1996 Fiscal Year Annual Research Report

有機材料のフォトリフラクティブ効果による光伝播制御技術の開発

Research Project

Project/Area Number	07246111
Research Institution	The Institute of Physical and Chemical Research
Principal Investigator	雀部博之理化学研究所, 生体高分子物理研究所, 主任研究員 (20015126)
Co-Investigator(Kenkyū-buntansha)	尾島十郎富山大学, 理学部, 教授 (00018988) 藤原裕文室蘭工業大学, 工学部, 教授 (80001303)
Keywords	フォトリフラクティブ効果 / カルバゾールデンドリマ- / ポーリング / 位相共役光学 / 二色素混合高分子膜 / 位相共役干渉 / オリゴチオフェン / 分子超分極率
Research Abstract	アクセプター導入カルバゾールオリゴマーの光キャリヤ発生および電気光学効果を調べ、フォトリフラクティブ効果の発現に必要な多機能性を有することを確認した。擾乱によって乱れた画面の波面の補正が4光波混合による位相共役波によって可能となった。(雀部) キサンテン系色素とアゾ系色素を含む二色素混合膜による、互いに直交した二種類の位相共役波の偏光特性の測定から、実効的な非線型感受率の振幅と位相差を調べた。二色素の混合比を変えることにより、実効的な非線型感受率の振幅と位相差をある範囲で変化させることができた。この色素膜に固有の位相差を位相補償板を用いて打ち消すことにより、ノベルテイフィルタリングや位相共役干渉が可能となった。(藤原) 本研究では、一方の末端に電子供与性の強さが異なる置換基(SMeおよびOMe)を有する一連の分子内電荷移動型ビチオフェン誘導体の合成を行い、それらの分子構造と電子物性について検討した。電荷移動吸収帯の遷移エネルギーが溶媒の極性(π^*値)と負の一次の相関関係があり、その感受率はSMe誘導体の方がOMe誘導体よりも大きいことを見いだした。また、低エネルギーシフトする程度について、OMe誘導体の場合は、共役長の長短に依存せず、一方、SMe誘導体の場合はねじれ型配座の分子構造の方においてより大きく現れる傾向を見いだした。(尾島)

Research Products

(28 results)

All Other

All Publications (28 results)

