1997 Fiscal Year Annual Research Report

有機非線形光学材料による光波マニピュレーション

Research Project

Project/Area Number	07246104
Research Institution	Tokyo University of Agriculture and Technology
Principal Investigator	宮田清蔵東京農工大学, 大学院・生物システム応用科学研究科, 教授 (90015066)
Co-Investigator(Kenkyū-buntansha)	雀部博之理化学研究所, 主任研究員 (20015126) 谷田貝豊彦筑波大学, 物理工学系, 教授 (90087445) 佐々木孝友大阪大学, 工学部, 教授 (50029237) 中西八郎東北大学, 反応化学研究所, 教授 (50240651) 伊藤良一東京大学, 工学部, 教授 (40133102)
Keywords	非線形光学効果 / 光波マニピュレーション / 有機材料 / 波長変換 / 光変調 / フォトリフラクティブ効果 / 位相 / 波面
Research Abstract	我々は10年ほど前から、それぞれ独立に有機非線形光学材料に関する研究を行ってきた。しかし、実際の素子化に対しては、1人の研究者にとってあまりにも研究の幅が広すぎると感じていた。そこで日本における最もアクティブな研究者が従来の垣根を取り払いアイデア、試料、ファブリケーションのノウハウをお互いに提供し合わなければならないという結論にいたった。本申請領域研究においては、(1)波長のマニピュレーション、(2)振幅のマニピュレーション、(3)波面のマニビュレーション、の3分野について研究を推進し、新材料創製→新プロセス技術開発→デバイス設計を一貫してできるよう、各研究グループの間の調整を行うと共に、従来までの研究成果をデータベース化して研究情報を各グループが円滑にアクセスできる新システムを開発することを目的とした。総括班は領域全体での研究の取りまとめと評価を行うのみならず、全体会議、班会議、電子メール、広報を通じて各研究グループと密接に連絡を取り、分子設計および合成とデバイス作製に関する研究の進展状況を迅速に参加者全体にフィードバックした。また、各研究者が現在の非線形光学材料や素子技術について簡単に情報が得られるように非線形光学材料データーベースを作製した。文献ソースとしてはケミカルアブストラクトより1次資料を抽出し、それらより抜き出した2次資料からデータの加工・分析、単位変襖、図麦入力等を行った。リレーショナルデータベースを用いて非線形光学材料の構造、非線形光学定数、屈折率、測定法、デバイスの概要などがキーワードや物質名、研究者名より、簡単に検索できるようにした。また、測定に用いた参照物質の非線形光学定数を統一することにより、これまで単純に比較できなかった非線形光学定数の大小関係をきちんと評価できるようになった。総括班では今までに蓄えた情報をインターネット対応にし、研究者がアップデ-トな情報をいつでも引き出せるようにするのみならず、自分自身のデータを登録できるセルフグローイングデータベースを構築した。

Research Products

(32 results)

All Other

All Publications (32 results)

