• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

1997 Fiscal Year Final Research Report Summary

New Material Transformation under Unusual Reaction Conditions

Research Project

Project/Area Number 07304047
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 物質変換
Research InstitutionKochi University

Principal Investigator

KOTSUKI Hiyoshizo  Department of Chemistry, Kochi University Associate Professor, 理学部, 助教授 (80093954)

Co-Investigator(Kenkyū-buntansha) KUZUYA Masayuki  Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University, 薬学部, 教授 (10082984)
TOMIOKA Hideo  Chemistry Department of Materials, Mie University Professor, 工学部, 教授 (20024599)
ANDO Takashi  Department of Chemistry, Shiga University of Medical Science Professor, 医学部, 教授 (70029867)
IBATA Toshikazu  Department of Chemistry, Osaka University Professor, 大学院・理学研究科, 教授 (80029644)
MATSUMOTO Kiyoshi  Graduate School of Human and Environmental Studies, Kyoto University Professor, 大学院・人間・環境学研究科, 教授 (20026818)
Project Period (FY) 1995 – 1997
KeywordsOrganic Synthesis / High Pressure Reaction / Ultrasonic Reaction / Flash Vapor Pyrolysis / Plasma / Radical Reaction / Functional Group Transformation / Unusual Methodology
Research Abstract

1 High Pressue Reactions : Synthesis of suprampolecular compounds having a novel molecular recognition property, synthesis of aromatic amines via high-pressure promoted nucleophilic aromatic substitution, transformation of nucleic acids by high-pressure promoted enzyme catalysis, cycloaddition reactions of troponoids, several ogranic functional group transformation such as E-Z isomerization and Michael addition reactions of beta-ketoesters.
2 Ultrasonic Reactios : Effect of ultrasonics on the solid state organic reactions, ultrasonic reaction activation of fluorouracil derivatives and their use as prodrags, ultrasonic of organic molecules in aqueous media, ultrasonic activation of oxygen and its mechanistic investigation, ultrasonic fluorination of organic molecules, selective transformation of organic compounds in the solid state.
3 Flash Vacuum Pyrolysis : Reactivity of carbenes and nitrenes generated at high pressure in vapor phase, synthesis of novel cyclic organosilicon and organogermanium compounds.
4 Plasma Chemistry : Selective transformation of organic materials, generation of radical species, surface treatment of functional polymers, structure and reactivity of peroxyl radicals in the solid state.

  • Research Products

    (90 results)

All Other

All Publications (90 results)

