite with high layer charge for CO2 adsorbent",Energy Convers. Mgmt." Energy Convers. Mgmt.,. 36[6-9],. 637-640 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Wada.T.Yoshida,M.Tsuji and Y.Tamaura :"“CO2 decomposition capacity of oxygen-deficient ferrites"" Energy Convers.Mgmt.,. 36[6-9],. 641-644 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama Y.Wada,T.Yamamoto,M.Tsuji and Y.Tamaura: "Synthesis and characterization of ultrafine NI (II)-bearing ferrites (NixFe3-xO4 ; x=0.14-1.0)," J.Mater.Chem.,. 5[9],. 1413-1418 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,T.Sano,M.Tabata,and Y.Tamaura: "Enhanced conversion of CO2 with a mixed system of metal oxide and carbon," Energy,. 20[9],. 869-876 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kato,T.Sano,Y.Wada,Y.Tamaura,M.Tsuji,T.Tsuji and S.Miyazaki :"Methanation of CO2 with the oxygen-deficient Ni (II)-ferrite under dynamic conditions" J.Mater.Sci.,. 30. 6350-6354 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,M.Tabata,T.Sano,M.Tsuji,and Y.Tamaura :"XRD and Moessbauer studies on oxygen-deficient Ni (II)-bearing ferrite with a high reactivity for CO2 decomposition to carbon" J.Solid State Chem.,. 120. 64-69 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,T.Sano,T.Yoshida,M.Tsuji,and Y.Tamaura: "CO2-decomposition reactivity of ferrite-derived metallic phase," Carbon,. 33[10]. 1443-1447 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,Y.Wada,T.Kodama,N.Hasegawa: "Endothermic and reversible reactions for a chemical heat pump," Proc.of Int.Sym.on Environmental Issues on Ceramics,The Ceramic Society of Japan,Hokkaido. 19-20. 109-115 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Yoshida,H.Kato,M.Tsuji and Y.Tamaura: "Effect of platinum impregnation onto magnetite or Ni (II)-bearing toward the methanation of CO2," Proc.of Int.Sym.on Environmental Issues on Ceramics,The Ceramic Society of Japan,Hokkaido,. 19-20. 139-144 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Wada,M.Tabata,M.Tsuji and Y.Tamaura: "Decomposition of CO2 with oxygen-defficient spinel ferrites," Proc.of Int.Sym.on Environmental Issues on Ceramics,The Ceramic Society of Japan,Hokkaido,. 19-20. 145-160 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kojima,T.Yoshida,M.Tsuji and Y.Tamaura: "Decomposition fo CO2 into carbon with Rh-,Pt- or Ce-impregnated Ni (Ii)-ferrite by H2-activation at 300C," Proc.of Int.Sym.on Environmental Issues on Ceramics,The Ceramic Society of Japan,Hokkaido,. 19-20. 154-160 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,Y.Wada,T.Yamamoto,T.Sano and Y.Tamaura: "CO2 decomposition by metallic phase on oxygen-deficient Ni (II)-bearing ferrite" J.Mater.Sci.Lett.,. 15. 156-158 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,Y.Wada,Y.Tamaura,A.Steinfeld,P.Kuhn and R.Palumbo: "Coal gasification by the coal/CH4-ZnO-Zn-H2O solar energy conversion system" Energy Convers.Mgmt.,. 37[6-8]. 1315-1320 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Hasegawa,T.Yoshida,M.Tsuji and Y.Tamaura :"Integrated carbon recycling system for mitigation of CO2 emissions utilizing degraded thermal energy," Energy Convers.Mgmt.,. 37[6-8]. 1333-1338 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Sano,T.Togawa,M.Kojima,M.Tsuji and Y.Tamaura: "Thermal study for release of the lattice oxygen from carbon-bearing Ni (II)-ferrite" Energy. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,Y.Wada,Y.Tamaura,A.Steinfeld,P.Kuhn,and R.D.Palumbo: "Coal gasification using the ZnO/Zn redox system" Energy Fuels,. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Togawa,T.Sano,Y.Wada,T.Kodama,T.Yoshida,M.Tsuji and Y.Tamaura :"The effect of the crystal orientation of the rate of formation of the cation-excess magnetite," Solid State Ionics,. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Sano,N.Hasegawa,M.Tsuji and Y.Tamaura: "A carbon-bearing Ni (II) ferrite : a tailor-made solid reactant for two-step thermochemical water splitting at 300℃" Journal of Materials chemistry. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,T.Yamamoto,Y.Tamaura,T.Kodama and Y.Kitayama :"Catalytic acceleration for CO2 decomposition into carbon by Rh,Pt or Ce-impregnation onto Ni (II)-bearing ferrite" Applied Catalysis A : General,. