1995 Fiscal Year Annual Research Report

有機非線形光学材料による光波マニピュレーション

Research Project

Project/Area Number	07246104
Research Category	Grant-in-Aid for Scientific Research on Priority Areas
Research Institution	Tokyo University of Agriculture and Technology
Principal Investigator	宮田清蔵東京農工大学, 大学院生物システム応用科学研究科, 教授 (90015066)
Co-Investigator(Kenkyū-buntansha)	雀部博之理化学研究所, 主任研究員 (20015126) 谷田貝豊彦筑波大学, 物理工学系, 教授 (90087445) 佐々木孝友大阪大学, 工学部, 教授 (50029237) 中西八郎東北大学, 反応化学研究所, 教授 (50240651) 伊藤良一東京大学, 工学部, 教授 (40133102)
Keywords	非線形光学効果 / 光波マニピュレーション / 有機材料 / 波長変換 / 光変調 / フォトリフラクティブ効果 / 位相 / 波面
Research Abstract	我々は10年ほど前から、それぞれ独立に有機非線形光学材料に関する研究を行ってきた。しかし、実際の素子化に対しては、1人の研究者にとってあまりにも研究の幅が広すぎると感じていた。そこで日本における最もアクティブな研究者が従来の垣根を取り払いアイデア、試料、ファブリケーションのノウハウをお互いに提供し合わなければならないという結論にいたった。本申請領域研究においては、(1)波長のマニピュレーション、(2)振幅のマニピュレーション、(3)波面のマニピュレーション、の3分野について研究を推進し、新材料創製→新プロセス技術開発→デバイス設計を一貫してできるよう、各研究グループの間の調整を行うと共に、従来までの研究成果をデータベース化して研究情報を各グループが円滑にアクセスできる新システムを開発することを目的とした。総括班は領域全体での研究の取りまとめと評価を行うのみならず、全体会議、班会議、、電子メール、広報を通じて各研究グループと密接に連絡を取り、分子設計および合成とデバイス作製に関する研究の進展状況を迅速に参加者全体にフィーバックした。また、各研究者が現在の非線形光学材料や素子技術について簡単に情報が得られるように非線形光学材料データベースを作製した。文献ソースとしてはケミカルアブストラクトより1次資料を抽出し、それらより抜き出した2次資料からデータの加工・分析、単位変襖、図麦入力等を行った。リレーショナルデータベースを用いて非線形光学材料の構造、非線形光学定数、屈折率、測定法、デバイスの概要などがキーワードや物質名、研究者名より単純に検索できるようにした。また、測定に用いた参照物質の非線形光学定数を統一することにより、これまで簡単に比較できなかった非線形光学定数の大小関係をきちんと評価できるようになった。今年度までに蓄えた情報をCDロム化すると共に、次年度以降にはこのデータベースをインターネット対応にし、アップデ-トな情報がいつも引き出せるようにする予定である。

Research Products

(40 results)

All Other

All Publications (40 results)