  • [Publications] K.Gamoh: "Enantioselectivity of Protein-Adsorbed Alkyl-Bonded Silica Gel Propared under High Pressure Conditions" 分析化学. 44. 853-858 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Synthesis of Novel Chiral Diazole Ligands for Enantioselective Addition of Diethylzinc to Benzaldehyde" Jetrahedron:Asymmetry. 6. 2665-2668 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "High Pressure Organic Chemistry.19.HighPressure Promoted,Silica Gel-Catalyzed Reaction of Epoxides with Nitrogen Heterocycles" Journal of Organic Chemistry. 61. 984-990 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "A Facile Conversion of Epoxides to β-Halohydrins with Silica Gel-supported Lithium Halides" Jetrahedron Letters. 37. 1845-1848 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Ytterbium(III)Trifluoro methane sulfonate Catalyzed High Pressure Roaction of Epoxides with Irdole.An Enantioselective Synthesis of(+)-Diolmycin A2" Jetrahedron Letters. 37. 3727-3730 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Epoxide Ring Opening Reaction at High Pressure" 化学工業. 47. 845-849 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Synthesis of Novel Chiral Diazole Derirative Ligands for the Enantioselective Addition of Diethylzinc of Benzaldehyde" Journal of Organic Chemistry. 61. 8915-8920 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "A New Faule Merhod for the Chemoselective Riductive Transfor mation of Azides to N-(tert Butoxycarbonyl)amines" Jetrahedron Letters. 38. 2129-2132 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Yb(Otf)_3-Catalyzed Michael Addition Reactions of β-Ketoesters on Silica Gel Supports and at High Pressure" Jetrahedron Letters. 38. 7583-7586 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kotsuki: "Organic Synthesis at High Dressure.Efficient Ring Opening Reaction of Epaxides Nith Hetero or cles" The Review of High Pressure Scionce and technology. 7. 印刷中 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Synrhesis of New Bis-crown Ethers that Show Specific Metal Ion Transport Properties" Heterocycles. 40. 521-524 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Synthesis of New Armed Cyclopropylamines and their Selective Extraction Properties for Metal Ions" Heterocycles. 41. 237-244 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Ag^+ Ion-Selective Lariat Ethers:High Pressure Syntheses and Cation Recognition Propreties" Jaurnal of Chomicak Society,Perkin Transaction 1. 2497-2502 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Molecular Inclusion Crystals of Novel Heterocyclic Compouncds" Molecular Crystals and Liquid Crystals. 276. 173-184 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "High Dressure Diels-Alder Reactions of Pyridone with Cyclooctyne" Heterocydes. 45. 15-18 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Ciobanu: "Recont Advances in Organic Synthesis under High Pressure" Liebigs Annalen. 623-635 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.C.K.Choi: "Catalytic Asymmetric Synthesis of (S)-Acetophenone Cyanohydrin under High Pressure" Jetrahedron Letters. 38. 6669-6672 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Synthesis of Diazathia 15- and 18-Crown Ethers and their Transport Properies for Metal Cations" Heterocycles. 47. 101-106 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "The Synthesis and Reactions of Heterocycles under High Pressures:Part II" Heterocycles. 47. 1135-1177 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ibata: "Nucleophilic Substitution Reaction of p-Chloronitrobenzene with N-Substituted Cyclic Amines under High Pressure" Heterocyclic Communications. 1. 241-244 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ibata: "Reaction of Mono^-,Di^-,and Trichloronitrobenzenes with N-Methyl Substituted Cyclic Tertiary Amines under High Pressure" Bulletin of the Chomical Society of Japan. 68. 2716-2726 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ibata: "The Nucleophilic Substitution Reaction of p-Chloronitrobenzene with N-Substituted Cyclic Amines under High Pressure" Bulletin of the Chomical Society of Japan. 68. 2941-2949 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ibata: "The SNAr Reaction of 2,3,5,6-Tetrachloronitrobenzene with Dianines under High Pressure:Formation of Cyclization Products" Bulletin of the Chomical Society of Japan. 68. 3227-3232 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.V.Chapyshev: "Now Type of Quirone-quirone Coxplexation in the Reaction of 2,5-Dichloro 1,4-benzoquinonone with Morpholine at High Pressure" Russian chemistry of bulletin. 45. 469-470 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kimura: "The Site of the Sonochemically-Initiated Radical Reaction of Lead Tetraacetate with β-Methylstyrene" Chemistry Letters. 55-56 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kimura: "Isomerization Mechanism of α-Phenetryl Thiocyanate in the Presence of a Supported Reagent" Bulletin of Shiga University of Medical Sciovce. 6. 1-5 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kimura: "1,2-Bis(0-aminophenoxy)ethane-N,N,N′,N′-tetraacetic Acid Deriuatives on Complexation with Lanthanoid Metal Ions.Correlation be tween Size of Trapping Hole and Metal Ion" Heteroatom Chemistry. 6. 57-62 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ando: "Physical Control of Chemical Reactivity" Ultrasonics Sonochemistry. 3. S145- (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kimura: "Standardization of Ultrasonic Power for Sonochemical Reacotion" Ultrasonics Sonochemistry. 