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1996 Fiscal Year Final Research Report Summary

Dynamics of the low-energy ion impact on the vander Warls thin films

Research Project

Project/Area Number 06453019
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionYamanashi University

Principal Investigator

HIRAOKA Kenzo  Yamanashi Univ.Fac.Eng.Professor, 工学部, 教授 (80107218)

Project Period (FY) 1994 – 1996
Keywordslow-energy ion impact / ion impact / vander Waals thin film / reflection TOFMS
Research Abstract

The study on the interactions between the low-energy ions and solid surface is of fundamental importance in the field of plasma technology and ion-beam technology. In this study, the dynamics of the low-energy ion impact on the van der Waals thin films were studied in detail. The newly designed reflectron-type TOF mass spectrometer was installed in the ultra-high vacuum chamber. The pulsed ion beam was injected into the van der Waals thin film deposited on the cold head of the cryocooler at 7 K.
When the film was bombarded by the He^+ ions, the cluster ions were hardly observed. Instead, fragment ions are formed with strong intensities. This is due to the fact that the kinetic energy of the small-size He^+ ion is mainly dissipated by the electronic excitation in the ion-solid collision events. In contrast, much more efficient momentum transfer takes place in the collision of Ne^+ with the solid films. The efficient momentum transfer in the collision events leads to the shock wave formation in the ion track. This results in the abundant cluster ion formation.
In sum, the holes and excitons formed in the matrix play very important roles in the secondary ion formatin.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 平岡賢三: "高速粒子による衝突活性化" J.Mass Spectrom.Soc.Jpn. 44. 577-624 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka,M.Nasu: "Bond energy oscillation in the cluster ion NO^+(NO)n" J.Chem. phys. 105. 9068-9071 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka,M.Nasu: "Gas-phase stahihity and structure of the clusxer ion CF_3^+(CO)n" J. Phys. Chem.100. 5245-5251 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka,A.Shimizu: "Gas,phase stahihity of clustir ions SFm^+(SF_6)n with m=0-5and n=1-3" Am Soc Mass Spectron. 6. 1137-1142 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka,S.Fukesawa: "Gas-phase positive and negativeion moleaule reactions in NF_3" J. phys. chem. 99. 15822-15829 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka,H.Fukasawa: "High flow liguid chromatography mass spectrometry interface" Rapid Commun.Mass Spetrom.9. 1349-1355 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hiraoka: "Collisional activation by fast atom fombardment" J.Mass Spectrom Soc.Jpn. 44. 577-624 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hiraoka, M.Nasu: "Bond energy asullition in the chorton ion NO^+ (NO) n" J.Chem.Phys.105. 9068-9071 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hiraoka, M.Nasu: "Gas-phase sfafility and structure of the cluster ion CF_3^+ (CO) n" J.Phys.Chem.100. 5245-5251 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hiraoka, A.Shimizu: "gas-phase sfafility of chuster ions SFm^+ (SF6) n with m=0-5 and n=1-3" Am.Soc.Mass Spectroml. 6. 1137-1142 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hiraoka, F.Fukasawa: "gas-phese positine and megafine ion moleaule reactions in NF_3" J.Phys.Chem.99. 15822-15829 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Hiraoka, H.Fukasawa: "High-flow bjoid chromatograply mass spectrometry in ferface" Ropid Commun Maes Speatron. 9. 1349-1355 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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