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,Y.Tamaura,A.Steinfeld and P.Kuhn: "The Solar-driven Coal-ZnO Redox System for CO2 Mitigation" Energy. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tamaura,M.Tsuji,A.Steinfeld and P.Kuhn: "Coal/magnetite System for Mixing the Solar Energy into Fossil Energy" Energy. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kodama,Y.Kitayama,M.Tsuji and Y.Tamaura: "Methanation of CO2 Using Ultrafine NixFe3-xO4 system" Energy. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Sano,N.Hasegawa,M.Tsuji and Y.Tamaura :"A two-step the mochemical water splitting on a carbon-bearing Ni (II) ferrite at 300℃" International J.of Hydrogen Energy.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kojima,T.Sano,Y.Wada,T.Yamamoto,M.Tusji and Y.Tamaura: "Thermochemical decomposition of H2O to H2 on cation-excess ferrite" J.Phys.Chem,Solids.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Tsuji,T.Kodama,T.Yoshida,Y.Kitayama and Y.Tamaura: "Preparation and CO2 Methanation Activity of Ultrafine Ni (II) Ferrite Catalyst" J.Catal.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] .Tamaura,Y.Wada and M.Tsuji,A.Steinfeld and P.Kuhn :"Temperature-programmed Gasification of Coal with ZnO as the Oxidant" submitted of Fuels.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tamaura,N.Hasegawa,M.Kojima,T.Sano and M.Tsuji: "Stoichiometry of H2 evolution in the 2-step water splitting by a CIO-layerd Ni (II)-ferrite" submitted to International J.of Hydrogen Energy.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 玉浦 裕: "CO2排出低減の水素エネルギー化学" 化学. 49[10]. 744-745 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 正道、玉浦 裕: "水素還元フェライトによるCO2メタン化反応" CO2固定シンポジウム講演予稿集. 5-6 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 玉浦 裕: "水素発生反応性セラミックを用いる廃熱有効利用技術" 水素エネルギーシステム研究発表予稿集(第15回). 1-6 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 玉浦 裕: "水素還元フェライトによるCO2メタン化反応" エネルギーシステム・経済コンファレンス講演論文集、. 263-266 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 正道、玉浦 裕: "300CにおけるフェライトCIO層による水素発生反応、" CO2固定シンポジウム講演予稿集. 24 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 玉浦 裕、辻 正道: "CIO層による水素発生と熱回収システムの検討" エネルギーシステム・経済コンファレンス講演論文集. 495-464 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 辻 正道、玉浦 裕: "金属酸化物/化石燃料反応系による高効率太陽/化学エネルギー変換システム" エネルギーシステム・経済コンファレンス講演論文集. 495-465 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] "CO_2 decomposition by oxide ceramics intercalated in layred compound, ." J.AM.Ceram.Soc.77 [1]. 161-164 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Nishizawa, H.Kato, K.Mimori, M.Tsuji, T.Yoshida and Y.Tamaura: "Methanation of carbon deposited CO_2 directly from CO_2 on rhodium-bearing activated magnetite" J.Mater.Sci.29 [3]. 768-772 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tabata, H.Kato, T.Kodama, T.Yoshida, M.Tsuji and Y.Tamaura: "CO_2 decomposition with manganowustite" J.Mater.Sci.29. 999-1003 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, H.Kato, S.G.Chang, N.Hasegawa, M.Tsuji and Y.Tamaura: "Decomposition of CO_2 to carbon by H_2-reduced Ni (II) -and Co (II) -bearing ferrites at 300゚C" J.Mater.Res.9 [2]. 462-467 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Mimori, Y.Wada, N.Hasegawa, M.Tsuji and Y.Tamaura: "A new reversible chemical system for efficient utilization of carbonaceous compounds" Energy. 19 [7]. 771-778 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tabata, K.Akanuma, T.Togawa, M.Tsuji.and Y.Tamaura: "Moessbauer study on oxygen-deficient Zn (II) -bearing ferrites (Zn_xFe_<3-x>O4,0<x<1) and their reactivity toward CO_2 decomposition to carbon" Chem.Soc.Faraday Trans.90 [8]. 1171-1175 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Nishizawa, H.Kato, K.Mimori, T.Yoshida, N.Hasegawa, M.Tsuji and Y.Tamaura: "Methanation of carbon deposited directly from CO_2 on rhodium-bearing activated magnetite" J.Mater.Sci.29. 768-772 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, K.Nishizawa, T.Yoshida and Y.Tamaura: "Methanation reactivity of the surface carbon deposited from CO_2 on the oxygen-deficient magnetite" J.Mater.Sci.29. 5481-5484 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kato, T.Kodama, M.Tsuji, Y.Tamaura and S.G.Chang: "Decomposition of carbon dioxide to carbon by hydrogen-reduced Ni (II) -bearing ferrite" J.Mater.Sci.29. 