[Publications] H.Abe,Rikukawa,K.Sanui,T.Watanabe and S.Miyata: "Synthesis and Nonlinear Optical Properties of Poly(γ-Methyl L-Glutamate)s having Nitrostilbene Dyes as Side Chains(I)" Nonlinear Optics. 14. 91-96 (1995)
[Publications] M.Talukder,S.Fujita,T.Watanabe and S.Miyata: "Study on Conformations of Polymeric Langmuir-Blodgett Films Prepared by using Kuhn Type and Moving-Wall Type Deposition Systems" Nonlinear Optics. 15. 77-80 (1996)
[Publications] X.T.Tao,T.Watanabe,H.Ukuda and S.Miyata: "Phase-Matched Seccond-Harmonic Generation in Poled Polymers by use of Birefringence" J.Opt.Soc.Am.12. 1581-1585 (1995)
[Publications] H.S.Nalwa,T.Watanabe and S.Miyata: "2-D Charge-Transfer Molecules for Second-Order NLO:Off-Diagonal Orientation" Adv.Mater.7. 754-758 (1995)
[Publications] X.T.Tao,T.Watanabe,H.Ssto and S.Miyata: "Polyurea wiht Large Positive Birefringence for Second Harmonic Generation" Macromolecules. 28. 2673-2643 (1995)
[Publications] T.Furukawa,K.Ishikawa,T.Watanabe,S.Miyata,J.Watanabe: "Highly-SHG-Active Nematic Liquid Crystal Formed From Aromatic Polyester" Nonlinear Optics. 15. 167-170 (1996)
[Publications] T.Kondo,F.Akase,M.Kumagai and R.Ito: "Linear and Nonlinear Optical Properties of Racemic(±)2-(α-Methylvenzylamion)-5-Nitropyridine Single Crystals" Opt.Rev.2. 128 (1995)
[Publications] N.Hashizume,M.Ohashi,T.Kondo and R.Ito: "Design of Optimal Phase-Only Filters by Direct Iterative Search" J.Opt.Soc.Am.B12. 1894 (1995)
[Publications] A.Kitamoto,T.Kondo,I.Shoji and R.Ito: "Absolute Mesurement of Second-Order Nonlinear Optical Coefficient of LiNbO_3 by Parametric Processes" Opt.Rev.2. 280 (1995)
[Publications] X.Zhang,K.Karaki,H.Yaguchi,K.Onabe,R.Ito: "Optical Property of GaAsP/AlGaAs Strained-layer Quantum Well Growm on GaAs-(III)B Substrate" Appl.Phys.Lett.66. 186-188 (1995)
[Publications] W.Pan,H.Yaguchi,K.Onabe,Y.Shiraki,R.Ito: "Tensile -strained GaAsP/AlGaAs Quantum Wells Grown by Low-pressure Metalorganic Vapor Phase Epitaxy" J.Appl.Phys.78. 3517 (1995)
[Publications] W.Pan,H.Yaguchi,K.Onabe,Y.Shiraki,R.Ito: "Composition Profile of AlGaAs Epilayer on a V-grooved Substrate Grown by Low-pressure Metalorganic Vapor Phase Epitaxy" Appl.Phys.lett.67. 959 (1995)
[Publications] X.-M.Duan,S.Okada,H.Oikawa,H.Matsuda and H.Nakanishi: "Second-Order Hyperpolarizabilities of Organic Ionic Species" Mol.Cryst.Liq.Cryst.267. 89-94 (1995)
[Publications] X.-M.Duan,T.Kimura,S.okada,M.Kato and H.Nakanishi: "Second Order Hyoperpolarizabilities of Aromatic Carboxylates without Visible Absorption" Jpn.J.Appl.Phys.34. L1161-L1163 (1995)
[Publications] S.Hasidate,Y.Nagasaki,M.Kato,H.Nakanishi: "Photocrosslinkable Second-Order Nonlinear Optical Polymers Synthesized by Cationic Copolymerization" Polym.Adv.Technol.6. 626-631 (1995)
[Publications] X.-M.Duan,S.Okada,H.Oikawa,H.Matsuda and H.Nakanishi: "Comparatively Large Second-Order Hyperpolarizabilities of Aromatic Ions with Short Cutoff Wavelength" Nonlinear Opt.(in press).
[Publications] X.-M.Duan,T.Kimura,S.Okada,M.Kato and H.Nakanishi: "Organic Species with Short Cutoff Wavelength and Large Second-Order Hyperpolarizabilities" Mol.Cryst.Lig.Cryst.(in press).
[Publications] M.Kato,K.Kanda,T.Kimura,H.Matsuda and H.Nakanishi: "Synthsis of Polymers Bearing Azo-Dye Chromophore with Photocrosslinkable Moiety for Nonlinear Optics" Polym.Bull.(in press).
[Publications] H.Minemoto,Y.Ozaki,K.Wakita and T.Sasaki: "Intracavity Second-Harmonic Generation and Influence of Optical Loss of Organic Nonlinear Optical Materials" Jpn.J.Appl.Phys.34. 497-503 (1995)
