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1995 Fiscal Year Final Research Report Summary

Stuoltes on puparation and new reactivity of chiral ferroeeuylchaliogenides.

Research Project

Project/Area Number 06453136
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

UEMURA Sakae  Kyoto University, Graduate School of Engineering, Professor, 工学研究科, 教授 (70027069)

Co-Investigator(Kenkyū-buntansha) OHE Kouichi  Kyoto University, Graduate School of Engineering, Associate Professor, 工学研究科, 助教授 (90213636)
Project Period (FY) 1994 – 1995
Keywordsferrocene / hydrosilation / double chiral / organic dichalcogenide / sigmatropic rearraugenunt / charality tronsfer / asymnutric selenixide elminatron / asymmetric selenocyclization
Research Abstract

The following points were disclosed by this project.
1) Double chiral ferrocenyl chalcogenides (Fc^* EEFc^* ; E=S,Sc, Tc) were newly prepared.
2) New asymmetric selenoxide elminotron producring chral allenes and new [2,3] sigmatropic rearrangement prcducing chiral allylic alocohols and immes coere developed.
3) New asymmetric selenoogelizaation of olcfons was developed.
4) New and very effscient fanctronaloty of these chalcoyensdes for asymmetsic hychosilatron of pitones ovas disloscid as shral logends.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Uemura, S.: "Synthesis of [R, S; R, S]-and [S, R; S, R]-Bis[2-[1-(dimethylamino)ethyl]ferrocenyl]Diselenides and Their Application" J. Org. Chem.60. 4114-4120 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uemura, S.: "High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic Rearrangement" J. Chem. Soc., Chem. Commun.1243-1244 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uemura, S.: "Allylic Amine Formation by Imination of Allylic Tellurides" Tetrahedron Lett.36. 6725-6728 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uemura, S.: "Highly Selective Asymmetric Intramolecular Selemocyclization" J. Chem. Soc., Chem. Commun.2321-2322 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uemura, S.: "Synthesis of Chiral Diferocenyl Dicharcogenides and Their Application to Asymmetric Nucleophilic Ring Opening of meso-Epoxides" J. Chem. Soc., Perkin 1. 2871-2876 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Uemura, S.: "Novel Chiral Ligands, Diferrocenyl Dicharcogenides and Their Derivatives, for Rh-and Ir- Catalyzed Asymmetric Hydrosilylation" Organometallics. 15. 370-379 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sakae Uemura: "Sythesis of [R,S ; R,S] -and [S,R : S.R] -Bis [2- [1- (dimethylamino) ethyl] ferrocenyl] Diselenides and Their Application to Asyumnetcic Selenoxide Elimination and [2,3] Signatropic Rearrangement" J.Org.Chem.60. 4114-4120 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sakae Uemura: "High Chirality Transfer in Chiral Seleninides via [2,3] Sigmatropic Rearrangenent" J.Chem.Soc., Chem.Commun.1243-1244 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sakae Uemura: "Allylic Amine Formation by Imination of Allylic Tellurides" Tetrahedron Lett.36. 6725-6728 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sakae Uemura: "Highly Selective Asymmetric Intramolecular Selenocycligation" J.Chem.Soc., Shem.Commun.2321-2322 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sakae Uemura: "Synthesis of Chiral Diferrocenyl Dicharcogenides and Their Application to Asyometric Nucleophilic Ring Opening of meso-Epoxides" J.Chem.Soc., Perhin Trans.1. 2871-2876 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sakae Uemura: "Novel Chiral Ligands, Diferrocenyl Dicharcogenides and Their Derivatives, for Rhadium-and Iridium-Catalyzed Asuymmetric Hydrosilylation" Organometallics. 15. 370-379 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1997-03-04  

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