3. S157-161 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ando: "Mechanism of Sonochemical Excitation in the Reactions of Lead Tetraacetate with Sone Organic subsbates" Ultrasonics Sonochemistry. 3. S223-227 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F.Hayakawa: "DNA Cleavage Reaction and Linolic Acid Peroxidation Induced by Tea Catechins in the Presence of Cupric Ion" Biochimica Biophysica Acta. 1336. 123-131 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Chemistry of 1-Alkyfluoreny lideres.Steric Effectcs on Aryl Carhene Roactivity" Journal of the American Chemical Society. 117. 4483-4498 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Thermolysis and Photolysis of 1-Substituted Triptycenes.Divergent Frggmcutation Path ways of Triptycyl Skeleion" Journal of the Chemical Society,Perkin Tramsaction I. 563-569 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Generation and Characterization of Persistent Triplet Diphenylcarbene" 有機合成化学協会誌. 54. 783-793 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Matrix Isolation study of Roactive o-Quinaid Compourds:Generation,Detection and Roactions" Pure & Appliecl Chemistry. 69. 837-840 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Flash Vacuum Pyrolysis of Trifluoro merhylatocl Diphenyldiazomethanes.Role of Trifluoromethyl Group on the ArylCarbene Rearoangemeont" Journal of Chemical Society,Chemical Communicatins. 1745-1746 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Tomioka: "Persistent Triplet Carbenes" Accounts of Chomical Research. 30. 315-321 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Electron Spin Rosonance Study on Plasma-Induced Surtace Radicals of Ethylene-Tetrafluoroethylene Copolymer" Polymer Journal. 27. 251-255 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Spectrochemistry of Plasma-Induced Free Radicals in Cellulose Derivatives" Chemical & Pharmateutical Bulletin. 43. 2037-2041 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "A Novel Method for Introduction of Plasma-Induced Hydro phikciy on Polyerhylene-Nophthalate" Journal of Photopolymer Scionce & Technology. 8. 381-384 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Special Features of Peroxy Rodicals on Plasma-Irradioted Polymers" Journal of Photopolymer Scionce & Technology. 9. 261-264 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Effect of Alkyl Substitution on Plasma-Induced Free Radicals of Cellulose Derivatives" Proceedings of Japanese Symposium on Plasma Chemistry. 9. 55-60 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Plasma-Induced Surface Radicals of Low Density Polyethylene Srudied by Electron Spin Resnance" Polymer Reoprints(ACS). 38. 1049-1050 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kuzuya: "Natere of Auto-Oxidations on Plasma-Induced Surface Radicals of Polyethylene Studied by Electron Spin Resonance" Journal of Photopolymer Science & Technology. 10. :135-138 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 1) K.Gamoh, D.Hama, K.Yanagisawa, and H.KOTSUKI: "Enantioselectivity of Protein-adsorbed Alkyl-bonded Silica Gel Prepared under High Pressure Conditions" BUNSEKIKAGAKU. 44. 853-858 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 2) H.KOTSUKI,H.Hayakawa, M.Wakao, T.Shimanouchi, and M.Ocji: "Synthesis of Novel Chiral Diazole Ligands for Enantioselective Addition of Diethylzinc to Benzaldehyde" Tetrahedron : Asymmrtry. 6. 2665-2668 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) H.KOTSUKI,K.Hayashida, T.Shimanouchi, and H.Nishizawa: "High Pressure Organic Chemistry. 19. High Pressure Promoted, Silica Gel-Catalyzed Reaction of Epoxides with Nitrogen Heterocycles" J.Org.Chem.61. 984-990 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) H.KOTSUKI and T.Shimanouchi: "A Facile Conversion of Epoxides to beta-Halohydrins with Silica Gel-Supported Lithium Halides" Tetrahedron Lett.37. 1845-1848 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) H.KOTSUKI,M.Teraguchi, N.Shimomoto, and M.Ochi: "Ytterbium (III) Trifluoromethanesulfonate Catalyzed High Pressure Reaction of Epoxides with Indole. An Enantioselective Synthesis of (+)-Diolmycin A2" Tetrahedron Lett.37. 3727-3730 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 6) H.KOTSUKI: "Epoxide Ring Opening Reaction at High Pressure" KAGAKUKOGYO. 47. 845-849 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 7) H.KOTSUKI,M.Wakao, H.Hayakawa, T.Shimanouchi, and M.Shiro: "Synthesis of Novel Chiral Diazole Derivative Ligands for the Enantioselective Addition of Diethylzinc to Benzaldehyde" J.Org.Chem.61. 8915-8920 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 8) H.KOTSUKI,T.Ohishi, and T.Araki: "A New Facile Method for the Chemoselective Reductive Transformation of Azides to N-(tert-Butoxycarbonyl) amines" Tetrahedron Lett.38. 2129-2132 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 9) H.KOTSUKI and K.Arimura: "Yb (OTf)_3-Catalyzed Michael Addition Reaction of beta-Ketoesters on Silica Gel Supports and at High Pressure" Tetrahedron Lett.38. 7583-7586 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 10) H.KOTSUKI: "Organic Synthesis at High Pressure. Efficient Ring Opening Reaction of Epoxides with Heterocytes" The Review of High Pressure Science and Technology. 7(in press.).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 1) K.MATSUMOTO,S.Okuno, H.Iida, and J.W.Lown: "Synthesis of New Bis-crown Ethers That Show Specific Metal Ion Transport Properties" Heterocycles. 40. 