[Publications] Y.Mori,I.Kuroda,S.Nakajima,T.Sasaki and S.Nakai: "Nonlinear Optical Properties of Cesium Lithium Borate" Jpn.J.Appl.Phys.34. 296-298 (1995)
[Publications] W.L.Zhou,Y.Mori,T.Sasaki,S.Nakai,K.Nkano and B.Craig: "Intracavity frequency doubiling of a continuous wave Ti:sapphire laser with over 70% conversion efficiency" Appl.Phys.Lett.66. 2463-2465 (1995)
[Publications] Wang-Long Zhou,Y.Mori,T.Sasaki and S.Niikura: "High-Efficiency Intracavity Frequency-Doubled CW and Tunable Ti:Sapphire Laser" Jpn.J.Appl.Phys.34. 3518-3521 (1995)
[Publications] Y.Mori,I.Kuroda,S.Nakajima,T.Sasaki and S.Nakai: "New nonlinear optical crystal:Cesium lithium borate" Appl.Phys.Lett.67. 1818-1820 (1995)
[Publications] 佐々木孝友: "新固体レーザー材料と非線形光学結晶" 応用物理. 64. 878-887 (1995)
[Publications] M.Itoh,R.Yamada,R.Tian,M.Tsai and T.Yatagai: "Broad-Band Light-Wave Correlation Topography Using Wavelet Transform" Opt.Rev.2. 135-138 (1995)
[Publications] J.Ding,M.Itoh and T.Yatagai: "Desing of Optimal Phase-Only Filters by Direct Iterative Search" Opt.Commun.118. 90-101 (1995)
[Publications] N.Yoshikawa,M.Itoh and T.Yatagai: "Quantized Phase Optimization of Two-Dimensional Fourier Kinoforms by Generic Aigorithm" Opt.Lett.20. 752-754 (1995)
[Publications] H.Huang,M.Itoh and T.Yatagai: "Optical Module for Modified Signed-Digit Computing Based on Bit Plane Encoding and Pattern Operations" Opt.Rev.2. 255-260 (1995)
[Publications] N.Yoshikawa,M.itoh and T.Yatagai: "Interpolation of Reconstructed Image in Fourier Transform Computer-Generated Hologram" Opt.Commun.119. 33-40 (1995)
[Publications] X.Tian,M.Itoh and T.Yatagai: "Simple Algorithm for Large-Grid Phase Reconstruction of Lateral-Shearing Interforometry" Appl.Opt.34. 7213-7220 (1995)
[Publications] Liu Y.,Xu Y.,Zhu D.,Wada T.,Sasabe H.,Zhao X.,and Xie X.: "Optical Xecond-Harmonic Generation from Langmuir-Blogett Films of an Asymmetrically Substituted Phthalocyanine" J.Phys.Chem.99. 6957-6960 (1995)
[Publications] Okawa H.,Wada T.,and Sasabe H.: "Linear and Nonlinear Optical Properties of Thin Films of Poly(2-pyridylacetylene)s" Synthetic Metals. 71. 1657-1658 (1995)
[Publications] Zhang Y.-D.,Wang L.,Wada T.,and Sasabe H.: "Molecular Design of Novel Main-Chain Biscarbazoly l Polymers for Nonlinear Optics" Mol.Cryst.Liq.Cryst.267. 65-70 (1995)
[Publications] Wada T.,Zhang Y.-D.,Wang L.,and Sasabe H.: "Carbazole Oligomers for Nonlinear Optics" Nonlinear Optics. 9. 267-273 (1995)
[Publications] Kitazawa M.,Ryoichi H.,Wada T.and Sasabe H.: "Novel Amino Acid Crystals for Phase-Matched Second-Harmonic Generation" J.Appl.Phys.78(2). 709-717 (1995)
[Publications] Higuchi H.,Nakayama T.,Wada T.and Sasabe H.: "Synthesis and Properties of a,w-Disubsituted Oligo(3-hyxylthiophene)s and Oligothienoquinonoids in Head-to-head Orientation" Bull.Chem.Soc.Jpn.68. 2363-2377 (1995)
[Publications] T.Watanabe,S.Miyata and H.S.Nalwa: "Ferroelectric Polymers" Nonlinear Optical Properties of Ferroelectric Polymers, (1995)
[Publications] T.Kondo and R.Ito: "Nonlinear Opt." A Comprehensive Study on Nonlinear Optical Properties of Chiral and Racemic2-(α-Methylvenzylamion)-5-Nitoropyridine Crystals, (1995)
[Publications] H.Yaguchi,S.Miyoshi,H.Arimoto,S.Saito and R.Ito: "Inst.Phys.Conf.Ser." Time-resolved Photoluminescence Study of Radiative Transition Processes in GaP_<3-x>N_x Alloys, (1995)
[Publications] Wada T.,Hosoda M.,Okawa H.,Terasaki A.and Sasabe H.: "Enrico Fermi" Molecular Design of Third-Order Nonlinear Optically Active p-Conjugated Compounds and Preparation of Thin Films, (1995)

