1995 Fiscal Year Annual Research Report

NOxの除去を目指した高活性な光触媒反応系の設計

Research Project

Project/Area Number	07044162
Research Institution	Osaka Prefecture University
Principal Investigator	安保正一大阪府立大学, 工学部, 教授 (70094498)
Co-Investigator(Kenkyū-buntansha)	GIAMELLO Eli イタリアトリノ大学, 助教授 COLUCCIA Sal イタリアトリノ大学, 教授 LOUIS Cather フランス触媒研究所, 主任研究員 CHE Michel フランスパリ第6大学, 教授山下弘巳大阪府立大学, 工学部, 助教授 (40200688)
Keywords	光触媒 / NOx分解 / 銅イオン / ゼオライト / EXAFS測定 / ESR測定 / FT-IR測定 / ホトルミネッセンス
Research Abstract	イオン交換法やゾル-ゲル法によりZSM-5ゼオライトやシリカゲルに高分散状態で担持した(Cu^+/ZSM-5)や(Ag^+/ZSM-5)触媒を調製した。また、それらのキャラクタリゼーションを、ESR、FT-IR、ラマン、ホトルミネッセンス分光法により行い、Cuイオンの配位構造を明らかにした。(Cu^+/ZSM-5)や(Ag^+/ZSM-5)触媒上でのNOxの吸着状態をESR、FT-IR、TPD法などのテクニックを利用して検討した。また、これらの調製された触媒を用い、NOxの光触媒分解反応を常温下で行い、反応生成物をガスクロ、マスで検討し、NOxの光触媒反応収率におよぼすCuイオンおよびAgイオンの配位構造の影響を明らかにした。パリにおいては、(Cu^+/ZSM-5)と(Ag^+/ZSM-5)触上のEXAFSを測定し、Cuイオンの配位数と配位構造を明らかにした。トリノでは(Cu^+/ZSM-5)と(Ag^+/ZSM-5)触媒でのNOxの吸着状態を、NOの同位体を用いESRとFT-IRで検討し明らかにした。これらの成果は、アメリカ化学会研究発表会に参加し発表した。

Research Products
(23 results)

All Other

All Publications (23 results)