5689-5692 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, H.Kato, T.Kodama, S.G.Chang, N.Hasegawa and Y.Tamaura: "Methanation of CO_2 on H_2-reduced Ni (II) -or Co (II) -bearing ferrites at 200゚C" J.Mater.Sci.29. 6227-6230 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tamaura, N.Hasegawa, M.Tsuji and K.Akanuma: "Synthesis of carbon-iron (II) oxide layr on the surface of magnetite and its reactivity with H2O for hydrogen generation" Mater.Sci.29. 6175-6180 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Togawa, H.Kato, M.Tsuji and Y.Tamaura: "Effect of crystal orientation on formation of oxygen-deficient magnetite." Mater.Res.Soc.Proc.344. 45-50 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Yoshida, T.Togawa, M.Tsuji and Y.Tamaura: "Kinetic study for the formation of the oxygen-deficient magnetite" Mater.Res.Soc.Proc.344. 51-56 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Hasegawa, K.Akanuma, M.Tsuji and Y.Tamaura: "New generation reaction of H2 from H2O over carbon-bearing ferrites at 300゚C" Mater Res.Soc.Proc.344. 57-62 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, T.Sano, S.G.Chang, M.Tsuji and Y.Tamaura: "Decomposition of CO_2 to carbon by H2-activated Ni (II) -and Co (II) -bearing ferrites at 300゚C" Mater.Res.Soc.Proc.344. 63-68 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Mimori, N.Hasegawa, M.Tsuji and Y.Tamaura: "A new route of generation CO with a redox of system of mixture of metal oxide and carbon" Mater.Res.Soc.Proc.344. 151-156 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tabata, H.Kato, M.Tsuji and Y.Tamaura: "Decomposition of CO2 to carbon using oxygen-deficient Zn (II) -bearing ferrite" Mater.Res.Soc.Proc.344. 157-162 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kato, T.Sano, M.Tsuji and Y.Tamaura: "Methanation of CO2 on Ni (II) -bearing ferrite (NixFe3-xO4-delta ; x=0.39, delta>0) in flow system" Mater.Res.Soc.Proc.344. 163-168 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akanuma, Y.Wada, M.Tsuji and Y.Tamaura: "Surface characterization of carbon-bearing magnetite (CBM) and carbon-bearing Ni (II) -ferrite (CBNF)" Mater.Res.Soc.Proc.344. 169-175 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, K.Mimori, N.Hasegawa and Y.Tamaura: "A chemical heat pump with an endothermic and reversible chemical system incorporated" Mater.Res.Soc.Proc.344. 301-306 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, T.Togawa, Y.Wada, T.Sano, and Y.Tamaura: "J.Kinetic study for the formation of cation-excess magnetite" Chem.Soc.Faraday Trans.91 [10]. 1533-1538 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, Y.Wada, T.Yamamoto, M.Tsuji and Y.Tamaura: "CO2 decomposition to carbon by ultrafine Ni (II) -bearing ferrite" Mater.Res.Bull.30 [8]. 1039-48 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Yamamoto, T.Kodama, N.Hasegawa, M.Tsuji, and Y.Tamaura: "Synthesis of hydrotalcite with high layr charge for CO2 adsorbent" Energy Convers.Mgmt.36 [6-9]. 637-640 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Wada, T.Yoshida, M.Tsuji and Y.Tamaura: "CO2 decomposition capacity of oxygen-deficient ferrites" Energy Convers.Mgmt.36 [6-9]. 641-644 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, Y.Wada, T.Yamamoto, M.Tsuji and Y.Tamaura: "Synthesis and characterization of ultrafine Ni (II) -bearing ferrites (NixFe3-xO4 ; x=0.14-1.0)" J.Mater.Chem.5 [9]. 1413-1418 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, T.Sano, M.Tabata, and Y.Tamaura: "Enhanced conversion of CO2 with a mixed system of metal oxide and carbon" Energy. 20 [9]. 869-876 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kato, T.Sano, Y.Wada, Y.Tamaura, M.Tsuji, T.Tsuji and S.Miyazaki: "Methanation of CO2 with the oxygen-deficient Ni (II) -ferrite under dynamic conditions" J.Mater.Sci.30. 6350-6354 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, M.Tabata, T.Sano, M.Tsuji, and Y.Tamaura: "XRD and Moessbauer studies on oxygen-deficient Ni (II) -bearing ferrite with a high reactivity for CO2 decomposition to carbon" J.Solid State Chem.120. 64-69 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, T.Sano, T.Yoshida, M.Tsuji and Y.Tamaura: "CO2-decomposition reactivity of ferrite-derived metallic phase" Carbon. 33 [10]. 