1995 Fiscal Year Annual Research Report

有機非線形光学材料による光波マニピュレーション

Principal Investigator

宮田 清蔵 東京農工大学, 大学院生物システム応用科学研究科, 教授 (90015066)

Research Products

[Publications] H.Abe,Rikukawa,K.Sanui,T.Watanabe and S.Miyata: "Synthesis and Nonlinear Optical Properties of Poly(γ-Methyl L-Glutamate)s having Nitrostilbene Dyes as Side Chains(I)" Nonlinear Optics. 14. 91-96 (1995)

[Publications] M.Talukder,S.Fujita,T.Watanabe and S.Miyata: "Study on Conformations of Polymeric Langmuir-Blodgett Films Prepared by using Kuhn Type and Moving-Wall Type Deposition Systems" Nonlinear Optics. 15. 77-80 (1996)

[Publications] X.T.Tao,T.Watanabe,H.Ukuda and S.Miyata: "Phase-Matched Seccond-Harmonic Generation in Poled Polymers by use of Birefringence" J.Opt.Soc.Am.12. 1581-1585 (1995)

[Publications] H.S.Nalwa,T.Watanabe and S.Miyata: "2-D Charge-Transfer Molecules for Second-Order NLO:Off-Diagonal Orientation" Adv.Mater.7. 754-758 (1995)

[Publications] X.T.Tao,T.Watanabe,H.Ssto and S.Miyata: "Polyurea wiht Large Positive Birefringence for Second Harmonic Generation" Macromolecules. 28. 2673-2643 (1995)

[Publications] T.Furukawa,K.Ishikawa,T.Watanabe,S.Miyata,J.Watanabe: "Highly-SHG-Active Nematic Liquid Crystal Formed From Aromatic Polyester" Nonlinear Optics. 15. 167-170 (1996)

[Publications] T.Kondo,F.Akase,M.Kumagai and R.Ito: "Linear and Nonlinear Optical Properties of Racemic(±)2-(α-Methylvenzylamion)-5-Nitropyridine Single Crystals" Opt.Rev.2. 128 (1995)

[Publications] N.Hashizume,M.Ohashi,T.Kondo and R.Ito: "Design of Optimal Phase-Only Filters by Direct Iterative Search" J.Opt.Soc.Am.B12. 1894 (1995)

[Publications] A.Kitamoto,T.Kondo,I.Shoji and R.Ito: "Absolute Mesurement of Second-Order Nonlinear Optical Coefficient of LiNbO_3 by Parametric Processes" Opt.Rev.2. 280 (1995)