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "One-Pot Synthesis of a New Hyperbranched Polyester Containing 3,6-Di-Acceptor-Substituted Carbazole Chromophores for Nonlinear Optics" Macromol.Chem.Phys.197. 667-676 (1996)
[Publications] T.Wada,L.Wang,Y.Zhang,M.Tian and H.Sasabe: "Multifunctional Chromophores for Monolithic Photorefractive Materials" Nonlinear Optics. 15. 103-110 (1996)
[Publications] S.Yanagi,T.Wada,H.Sasabe and K.Sasaki: "Linear and Nonlinear Optical Properties of Soluble Metallophthalocyanines" Nonlinear Optics. 15. 267-270 (1996)
[Publications] T.Aoyama,T.Wada,Y.-D.Zhang,T.Isoshima,Y.Togo,H.Sasabe and K.Sasaki: "Electro-optic Effects in Mono- and Di-substituted Carbazoles" Nonlinear Optics. 15. 403-406 (1996)
[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "A New Synthetic Approach for Polymers Contaning High Density of Second-order Nonlinear Optical Chromophores" Chem.Commun.559-561 (1996)
[Publications] Y.Zhang,T.Wada and H.Sasabe: "A New Synthetic Approach to Macrocyclic Molecules and Main-Chain Polymers Containing Carbazole Moieties" Chem.Commun.621-622 (1996)
[Publications] T.Isoshima,T.Wada,Y.-D.Zhang,E.Brouyere,J.-L.Bredas and H.Sasabe: "Poling Behaviour of Optical Absorption Spectra in Carbazoles with One-and Two-Dimensional Charge-Transfer Character" J.Chem.Phys.107. 2467-2475 (1996)
[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Polymers Containing in the Chain Backbone Carbazole Substituted with Two Acceptor Groups as Nonlinear Optical Chromopheres" Macromolecules. 29. 1569-1573 (1996)
[Publications] T.Wada,Y.Zhang,L.Wang and H.Sasabe: "Novel Molecules for Photorefractive Application" Mol.Cryst.Liq.Cryst.280. 71-78 (1996)
[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Novel Hyperbranched Polymer with Dipole Cabazole Moieties for Multifunctional Materials" J.Polym.Sci.A : Polym.Chem.34. 1359-1363 (1996)
[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Second-Order Nonlinear Optical Main-Chain Polyurethanes Containing Acceptor-Substituted Carbazole Units" Macromol.Chem.Phys.197. 1877-1888 (1996)
[Publications] L.Wang,Y.Zhang,T.Wada and H.Sasabe: "Photorefractive Effect in a Photoconductive Electro-optic Carbazole Trimer" Appl.Phys.Lett.69. 728-730 (1996)
[Publications] Y.Zhang,T.Wada and H.Sasabe: "Synthesis of a New Carbazole Cyclic Dimer via Knoevenagle Condensation" Tetrahedron Letters. 37. 5909-5912 (1996)
[Publications] J.W.Perry,K.Mansour,I.-Y.S.Lee,X.-L.Wu,P.V.Bedworth,C.-T.Chen,D.Ng,S.R.Marder,P.Miles,T.Wada,M.Tian,H.Sasabe: "Organic Optical Limiter with a Strong Nonlinear Absorptive Response" Science. 273. 1533-1536 (1996)
[Publications] Y.Zhang,T.Wada and H.Sasabe: "Carbazole Main-Chain Polymers for Multifunctional Materials : Synthesis and Characterization" J.Polym.Sci.A : Polym.Chem.34. 2289-2298 (1996)
[Publications] E.Tokunaga,A.Terasaki,V.S.Valencia,T.Wada and H.Sasabe and T.Kobayashi: "Femtosecond Phase Spectroscopy of Multi-level Systems : Phthalocyanines" Appl.Phys.B. 63. 255-264 (1996)
[Publications] Y.Zhang,T.Wada,L.Wang,T.Aoyama and H.Sasabe: "Photorefractive Polymers Containing a Single Multifunctional Chromophore" Chem.Commun.2325-2326 (1996)
[Publications] K.Kajikawa,L.Wang,T.Isoshima,T.Wada,W.Knoll,H.Sasebe,S.Okada and H.Nakanishi: "Phase Measurement of Second-Harmonic Generation Reveals the Directional Sense of a 2-docosylamino-5-nitropyridine (DCANP) Molecule in Langmuir-Blodgett Films" Thin Solid Films. 284-285. 612-614 (1996)
[Publications] A.-C.Ribou,T.Wada and H.Sasebe: "Molecular design of asymmetric bichromophoric compounds" Synthetic Metals. 81. 277-280 (1996)
[Publications] M.Tian,T.Wada and H.Sasebe: "Synthesis of Unsymmetrically Substituted Dodecakis (trifluoroethoxy)-phthalocyaninato Vanadyl Complexes" J.Heterocyclic Chem.34. 1-6 (1997)
[Publications] K.Nakagawa,R.Komatsu,H.Fujiwara and M.Sato: "Holographic Redording in Polyesters Having Cyanoazobenzen Units in the Side Chain" SPIE. 2778. 571-572 (1996)
[Publications] T.Takeda,M.Murakami and H.Fujiwara: "Phase Conjugate Interferometry Using a Polymer Film Doped with Two Kinds of Dyes" SPIE. 2778. 880-881 (1996)
[Publications] H.Higuchi,H.Koyama,H.Yokota and J.Ojima: "Solvent Effect on the Bathochromic Shifts of Push-pull Dihexylbithiophenes with Head-to-head and Head-to-tail Orientations" Tetrahedoron Lett.37. 1617-1620 (1996)
[Publications] H.Higuchi,H.Koyama,N.Hayashi,J.Ojima,T.Wada and H.Sasebe: "Electronic and Nonlinear Optical Properties of Monosubstituted Oligo (3-hexylthiophene) s" Nonlinear Optics. 15. 209-212 (1996)
[Publications] H.Higuchi,N.Hiraiwa,S.Kondo,J.Ojima and G.Yamamoto: "5,10-Dimethyl 〔13〕 annulenone,the First Monocyclic Annulenone Larger Than Tropone" Tetrahedron Lett.37. 2601-2604 (1996)
[Publications] J.Ojima,N.Hiraiwa,H.Higuchi,I.Kobayashi,K.Yamamoto,T.Yoshida,T.Adachi,H.Matsubara and G.Yamamoto: "Synthesis,Conformation and Tropicit of Dimethano-bridged Tetradehydrothia 〔21〕-,-〔23〕-,and 〔25〕 annulenes" J.Chem.Soc.,Perkin Trans.J.2755-276 (1996)
[Publications] H.Higuchi,M.Takeuchi and J.Ojima: "Mono-,Di-,and Trimetallic Palladium (II) Porphyrin Trimers with Etheno-bridges" Chem.Lett.593-594 (1996)
[Publications] 尾島十郎、樋口弘行、山本学: "大環状共役化合物の合成と性質" 有機合成化学協会誌. 46. 772-782 (1996)