[Publications] Masakazu Anpo: "Approach to Photocatalysis at the Molecular Level : Design of Photocatalysts,Detection of Intermediate species,and Reaction Mechanism." Solar Energ.Mater.Solar Cells.38. 221-238 (1995)
[Publications] Masakazu Anpo: "ESR,XPS,UV-VIS and FT-IR Investigation on the Interaction of NO and O_2 with Dispersed C_<60> Supported on Silica,Titanium and Alkali Cation-exchanged Y-zeolites" Res.Chem.Intermedi.21. 631-639 (1995)
[Publications] Masakazu Anpo: "The Photocatalytic Reduction of CO_2 with H_2O on Titanium Oxide Catalysts." Sekiyu Gakkaishi. 38. 300-310 (1995)
[Publications] Masakazu Anpo: "Photocatalytic reduction of CO_2 with H_2O on Various Titanium Oxide Catalysts" J.Electroanal.Chem.396. 21-26 (1995)
[Publications] Hiromi Yamashita: "Photocatalytic Synthesis of CH_4 and CH_3OH From CO_2 and H_2O on Highly Dispersed Active Titanium Oxide Catalysts" Energy.Conv.Manag.36. 617-620 (1995)
[Publications] Sang-Chul Moon: "The Photocatalytic Isomerization of 2-Butenes on ZrO_2 Catalyst with Low Coordinated Surface Sites" Chem.Lett.447-448 (1995)
[Publications] Masaya Matsuoka: "The Photocatalytic Decomposition of Nitric Oxide on the Silver (I) Ion-exchanged ZSM-5 Catalyst" Chem.Lett.375-376 (1995)
[Publications] Hiroyasu Nishiguchi: "Photophysical and Photochemical Processes in Zeolite Cavities : The effect of Ion-exchanged Alkali Metal Cations on the Excited States of Xanthone and the Photolysis of 2-Pentanone" Res.Chem.Intermedi.21. 885-898 (1995)
[Publications] Hiroyasu Nishiguchi: "The effect of Ion-exchanged Alkali Metal Cations on the Excited States of Xanthone and the Photolysis of 2-Pentanone Included within the Zeolite Cavities" J.Photochem.Photobiol,A : Chem.92. 85-90 (1995)
[Publications] M.C.Martinez: "Metal-Support Interaction in Pt/C Catalysts.Influence of the Support Surface Chemistry and the Metal Precursor" Carbon. 33. 3-15 (1995)
[Publications] S.Tanaka: "CO_2 Gasification of Iron-Loaded Carbons : Activation of the Iron Catalyst with CO" Energy & Fuels. 9. 45-52 (1995)
[Publications] 文相吉: "酸化ジルコニウム上での触媒反応および光触媒反応における配位不飽和サイトの役割" 触媒. 37. 132-135 (1995)
[Publications] Tsuneo Fujii: "Influence of Pore Size on the Intensity of the Monomer and Excimer-like Fluorescence of Pyrene Adsorbed onto Porous Glasses" J.Photochem.Photobiol,A : Chem.86. 219-225 (1995)
[Publications] 山下弘巳: "超微粒子半導体の光触媒・光表面反応" 表面科学. 16. 194-200 (1995)
[Publications] 松岡雅也: "ゼオライト細孔内での光触媒反応(1)金属イオンを光り触媒とするNOx分解反応" 表面. 33. 773-781 (1995)
[Publications] Tsuneo Fujii: "Characteristic Changes in the Fluorescence Spectra of 1-Naphthol at the Gelation Point of the Sol-Gel Xerogel Transitions" Res.Chem.Intermedi.Vol.21. 643-654 (1995)
[Publications] Tsuneo Fujii: "Fluorescence Spectra of Methyl Salicylate During the Sol Gel Xerogel Transitions of Mixed Si-Al Alkoxides" J.Chem.Soc,Faraday Trans.91. 4285-4279 (1995)
[Publications] Hiromi Yamashita: "In Situ XAFS,Photoluminescence,and IR Investigtions of Copper Ions Included within Various Kinds of Zeolites" J.Phys.Chem.100. 397-402 (1996)
[Publications] Hiromi Yamashita: "Photocatalytic Degradation of 1-Octanol on Anchored Titanium Oxide and on TiO_2 Powder Catalysts" J.Catal.158. 97-101 (1996)
[Publications] Masaya Matsuoka: "The Photocatalytic Decomposition of Nitric Oxide on Ag^+/ZSM-5 Catalyst Prepared by Ion-Exchang" J.Mol.Catal.(in press). (1996)
[Publications] Masakazu Anpo: "In Situ Investigations of the Photocatalytic Decomposition of NOx on Ion-exchanged Silver (I) ZSM-5 Catalysts" Catal.Today. (in press). (1996)
[Publications] Hiromi Yamashita: "Science & Technology Catalysis" Kodansha, 467 (1995)
[Publications] Masakazu Anpo: "Surface Photochemistry" John Wiley & Sons Ltd, 174 (1996)

1995 Fiscal Year Annual Research Report

NOxの除去を目指した高活性な光触媒反応系の設計

Principal Investigator

安保 正一 大阪府立大学, 工学部, 教授 (70094498)

Research Products

[Publications] Masakazu Anpo: "Approach to Photocatalysis at the Molecular Level : Design of Photocatalysts,Detection of Intermediate species,and Reaction Mechanism." Solar Energ.Mater.Solar Cells.38. 221-238 (1995)

[Publications] Masakazu Anpo: "ESR,XPS,UV-VIS and FT-IR Investigation on the Interaction of NO and O_2 with Dispersed C_<60> Supported on Silica,Titanium and Alkali Cation-exchanged Y-zeolites" Res.Chem.Intermedi.21. 631-639 (1995)

[Publications] Masakazu Anpo: "The Photocatalytic Reduction of CO_2 with H_2O on Titanium Oxide Catalysts." Sekiyu Gakkaishi. 38. 300-310 (1995)

[Publications] Masakazu Anpo: "Photocatalytic reduction of CO_2 with H_2O on Various Titanium Oxide Catalysts" J.Electroanal.Chem.396. 21-26 (1995)

