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1995 Fiscal Year Final Research Report Summary

In situ measurement of Phot-electronic Properties and Fabrication of Quantum Well Structures with Super Lattices of Dyes.

Research Project

Project/Area Number 06650955
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionTokyo Metropolitan University

Principal Investigator

SHIMURA Michiko  Tokyo Metropolitan University, Faculty of Engeneering, Asiistant Professor, 工学部・電子情報工学科, 助教授 (60087294)

Co-Investigator(Kenkyū-buntansha) OKUMURA Tsugunori  Tokyo Metropolitan University, Faculty of Engeneering, Professor, 工学部・電子情報工学科, 教授 (00117699)
Project Period (FY) 1994 – 1995
KeywordsEpitaxial growth / Phthalocyanine / Organic / inorganic built-up fi / Photocurrent / In situ measurement
Research Abstract

Molecular arrangement of functional dyes was investigated for fundamental study of fabrication of molecular devices using aluminum chloride phthalocyanine (AlPcCl) and aluminum fluoride phthalocyanine ( (AlPcF) _n). The sublimation of the dyes was carried out at ultra high vacumm on substrates such as alkali halide, silicon, or SiO_2 glass, which was kept at -120,25, or 180゚C.The obtained results are shown as the following.
(1) Regardless of the crystal structure and chemical properties, AlPcCl arranged with its molecular axis perpendicular to the substrate. On KCl (100), orientaion was (v10 x v10) 3.146 with the tilt angle of 27゚.
(2) Arrangement of (AlPcF) _n was controlled by the chemical nature of the substrate. On KCl (100), its molecular axis was perpendicular to the substrate surface and the arrangement was (v17 x v17) 3.146. On H-si (100) and H-Si (111) and SiO_2 glass, the molecular axis is parallel to the substrate.
(3) To obtain highly arranged phthalocyanine dyes, it was necessary to keep the substrate at 60-200゚C.

  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] 志村美知子、市川善隆、黒田淳一、奥村次徳: "超高真空中で作製したフタロシアニン系分子配向膜の電気的性質-その場測定による評価" 電気学会誌、A. 116. 12-17 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 志村美知子: "有機機能性分子の薄膜化技術" 表面技術. 45. 1189-1193 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. SHIMURA and T. OKUMURA: "Molecular Arrangement of Aluminum Halogenide Phthalocyanines." Memoris of Fac.Tech. , Tokyo Metropol. Univ.44. 4925-4930 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. SHIMURA, Y.Shimura,and T.OKUMURA: "ESR Study of Electrochromism in Phthalo-and Naphthalocyanines." The Electrochem. Soc. The 186th Extended Abstracts,. 94-2. 891-892 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 市川善隆、志村美知子、奥村次徳: "フタロシアニン分子配向膜の超高真空中における電気的・光学的性質" 信学技報. CME-4. 17-22 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.SHIMURA: "Preparation of Molecular Films" Soc.Surface Finishing. Vol.45, No.12. 1189-1193 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.SHIMURA,Y.ICHIKAWA,J.KURODA,and T.OKUMURA: "Electric Properties and the Molecular Orientation of Chloroaluminum Phthalocyanine Prepared in Situ in Ultra High Vacuum" T.IEE Japan. Vol.116-A,No.1. 12-17 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.SHIMURA,and T.OKUMURA: "Molecular Arrangement of Aluminum Halogenide Phthalocyanines" Memoirs of Fac.Tech. Tokyo Metropolitan Univ.No.44. 4925-4930 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.SHIMURA,Y.SHIMURA,and T.OKUMURA: "ESR Study of Electrochromism in Phthalo-and Naphthalocyanines" The Electrochem.Soc., The 186th Extended Abs.No.94-2. 891-892 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.ICHIKAWA,M.SHIMURA,and T.OKUMURA: "In Situ Measurement of Electric and Photo-electric Properties of AlPcCl Molecularly Arranged Films in Ultra-high Vacuum." Tech. Report of IEICE. OME95-4. 17-22 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1997-03-04  

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