1996 Fiscal Year Annual Research Report

有機材料のフォトリフラクティブ効果による光伝播制御技術の開発

Principal Investigator

雀部 博之 理化学研究所, 生体高分子物理研究所, 主任研究員 (20015126)

Research Products

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "One-Pot Synthesis of a New Hyperbranched Polyester Containing 3,6-Di-Acceptor-Substituted Carbazole Chromophores for Nonlinear Optics" Macromol.Chem.Phys.197. 667-676 (1996)

[Publications] T.Wada,L.Wang,Y.Zhang,M.Tian and H.Sasabe: "Multifunctional Chromophores for Monolithic Photorefractive Materials" Nonlinear Optics. 15. 103-110 (1996)

[Publications] S.Yanagi,T.Wada,H.Sasabe and K.Sasaki: "Linear and Nonlinear Optical Properties of Soluble Metallophthalocyanines" Nonlinear Optics. 15. 267-270 (1996)

[Publications] T.Aoyama,T.Wada,Y.-D.Zhang,T.Isoshima,Y.Togo,H.Sasabe and K.Sasaki: "Electro-optic Effects in Mono- and Di-substituted Carbazoles" Nonlinear Optics. 15. 403-406 (1996)

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "A New Synthetic Approach for Polymers Contaning High Density of Second-order Nonlinear Optical Chromophores" Chem.Commun.559-561 (1996)

[Publications] Y.Zhang,T.Wada and H.Sasabe: "A New Synthetic Approach to Macrocyclic Molecules and Main-Chain Polymers Containing Carbazole Moieties" Chem.Commun.621-622 (1996)

[Publications] T.Isoshima,T.Wada,Y.-D.Zhang,E.Brouyere,J.-L.Bredas and H.Sasabe: "Poling Behaviour of Optical Absorption Spectra in Carbazoles with One-and Two-Dimensional Charge-Transfer Character" J.Chem.Phys.107. 2467-2475 (1996)

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Polymers Containing in the Chain Backbone Carbazole Substituted with Two Acceptor Groups as Nonlinear Optical Chromopheres" Macromolecules. 29. 1569-1573 (1996)

[Publications] T.Wada,Y.Zhang,L.Wang and H.Sasabe: "Novel Molecules for Photorefractive Application" Mol.Cryst.Liq.Cryst.280. 71-78 (1996)

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Novel Hyperbranched Polymer with Dipole Cabazole Moieties for Multifunctional Materials" J.Polym.Sci.A : Polym.Chem.34. 1359-1363 (1996)

[Publications] Y.Zhang,L.Wang,T.Wada and H.Sasabe: "Synthesis and Characterization of Second-Order Nonlinear Optical Main-Chain Polyurethanes Containing Acceptor-Substituted Carbazole Units" Macromol.Chem.Phys.197. 1877-1888 (1996)

[Publications] L.Wang,Y.Zhang,T.Wada and H.Sasabe: "Photorefractive Effect in a Photoconductive Electro-optic Carbazole Trimer" Appl.Phys.Lett.69. 728-730 (1996)

[Publications] Y.Zhang,T.Wada and H.Sasabe: "Synthesis of a New Carbazole Cyclic Dimer via Knoevenagle Condensation" Tetrahedron Letters. 37. 5909-5912 (1996)