[Publications] Hiromi Yamashita: "Photocatalytic Synthesis of CH_4 and CH_3OH From CO_2 and H_2O on Highly Dispersed Active Titanium Oxide Catalysts" Energy.Conv.Manag.36. 617-620 (1995)

[Publications] Sang-Chul Moon: "The Photocatalytic Isomerization of 2-Butenes on ZrO_2 Catalyst with Low Coordinated Surface Sites" Chem.Lett.447-448 (1995)

[Publications] Masaya Matsuoka: "The Photocatalytic Decomposition of Nitric Oxide on the Silver (I) Ion-exchanged ZSM-5 Catalyst" Chem.Lett.375-376 (1995)

[Publications] Hiroyasu Nishiguchi: "Photophysical and Photochemical Processes in Zeolite Cavities : The effect of Ion-exchanged Alkali Metal Cations on the Excited States of Xanthone and the Photolysis of 2-Pentanone" Res.Chem.Intermedi.21. 885-898 (1995)

[Publications] Hiroyasu Nishiguchi: "The effect of Ion-exchanged Alkali Metal Cations on the Excited States of Xanthone and the Photolysis of 2-Pentanone Included within the Zeolite Cavities" J.Photochem.Photobiol,A : Chem.92. 85-90 (1995)

[Publications] M.C.Martinez: "Metal-Support Interaction in Pt/C Catalysts.Influence of the Support Surface Chemistry and the Metal Precursor" Carbon. 33. 3-15 (1995)

[Publications] S.Tanaka: "CO_2 Gasification of Iron-Loaded Carbons : Activation of the Iron Catalyst with CO" Energy & Fuels. 9. 45-52 (1995)

[Publications] 文相吉: "酸化ジルコニウム上での触媒反応および光触媒反応における配位不飽和サイトの役割" 触媒. 37. 132-135 (1995)

[Publications] Tsuneo Fujii: "Influence of Pore Size on the Intensity of the Monomer and Excimer-like Fluorescence of Pyrene Adsorbed onto Porous Glasses" J.Photochem.Photobiol,A : Chem.86. 219-225 (1995)

[Publications] 山下弘巳: "超微粒子半導体の光触媒・光表面反応" 表面科学. 16. 194-200 (1995)

[Publications] 松岡雅也: "ゼオライト細孔内での光触媒反応(1)金属イオンを光り触媒とするNOx分解反応" 表面. 33. 773-781 (1995)

[Publications] Tsuneo Fujii: "Characteristic Changes in the Fluorescence Spectra of 1-Naphthol at the Gelation Point of the Sol-Gel Xerogel Transitions" Res.Chem.Intermedi.Vol.21. 643-654 (1995)

[Publications] Tsuneo Fujii: "Fluorescence Spectra of Methyl Salicylate During the Sol Gel Xerogel Transitions of Mixed Si-Al Alkoxides" J.Chem.Soc,Faraday Trans.91. 4285-4279 (1995)

[Publications] Hiromi Yamashita: "In Situ XAFS,Photoluminescence,and IR Investigtions of Copper Ions Included within Various Kinds of Zeolites" J.Phys.Chem.100. 397-402 (1996)

[Publications] Hiromi Yamashita: "Photocatalytic Degradation of 1-Octanol on Anchored Titanium Oxide and on TiO_2 Powder Catalysts" J.Catal.158. 97-101 (1996)

[Publications] Masaya Matsuoka: "The Photocatalytic Decomposition of Nitric Oxide on Ag^+/ZSM-5 Catalyst Prepared by Ion-Exchang" J.Mol.Catal.(in press). (1996)

[Publications] Masakazu Anpo: "In Situ Investigations of the Photocatalytic Decomposition of NOx on Ion-exchanged Silver (I) ZSM-5 Catalysts" Catal.Today. (in press). (1996)

[Publications] Hiromi Yamashita: "Science & Technology Catalysis" Kodansha, 467 (1995)

[Publications] Masakazu Anpo: "Surface Photochemistry" John Wiley & Sons Ltd, 174 (1996)

安保正一大阪府立大学, 工学部, 教授 (70094498)