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1995 Fiscal Year Final Research Report Summary

Synthese and application of highly efficient surface modifier bonded to dental material and tooth surface.

Research Project

Project/Area Number 06671931
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Conservative dentistry
Research InstitutionKanagawa Dental College

Principal Investigator

TERANAKA Toshio  Kanagawa Dental Coll. Dept.of Restorative Dent.Assoc.Prof., 歯学部, 助教授 (60104460)

Co-Investigator(Kenkyū-buntansha) NIHEI Tomotaro  Kanagawa Dental Coll.Dept.of Restorative Dent.Instructor, 歯学部, 助手 (50237781)
YOSHINO Norio  Science Univ.of Tokyo.Dept.of Industrial Chem.Assoc.Prof., 工学部, 助教授 (50084380)
Project Period (FY) 1994 – 1995
KeywordsSilane Coupling Agent / Poly (fluoro) alkyl Silane / Surface Modification / Resin Composite / Prevention of Contamonation / Prevention of Plaque Accumulation / プラーク付着防止
Research Abstract

The objectives of this research project were 1) to evaluate the effectiveness of the surface modifier (1H,1H,2H,2H-henicosafluorododecyl) trimethoxysilane (10F2S-3M) for the prevention of staining, 2) to improve the water resistance of the polysiloxane at the silica-resin interfaceface and 3) to demonstrate the plaque formation inhibiting ability and the plaque detachment efficacy of 10F2S-3M.
The results obtained were as follows :
1. Significant large contact angles were displayd on all specimens modified with 10F2S-3M compared with those of untreated ones irrespective of the immersing solutions and the storage periods. The contact angles of all groups were significantly decreased after storage, though remarkable increases were shown after ultrasonic cleansing of the experimental (surface modified) groups stored in tea extract and oil orange. Significant slow progres of staining of the treated groups was apparent compared with that of the control group. Although the stains adhering to t … More he treated specimens were easily removed by ultrasonic cleansing, the stains adhering to the untreated specimens were difficult to remove. Treatment with the surface modifier did not affect the surface hardness and roughness.
2. The tensile bond strength of the resin composite to the glass surface treated with a mixture of 3-MPS and 20-40% of trifluoropropyl- and nonafluorohexyl-trimethoxysilane showed significantly high values compared with 3-MPS treated specimen. These mixed silanes demostnrated stable bond strength, excellent waterproofness and thermotensile resistance. Also the maximum value of the surface free energy was displayd at the concentration of 20-40% of trifluoropropyl- and nonafluorohexyl-trimethoxysilane.
3. The amount of adhead bacteria on the modified glass surface was significantly less than the native one. The amount of detached bacteria from the PTFE and modified glass and resin composite was approximately 50% at the first 10w 10s ultrasonic cleansing, while the native ones showed approx. 30%. After the final cleansing, the remaining bacteria on the PTFE and modified glass and composite were less than 1%, while the native specimens showed 35-40%. 10F2S-3M significantly decreased the surface free energy of the glass and composite to a comparable state to the PTFE.
From the results obtained in this research project, it was suggested that the surface modification of resin composite with 10F2S-3M may have a high preventive effect on contamination of restoration intraorally and was concluded that the modification of silica surface with a mixture of 3-MPS and trifluoropropyl- or nonafluorohexyl-trimethoxysilane should improve the water resistance of the polysiloxane at the silica-resin interface. Less

  • Research Products

    (13 results)

All Other

All Publications (13 results)

  • [Publications] 松本好文: "フルオロカーボン鎖を持つシランカップリング剤によるコンポジットレジンの着色抑制効果" 日本歯科保存学会誌. 39. 197-209 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 山中秀起: "ポリフロオロアルキリシラン混合シランカップリング剤の接着強さと耐水性向上" 日本歯科保存学会誌. 39. 221-227 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 荻原早紀子: "フッ化炭素鎖を含む表面処理剤で改質したコンポジットレジンに対するプラーク付着性と脱離性" 日本歯科保存学会誌. 38. 1071-1081 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 好野則夫: "フッ化炭素鎖を有するシランカップリング剤を用いたガラスの表面改質-鎖長の異なるシランカップリング剤混合物による改質ならびに改質溶媒に関する検討-" 材料技術. 13. 304-408 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 好野則夫: "フッ化炭素鎖を有するシランカップリング剤を用いた金属表面の改質" 材料技術. 13. 55-59 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 寺中敏夫: "Application of Newly Developed Surface Modifier to Dental Material" Bull Kanagawa Dental Coll. 22. 151-156 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Teranaka T,Iwamoto T,Yoshino N.: "Application of newly developed surface modifier to dental material." Bull Kanagawa Dental Coll. 22-2. 151-156 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yoshino N,Chino S,Nakaseko H,Ogihara S,Okada S,Iwamoto T,Teranaka T.: "Surface modification of metals by using silane coupling agents containing fluorocarbone chain." Jpn Res Inst Mater Tech. 13-2. 55-59 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yoshino N,Sakama K,Nakaseko H,Kondo Y,Ogihara S,Okada S,Iwamoto T,Teranaka T.: "Surface modification of glass by use of silane coupling agents containing fluorocarbone chain. -Modification by mixed silane solution and effect of solvent used-" Jpn Res Inst Mater Tech. 13-10. 304-308 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Ogihara S,Teranaka T,Kumada H,Yoshino N.: "Effect of a fluorocarbon chain containing silane coupling agent on accumulation and detachment of Streptococcus mutans on and from resin composite in vitro." Jpn J Consev Dent. 38-4. 1071-1081 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Matsumoto Y,Teranaka T,Yoshino N.: "Stain inhibitory effect on resin composite modified by silane coupling agent containing fluorocarbon chain." Jpn J Consev Dent. 39-1. 196-208 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yamanaka H,Teranaka T,Kurata S,Yoshino N.: "Improvement of bond strength and water resistance of silane coupling agent containing poly (fluoro) -alkyltrimethoxysilane." Jpn J Consev Dent. 39-1. 218-226 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Nihei T,Ogihara S,Okada S,Teranaka T,Iwamoto T,Yoshino N: "Effect of a fluorocarbon chain containing silane modifier on resin composite surface character and water sorption." Jpn J Consev Dent. (in press).

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      「研究成果報告書概要(欧文)」より

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Published: 1997-03-04  

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