1443-1447 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, Y.Wada, T.Kodama, HN.Hasegawa: "Endothermic and reversible reactions for a chemical heat pump" Proc.of Int.Sym.on Environmental Issues, on Ceramics 19-20,1994. 109-115 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Yoshida, H.Kato, M.Tsuji and Y.Tamaura: "Effect of platinum impregnationonto magnetite or Ni (II) -bearing toward the methanation of CO2" Proc.of Int.Sym.on Environmental Issues, on Ceramics 19-20,1994. 139-144 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Wada, M.Tabata, M.Tsuji and Y.Tamaura: "Decomposition of CO2 with oxygen-defficient spinel ferrites toward the methanation of CO2" Proc.of Int.Sym.on Environmental Issues, on Ceramics 119-20,1994. 145-153 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Kojima, T.Yoshida, M.Tsuji and Y.Tamaura: "Decomposition fo CO2 into carbon with Rh-, Pt- or Ce-impregnated Ni (II) -ferrite by H2-activation at 300C" Proc.of Int.Sym.on Environmental Issues, on Ceramics 19-20,1994. 154-160 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, Y.Wada, T.Yamamoto, T.Sano and Y.Tamaura: "CO2 decomposition by metallic phase on oxygen-deficient Ni (II) -bearing ferrite" J.Mater.Sci.Lett.15. 156-158 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, Y.Wada, Y.Tamaura, A.Steinfeld, P.Kuhn and R.Palumbo: "Coal gasification by the coal/CH4-ZnO-Zn-H2O solar energy conversion system" Energy Convers.Mgmt.37 [6-8]. 1315-1320 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Hasegawa, T.Yoshida, M.Tsuji and Y.Tamaura: "Integrated carbon recycling system for mitigation of CO2 emissions utilizing degraded thermal energy" Energy Convers.Mgmt.37 [6-8]. 1333-1338 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Sano, T.Togawa, M.Kojima, M.Tsuji and Y.Tamaura: "Thermal study for release of the lattice oxygen from carbon-bearing Ni (II) -ferrite" Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, Y.Wada, Y.Tamaura, A.Steinfeld, P.Kuhn, and R.D.Palumbo: "Coal gasification using the ZnO/Zn redox system" Energy Fuels. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Togawa, T.Sano, Y.Wada, T.Kodama, T.Yoshida, M.Tsuji and Y.Tamaura: "The effect of the crystal orientation on the rate of formation of the cation-excess magnetite" Solid State Ionics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Sano, N.Hasegawa, M.Tsuji and Y.Tamaura: "A carbon-bearing Ni (II) ferrite : a tailor-made solid reactant for two-step thermochemical water splitting at 300゚C" Journal of Materials Chemistry. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, T.Yamamoto, Y.Tamaura, T.Kodama and Y.Kitayama: "Catalytic acceleration for CO2 decomposition into carbon by Rh, Pt or Ce-impregnation onto Ni (II) -bearing ferrite" Applied Catalysis A : General. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, Y.Tamaura, A.Steinfeld and P.Kuhn: "The Solar-driven Coal-ZnO Redox System for CO2 Mitigation" Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tamaura, M.Tsuji, A.Steinfeld and P.Kuhn: "Coal/magnetite System for Mixing the Solar Energy into Fossil Energy" Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kodama, Y.Kitayama, M.Tsuji and Y.Tamaura: "Methanation of CO2 Using Ultrafine NixFe3-xO4 system" Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Sano, N.Hasegawa, M.Tsuji and Y.Tamaura: "A two-step thermochemical water splitting on a carbon-bearing Ni (II) ferrite at 300゚C" International J.of.Hydrogen Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Kojima, T.Sano, Y.Wada, T.Yamamoto, M.Tsuji and Y.Tamaura: "Thermochemical decomposition of H2O to H2 on cation-excess ferrite, submitted to J.Phys.Chem.Solids."

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Tsuji, T.Kodama, T.Yoshida, Y.Kitayama and Y.Tamaura: "Preparation and CO2 Methanation Activity of Ultrafine Ni (II) Ferrite Catalyst" J.Catal.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tamaura, Y.Wada and M.Tsuji, A.Steinfeld and P.Kuhn: "Temperature-programd Gasification of Coal with ZnO as the Oxidant" Fuels. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tamaura, N.Hasegawa, M.Kojima, T.Sano and M.Tsiji: "Stoichiometry of H2 evolution in the 2-step water splitting by a CIO-layrd Ni (II) -ferrite" International J.of Hydrogen Energy. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1997-03-04  

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