[Publications] J.C.Kim: "Preparation of Retardation Film for Supertwisted Nematic Liquid Crystal Display by Drawing and Polings" Jpn.J.Appl.Phys. 36. 232-238 (1997)
[Publications] X.T.Tao: "Metal Complex Polymer for Second Harmonic Generation and Electroluminescence Applications" Appl.Phys.Left.70. 1503-1505 (1997)
[Publications] J.C.Kim: "Preparation of Retaedation Film for STN-LCD with Wide Viewing Angle by Drawing and Poling" Mol.Cryst.Liq.Cryst.295. 75-78 (1997)
[Publications] X.T.Tao: "Novel Main-chain Poly-carbazoles as Hole and Electron Transport Materials in Polymer Light-emitting Diodes" Appl.Phys.Left. 1921-1923 (1997)
[Publications] 重原淳孝: "側鎖に分極基を有するポリフマレートの合成とそのLB膜のSHG特性" 高分子論文集. 54(11). 805-811 (1997)
[Publications] 渡辺敏行: "量子化学計算による有機光学材料の分子設計" 応用物理. 66(10). 1102-1106 (1997)
[Publications] H.Usui: "Deposition of polyurea thin films by ionization-assited method" J.Vac.Sci.Technol.A16(1). 105-113 (1997)
[Publications] N.Tsutsumi: "Precise study of nonlinear optical coefficients and hyperpolarizabilities in cold-drawn and poled ferroelectric nylon 11 films" J.Chem.Phys. (in press). (1988)
[Publications] X.Tao: "Hyperbranched Polymers for Electroluminescence Applications" Adv.Mater.10(3). 226-230 (1998)
[Publications] M.Tian: "Syntheses and Nonlinear Optical Properties of Nonaggregated Metallophthalocyanines" J.Opt.Soc.Am.B. 15(1). 1998 (846-853)
[Publications] H.Nakahara: "Linear and Nonlinear Optical Behaviors of Langmuir-Blodgett Multilayers of Push-Pull Tolan Derivatives" J.Opt.Soc.Am.B. 15(2). 1988 (458-465)
[Publications] Y.Zhang: "Amorphous Conjugated Carbazole Trimers for Photorefractive Materials" Chem.Mater.9(12). 2798-2804 (1997)
[Publications] Y.Zhang: "Synthesis of N-Vinylcarbazole Derivatives with Acceptor Groups" Tetrahedron Left.38(50). 8721-8722 (1997)
[Publications] N.Hashizume: "Fabrication of Periodic Waveguides Using Organic Crystals and Fluorinated Polyimides for Quasi-Phase-Matched Second-Harmonic Generation" Opt.Rev. 4. 316 (1997)
[Publications] I.Shoji: "Absolute Scale of the Second-Order Nonlinear Optical Coefficients" J.Opt.Soc.Am., B. 14. 2268 (1997)
[Publications] T.Kondo: "Biexciton Lasing in the Perovskite-Type Material (C_6H_<13>NH_3)_2PbI_4" Solid State Commun.105. 253 (1998)
[Publications] T.Kondo: "Resonant Third-Order Optical Nonlinearity in the Layered Perovskite-Type Material (C_6H_<13>NH_3)2Pb_4" Solid State Commun.105. 503 (1988)
[Publications] J.Ishi: "Third-Order Optical Nonlinearity due to Excitons and Biexcitons in a Self-Organized Quantum-Well Material C_6H_<13>NH_3)_2PbI_4" Nonlinear Opt.Phys.Mater.(in press). (1988)
[Publications] X.-M.Duan: "Second-Order Hyperpolarizability of Pyridinium Cations" Chem.Left.247 (1997)
[Publications] T.Kimura: "Synthesis and Non-linear Optical Properties of Aromatic Ester Oligomers as Chained Chromophores" Polymer. 39. 491 (1998)
[Publications] M.Yoshimura: "Effective Solid-State Stimulated Brillouin Scattering Mirror by Organic Crystals LAP, DLAP" OSA TOPS. 10. 356 (1997)
[Publications] 吉田英次: "有機結晶LAP位相共役鏡による固体レーザーの高性能化" レーザー研究. 25. 232 (1997)
[Publications] H.Yoshida: "High Energy Operation of Stimulated Brillouin Scattering Mirror in L-Argine Phosphate Monohydorate Crystal" Applied Optics. 36. 7783 (1997)
[Publications] M.Yoshimura: "Efficient stimulated Brillouin scattering in the organic crystal deuterated L-arginine phosphate monohydrate" J.Opt.Soc.Am.B. 15. 1988 (446)
[Publications] T.Sassa: "Cerenkov-Radiation-Type Second-Harmonic Generation in Nonlinear-Optical Photoconducting Polymers Based on Self-Organized Quasi-Phase Matching" Opt.Lett. 22. 856 (1997)
[Publications] T.Sassa: "Enhancement of Second-Harmonic Power Due to Self-Construction of an Anti-Guide Structure in a Thin-Film Waveguide of a Nonlinear-Optical Photoconducting Polymer" Jpn.J.Appl.Phys. (in press). (1998)
[Publications] 梅垣真祐: "波長変換・光変調と有機材料" 光学. 26. 130 (1997)
[Publications] 梅垣真祐: "2次元情報処理用光機能材料" 機能材料. 18. 6 (1998)
[Publications] K.Harada: "Spatial Light Modulators with Polymeric Thin Film Fabry-Perot Etalons" OSA TOPS. 14. 127 (1997)
[Publications] K.Harada: "Microfabrication of Electro-Optical Structures in Polymer Films : Novel Polymer Waveguide Structure for Spatial Light Modulation" OSA TOPS. 14. 132 (1997)
[Publications] S.Miyata: "Novel fabrication techniques of Electroluminescent and Photoluminescent Devices" in Organic Electroluminescent Materials and Devices" Gordon and Breach Science Publishers, 487 (1997)
[Publications] S.Miyata: "Poled Polymers and their Applications to SHG and EO Device" Gordon and Breach Science Publishers, 252 (1997)

1997 Fiscal Year Annual Research Report

有機非線形光学材料による光波マニピュレーション

Principal Investigator

宮田 清蔵 東京農工大学, 大学院・生物システム応用科学研究科, 教授 (90015066)

Research Products

[Publications] J.C.Kim: "Preparation of Retardation Film for Supertwisted Nematic Liquid Crystal Display by Drawing and Polings" Jpn.J.Appl.Phys. 36. 232-238 (1997)

[Publications] X.T.Tao: "Metal Complex Polymer for Second Harmonic Generation and Electroluminescence Applications" Appl.Phys.Left.70. 1503-1505 (1997)

[Publications] J.C.Kim: "Preparation of Retaedation Film for STN-LCD with Wide Viewing Angle by Drawing and Poling" Mol.Cryst.Liq.Cryst.295. 75-78 (1997)

[Publications] X.T.Tao: "Novel Main-chain Poly-carbazoles as Hole and Electron Transport Materials in Polymer Light-emitting Diodes" Appl.Phys.Left. 1921-1923 (1997)

[Publications] 重原淳孝: "側鎖に分極基を有するポリフマレートの合成とそのLB膜のSHG特性" 高分子論文集. 54(11). 805-811 (1997)