[Publications] J.W.Perry,K.Mansour,I.-Y.S.Lee,X.-L.Wu,P.V.Bedworth,C.-T.Chen,D.Ng,S.R.Marder,P.Miles,T.Wada,M.Tian,H.Sasabe: "Organic Optical Limiter with a Strong Nonlinear Absorptive Response" Science. 273. 1533-1536 (1996)

[Publications] Y.Zhang,T.Wada and H.Sasabe: "Carbazole Main-Chain Polymers for Multifunctional Materials : Synthesis and Characterization" J.Polym.Sci.A : Polym.Chem.34. 2289-2298 (1996)

[Publications] E.Tokunaga,A.Terasaki,V.S.Valencia,T.Wada and H.Sasabe and T.Kobayashi: "Femtosecond Phase Spectroscopy of Multi-level Systems : Phthalocyanines" Appl.Phys.B. 63. 255-264 (1996)

[Publications] Y.Zhang,T.Wada,L.Wang,T.Aoyama and H.Sasabe: "Photorefractive Polymers Containing a Single Multifunctional Chromophore" Chem.Commun.2325-2326 (1996)

[Publications] K.Kajikawa,L.Wang,T.Isoshima,T.Wada,W.Knoll,H.Sasebe,S.Okada and H.Nakanishi: "Phase Measurement of Second-Harmonic Generation Reveals the Directional Sense of a 2-docosylamino-5-nitropyridine (DCANP) Molecule in Langmuir-Blodgett Films" Thin Solid Films. 284-285. 612-614 (1996)

[Publications] A.-C.Ribou,T.Wada and H.Sasebe: "Molecular design of asymmetric bichromophoric compounds" Synthetic Metals. 81. 277-280 (1996)

[Publications] M.Tian,T.Wada and H.Sasebe: "Synthesis of Unsymmetrically Substituted Dodecakis (trifluoroethoxy)-phthalocyaninato Vanadyl Complexes" J.Heterocyclic Chem.34. 1-6 (1997)

[Publications] K.Nakagawa,R.Komatsu,H.Fujiwara and M.Sato: "Holographic Redording in Polyesters Having Cyanoazobenzen Units in the Side Chain" SPIE. 2778. 571-572 (1996)

[Publications] T.Takeda,M.Murakami and H.Fujiwara: "Phase Conjugate Interferometry Using a Polymer Film Doped with Two Kinds of Dyes" SPIE. 2778. 880-881 (1996)

[Publications] H.Higuchi,H.Koyama,H.Yokota and J.Ojima: "Solvent Effect on the Bathochromic Shifts of Push-pull Dihexylbithiophenes with Head-to-head and Head-to-tail Orientations" Tetrahedoron Lett.37. 1617-1620 (1996)

[Publications] H.Higuchi,H.Koyama,N.Hayashi,J.Ojima,T.Wada and H.Sasebe: "Electronic and Nonlinear Optical Properties of Monosubstituted Oligo (3-hexylthiophene) s" Nonlinear Optics. 15. 209-212 (1996)

[Publications] H.Higuchi,N.Hiraiwa,S.Kondo,J.Ojima and G.Yamamoto: "5,10-Dimethyl 〔13〕 annulenone,the First Monocyclic Annulenone Larger Than Tropone" Tetrahedron Lett.37. 2601-2604 (1996)

[Publications] J.Ojima,N.Hiraiwa,H.Higuchi,I.Kobayashi,K.Yamamoto,T.Yoshida,T.Adachi,H.Matsubara and G.Yamamoto: "Synthesis,Conformation and Tropicit of Dimethano-bridged Tetradehydrothia 〔21〕-,-〔23〕-,and 〔25〕 annulenes" J.Chem.Soc.,Perkin Trans.J.2755-276 (1996)

[Publications] H.Higuchi,M.Takeuchi and J.Ojima: "Mono-,Di-,and Trimetallic Palladium (II) Porphyrin Trimers with Etheno-bridges" Chem.Lett.593-594 (1996)

[Publications] 尾島十郎、樋口弘行、山本 学: "大環状共役化合物の合成と性質" 有機合成化学協会誌. 46. 772-782 (1996)

雀部博之理化学研究所, 生体高分子物理研究所, 主任研究員 (20015126)

[Publications] 尾島十郎、樋口弘行、山本学: "大環状共役化合物の合成と性質" 有機合成化学協会誌. 46. 772-782 (1996)