[Publications] X.Zhang,K.Karaki,H.Yaguchi,K.Onabe,R.Ito: "Optical Property of GaAsP/AlGaAs Strained-layer Quantum Well Growm on GaAs-(III)B Substrate" Appl.Phys.Lett.66. 186-188 (1995)

[Publications] W.Pan,H.Yaguchi,K.Onabe,Y.Shiraki,R.Ito: "Tensile -strained GaAsP/AlGaAs Quantum Wells Grown by Low-pressure Metalorganic Vapor Phase Epitaxy" J.Appl.Phys.78. 3517 (1995)

[Publications] W.Pan,H.Yaguchi,K.Onabe,Y.Shiraki,R.Ito: "Composition Profile of AlGaAs Epilayer on a V-grooved Substrate Grown by Low-pressure Metalorganic Vapor Phase Epitaxy" Appl.Phys.lett.67. 959 (1995)

[Publications] X.-M.Duan,S.Okada,H.Oikawa,H.Matsuda and H.Nakanishi: "Second-Order Hyperpolarizabilities of Organic Ionic Species" Mol.Cryst.Liq.Cryst.267. 89-94 (1995)

[Publications] X.-M.Duan,T.Kimura,S.okada,M.Kato and H.Nakanishi: "Second Order Hyoperpolarizabilities of Aromatic Carboxylates without Visible Absorption" Jpn.J.Appl.Phys.34. L1161-L1163 (1995)

[Publications] S.Hasidate,Y.Nagasaki,M.Kato,H.Nakanishi: "Photocrosslinkable Second-Order Nonlinear Optical Polymers Synthesized by Cationic Copolymerization" Polym.Adv.Technol.6. 626-631 (1995)

[Publications] X.-M.Duan,S.Okada,H.Oikawa,H.Matsuda and H.Nakanishi: "Comparatively Large Second-Order Hyperpolarizabilities of Aromatic Ions with Short Cutoff Wavelength" Nonlinear Opt.(in press).

[Publications] X.-M.Duan,T.Kimura,S.Okada,M.Kato and H.Nakanishi: "Organic Species with Short Cutoff Wavelength and Large Second-Order Hyperpolarizabilities" Mol.Cryst.Lig.Cryst.(in press).

[Publications] M.Kato,K.Kanda,T.Kimura,H.Matsuda and H.Nakanishi: "Synthsis of Polymers Bearing Azo-Dye Chromophore with Photocrosslinkable Moiety for Nonlinear Optics" Polym.Bull.(in press).

[Publications] H.Minemoto,Y.Ozaki,K.Wakita and T.Sasaki: "Intracavity Second-Harmonic Generation and Influence of Optical Loss of Organic Nonlinear Optical Materials" Jpn.J.Appl.Phys.34. 497-503 (1995)

[Publications] Y.Mori,I.Kuroda,S.Nakajima,T.Sasaki and S.Nakai: "Nonlinear Optical Properties of Cesium Lithium Borate" Jpn.J.Appl.Phys.34. 296-298 (1995)

[Publications] W.L.Zhou,Y.Mori,T.Sasaki,S.Nakai,K.Nkano and B.Craig: "Intracavity frequency doubiling of a continuous wave Ti:sapphire laser with over 70% conversion efficiency" Appl.Phys.Lett.66. 2463-2465 (1995)

[Publications] Wang-Long Zhou,Y.Mori,T.Sasaki and S.Niikura: "High-Efficiency Intracavity Frequency-Doubled CW and Tunable Ti:Sapphire Laser" Jpn.J.Appl.Phys.34. 3518-3521 (1995)

[Publications] Y.Mori,I.Kuroda,S.Nakajima,T.Sasaki and S.Nakai: "New nonlinear optical crystal:Cesium lithium borate" Appl.Phys.Lett.67. 1818-1820 (1995)

[Publications] 佐々木孝友: "新固体レーザー材料と非線形光学結晶" 応用物理. 64. 878-887 (1995)