[Publications] 渡辺敏行: "量子化学計算による有機光学材料の分子設計" 応用物理. 66(10). 1102-1106 (1997)

[Publications] H.Usui: "Deposition of polyurea thin films by ionization-assited method" J.Vac.Sci.Technol.A16(1). 105-113 (1997)

[Publications] N.Tsutsumi: "Precise study of nonlinear optical coefficients and hyperpolarizabilities in cold-drawn and poled ferroelectric nylon 11 films" J.Chem.Phys. (in press). (1988)

[Publications] X.Tao: "Hyperbranched Polymers for Electroluminescence Applications" Adv.Mater.10(3). 226-230 (1998)

[Publications] M.Tian: "Syntheses and Nonlinear Optical Properties of Nonaggregated Metallophthalocyanines" J.Opt.Soc.Am.B. 15(1). 1998 (846-853)

[Publications] H.Nakahara: "Linear and Nonlinear Optical Behaviors of Langmuir-Blodgett Multilayers of Push-Pull Tolan Derivatives" J.Opt.Soc.Am.B. 15(2). 1988 (458-465)

[Publications] Y.Zhang: "Amorphous Conjugated Carbazole Trimers for Photorefractive Materials" Chem.Mater.9(12). 2798-2804 (1997)

[Publications] Y.Zhang: "Synthesis of N-Vinylcarbazole Derivatives with Acceptor Groups" Tetrahedron Left.38(50). 8721-8722 (1997)

[Publications] N.Hashizume: "Fabrication of Periodic Waveguides Using Organic Crystals and Fluorinated Polyimides for Quasi-Phase-Matched Second-Harmonic Generation" Opt.Rev. 4. 316 (1997)

[Publications] I.Shoji: "Absolute Scale of the Second-Order Nonlinear Optical Coefficients" J.Opt.Soc.Am., B. 14. 2268 (1997)

[Publications] T.Kondo: "Biexciton Lasing in the Perovskite-Type Material (C_6H_<13>NH_3)_2PbI_4" Solid State Commun.105. 253 (1998)

[Publications] T.Kondo: "Resonant Third-Order Optical Nonlinearity in the Layered Perovskite-Type Material (C_6H_<13>NH_3)2Pb_4" Solid State Commun.105. 503 (1988)

[Publications] J.Ishi: "Third-Order Optical Nonlinearity due to Excitons and Biexcitons in a Self-Organized Quantum-Well Material C_6H_<13>NH_3)_2PbI_4" Nonlinear Opt.Phys.Mater.(in press). (1988)

[Publications] X.-M.Duan: "Second-Order Hyperpolarizability of Pyridinium Cations" Chem.Left.247 (1997)

[Publications] T.Kimura: "Synthesis and Non-linear Optical Properties of Aromatic Ester Oligomers as Chained Chromophores" Polymer. 39. 491 (1998)

[Publications] M.Yoshimura: "Effective Solid-State Stimulated Brillouin Scattering Mirror by Organic Crystals LAP, DLAP" OSA TOPS. 10. 356 (1997)

[Publications] 吉田英次: "有機結晶LAP位相共役鏡による固体レーザーの高性能化" レーザー研究. 25. 232 (1997)

[Publications] H.Yoshida: "High Energy Operation of Stimulated Brillouin Scattering Mirror in L-Argine Phosphate Monohydorate Crystal" Applied Optics. 36. 7783 (1997)

[Publications] M.Yoshimura: "Efficient stimulated Brillouin scattering in the organic crystal deuterated L-arginine phosphate monohydrate" J.Opt.Soc.Am.B. 15. 1988 (446)

[Publications] T.Sassa: "Cerenkov-Radiation-Type Second-Harmonic Generation in Nonlinear-Optical Photoconducting Polymers Based on Self-Organized Quasi-Phase Matching" Opt.Lett. 22. 856 (1997)

[Publications] T.Sassa: "Enhancement of Second-Harmonic Power Due to Self-Construction of an Anti-Guide Structure in a Thin-Film Waveguide of a Nonlinear-Optical Photoconducting Polymer" Jpn.J.Appl.Phys. (in press). (1998)

[Publications] 梅垣真祐: "波長変換・光変調と有機材料" 光学. 26. 130 (1997)

[Publications] 梅垣真祐: "2次元情報処理用光機能材料" 機能材料. 18. 6 (1998)

[Publications] K.Harada: "Spatial Light Modulators with Polymeric Thin Film Fabry-Perot Etalons" OSA TOPS. 14. 127 (1997)

[Publications] K.Harada: "Microfabrication of Electro-Optical Structures in Polymer Films : Novel Polymer Waveguide Structure for Spatial Light Modulation" OSA TOPS. 14. 132 (1997)

[Publications] S.Miyata: "Novel fabrication techniques of Electroluminescent and Photoluminescent Devices" in Organic Electroluminescent Materials and Devices" Gordon and Breach Science Publishers, 487 (1997)

[Publications] S.Miyata: "Poled Polymers and their Applications to SHG and EO Device" Gordon and Breach Science Publishers, 252 (1997)

宮田清蔵東京農工大学, 大学院・生物システム応用科学研究科, 教授 (90015066)