| Co-Investigator(Kenkyū-buntansha) |
YAMASHITA Masahiro Nagoya University, School of Informatics and Sciences, Professor, 情報文化学部, 助教授 (60167707)
KOBAYASHI Hayao Institute for Molecular Ssience, Professor, 分子科学研究所, 教授 (60057635)
ENOKI Toshiaki Tokyo Institute of Technology, Faculty of Science, Professor, 理学部, 教授 (10113424)
KITAGAWA Susumu Tokyo Metropolitan University, Faculty of Science, Professor, 理学部, 教授 (20140303)
SHIROTANI Ichimin Muroran Institute of Technology, Faculty of Technology, Professor, 工学部, 教授 (90110692)
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| Research Abstract |
Transition metal complexes which are located between organic and inorganic materials hava a possibility of various kinds of multi-functional properties mixed with optical, magnetic or transport properties. In order to search and develop new multifunctional properties for transition metal complexes, we have organized the research project, grant-in-aid for scientific research whose title is "Design and Development of the Transition Metal Complexes Having Multi-Functional Properties".
During the term of the project (1995-1996), the noticeable results of our project are following ; (1) Field induced insulator-to-metal transition in (BETS) _2FeCl_4, which is driven by the d-pi interaction, (2) Competition between the superconducting and antiferromagnetic phases in (BETS) _2Ga_<1-X>Fe_XCl_4, (3) An exotic metal-insulator transition driven by the d-pi electron transfer coupled with proton transfer in [Pd (H_2DAG) (HDAG)]TCNQ (M=Ni, Pd, Pt), (4) Development of new ferromagnets and ferrimagnets, (5) Development of new spin crossover complexes, (6) Existence of dense nonlinear excitations such as solitons or polarons for mixed-valence MX chain system, (7) Metal-insulator transition in mixed-valence MMX-chain system, (8) Development of highly nonlinear optics (SHG) for transition metal cluster complexes, (9) Photo-induced ligand-driven crystalline vibration for coordination polymer.
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