[Publications] M.Itoh,R.Yamada,R.Tian,M.Tsai and T.Yatagai: "Broad-Band Light-Wave Correlation Topography Using Wavelet Transform" Opt.Rev.2. 135-138 (1995)

[Publications] J.Ding,M.Itoh and T.Yatagai: "Desing of Optimal Phase-Only Filters by Direct Iterative Search" Opt.Commun.118. 90-101 (1995)

[Publications] N.Yoshikawa,M.Itoh and T.Yatagai: "Quantized Phase Optimization of Two-Dimensional Fourier Kinoforms by Generic Aigorithm" Opt.Lett.20. 752-754 (1995)

[Publications] H.Huang,M.Itoh and T.Yatagai: "Optical Module for Modified Signed-Digit Computing Based on Bit Plane Encoding and Pattern Operations" Opt.Rev.2. 255-260 (1995)

[Publications] N.Yoshikawa,M.itoh and T.Yatagai: "Interpolation of Reconstructed Image in Fourier Transform Computer-Generated Hologram" Opt.Commun.119. 33-40 (1995)

[Publications] X.Tian,M.Itoh and T.Yatagai: "Simple Algorithm for Large-Grid Phase Reconstruction of Lateral-Shearing Interforometry" Appl.Opt.34. 7213-7220 (1995)

[Publications] Liu Y.,Xu Y.,Zhu D.,Wada T.,Sasabe H.,Zhao X.,and Xie X.: "Optical Xecond-Harmonic Generation from Langmuir-Blogett Films of an Asymmetrically Substituted Phthalocyanine" J.Phys.Chem.99. 6957-6960 (1995)

[Publications] Okawa H.,Wada T.,and Sasabe H.: "Linear and Nonlinear Optical Properties of Thin Films of Poly(2-pyridylacetylene)s" Synthetic Metals. 71. 1657-1658 (1995)

[Publications] Zhang Y.-D.,Wang L.,Wada T.,and Sasabe H.: "Molecular Design of Novel Main-Chain Biscarbazoly l Polymers for Nonlinear Optics" Mol.Cryst.Liq.Cryst.267. 65-70 (1995)

[Publications] Wada T.,Zhang Y.-D.,Wang L.,and Sasabe H.: "Carbazole Oligomers for Nonlinear Optics" Nonlinear Optics. 9. 267-273 (1995)

[Publications] Kitazawa M.,Ryoichi H.,Wada T.and Sasabe H.: "Novel Amino Acid Crystals for Phase-Matched Second-Harmonic Generation" J.Appl.Phys.78(2). 709-717 (1995)

[Publications] Higuchi H.,Nakayama T.,Wada T.and Sasabe H.: "Synthesis and Properties of a,w-Disubsituted Oligo(3-hyxylthiophene)s and Oligothienoquinonoids in Head-to-head Orientation" Bull.Chem.Soc.Jpn.68. 2363-2377 (1995)

[Publications] T.Watanabe,S.Miyata and H.S.Nalwa: "Ferroelectric Polymers" Nonlinear Optical Properties of Ferroelectric Polymers, (1995)

[Publications] T.Kondo and R.Ito: "Nonlinear Opt." A Comprehensive Study on Nonlinear Optical Properties of Chiral and Racemic2-(α-Methylvenzylamion)-5-Nitoropyridine Crystals, (1995)

[Publications] H.Yaguchi,S.Miyoshi,H.Arimoto,S.Saito and R.Ito: "Inst.Phys.Conf.Ser." Time-resolved Photoluminescence Study of Radiative Transition Processes in GaP_<3-x>N_x Alloys, (1995)

[Publications] Wada T.,Hosoda M.,Okawa H.,Terasaki A.and Sasabe H.: "Enrico Fermi" Molecular Design of Third-Order Nonlinear Optically Active p-Conjugated Compounds and Preparation of Thin Films, (1995)

宮田清蔵東京農工大学, 大学院生物システム応用科学研究科, 教授 (90015066)