521-524 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 2) K.MATSUMOTO,K.Fukuyama, H.Iida, M.Toda, and J.W.Lown: "Synthesis of New Armed Cyclopropylamines and Their Selective Extraction Properties for Metal Ions" Heterocycles. 41. 237-244 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) K.MATSUMOTO,M.Hashimoto, M.Toda, and H.Tsukube: "Ag^+ Ion-Selective Lariat Ethers : High Pressure Syntheses and Cation Recognition Properties" J.Chem.Soc.Perkin Trans.1. 2497-2502 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) K.MATSUMOTO,M.Toda, Y.Ikemi, A.Kakehi, S.Hashimoto, and S.Otani: "Molecular Inclusion Crystals of Novel Heterocyclic Compounds" Mol.Cryst.Liq.Cryst.276. 173-184 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) K.MATSUMOTO,M.Ciobanu, M.TYoshida, and T.Uchida: "High Pressure Diels-Alder Reactions of Pyridone with Cyclooctyne" Heterocycles. 45. 15-18 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 6) M.Ciobanu and K.MATSUMOTO: "Recent Advances in Organic Synthesis under High Pressue" Liebigs Ann.623-635 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 7) M.C.K.Choi, S.S.Chan, and K.MATSUMOTO: "Catalytic Asymmertric Synthesis of (S)-Acetophenone Cyanohydrin under High Pressure" Tetrahedron Lett.38. 6669-6672 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 8) K.MATSUMOTO,M.Nogami, M.Toda, H.Katsura, N.Hayashi, and R.Tamura: "Synthesis of Diazathia 15- and 18-Crown Ethers and Their Transport Properties for Metal Cations" Heterocycles. 47. 101-106 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 9) K.MATSUMOTO,M.Kaneko, H.Katsura, N.Hayashi, T.Uchida, and R.M.Acheson: "The Synthesis and Reactions of Heterocycles under High Pressures : Part II" Heterocycles. 47. 1135-1177 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 1) T.IBATA,M.Shang, and T.Demura: "Nucleophilic Substitution Reaction of p-Chloronitrobenzene with N-Substituted Cyclic Amines under High Pressure" Heterocyclic Commun.1. 241-244 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 2) T.IBATA,M.Shang, and T.Demura: "Reaction of Mono-, Di-, and Trichloronitrobenzenes with N-Methyl Substituted Cyclie Tertiary Amines under High Pressure" Bull.Chem.Soc.Jpn.68. 2717-2726 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) T.IBATA,M.Shang, and T.Demura: "The Nucleophilic Substitution Reaction of p-Chloronitrobenzene with N-Substituted Cyclic Amines under High Pressure" Bull.Chem.Soc.Jpn.68. 2941-2949 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) T.IBATA,X.Zou, and T.Demura: "The S_NAr Reaction of 2,3,5,6-Tetrachloronitrobenzene with Diamines under High Pressure : Formation of Cyclization Products" Bull.Chem.Soc.Jpn.68. 3227-3232 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) S.V.Chapyshev and T.IBATA: "New Type of Quinone-quinone Complexation in the Reaction of 2,5-Dichloro-1,4-benzoquinone with Morpholine at High Pressure" Russ.Chem.Bull.45. 469-470 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 1) T.Kimura, M.Fujita, H.Sohmiya, and T.ANDO: "The Site of the Sonochemically-Initiated Radical Reaction of Lead Tetraacetate with beta-Methylstirene" Chem.Lett.55-56 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kimura, M.Fujita, H.Sohmiya, and T.ANDO: "2) Isomerization Mechanism of alpha-Phenethyl Thiocyanate in the Presence of a SupportedReagent" Bull.Shiga Univ.Med.Sci. (General Education). 6. 1-5 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) T.Kimura, T.ANDO,T.Maruyama, T.Sugiyama, A.Ohno, and M.Okamura: "1,2-Bis (o-aminophenoxy) ethane-N,N,N', N'-tetraacetic Acid Derivatives on Complexation with Lanthanoid Metal Ions. Correlation between Size of Trapping Hole and Metal Ion" Heteroatom Chem.6. 57-62 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) T.ANDO: "Physical Control of Chemical Reactivity" Ultrasonics Sonochemistry. 3. S145 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) T.Kimura, T.Sakamoto, J.-M.Leveque, H.Sohmiya, M.Fujita, S.Ikeda, and T.ANDO: "Standardization of Ultrasonic Power for Sonochemical Reaction" Ultrasonics Sonochemistry. 3. S157-161 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 6) T.ANDO,M.Fujita, T.Kimura, J.-M.Leveque, J.-L.Luche, and H.Sohmiya: "Mechanism of Sonochemical Excitation in the Reactions of Lead Tetraacetate with Some Organic Substrates" Ultrasonics Sonochemistry. 3. S223-227 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 7) F.Hayakawa, T.Kimura, T.Maeda, M.Fujita, H.Sohmiya, M.Fujii, and T.ANDO: "DNA Cleavage Reaction and Linolic Acid Peroxidation Induced by Tea Catechins in the Presence of Cupric Ion" Biochem.Biophys.Acta. 1336. 123-131 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 1) H.TOMIOKA,H.Kawasaki, N.Kobayashi, and K.Hirai: "Chemistry of 1-Alkylfluorenylidenes. Steric Effects on Arylcarbene Reactivities" J.Am.Chem.Soc.117. 4483-4498 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 2) H.TOMIOKA,and J.Nakajima: "Thermolysis and Photolysis of 1-Substituted Triptycenes. Divergent Fragmentation Pathways of Triptycyl Skeleton" J.Chem.Soc., Perkin Trans.1. 563-569 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) H.TOMIOKA,and K.Hirai: "Generation and Characterization of Persistent Triplet Diphenylcarbone" Yuki Gohsei Kagaku Kyokaishi. 54. 783-793 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) H.TOMIOKA: "Maxtrix Isolation Study of Reactive o-Quinoid Compounds : Generation, Detection and Reactions" Pure Appl.Chem.69. 837-840 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) H.TOMIOKA,and K.Taketsuji: "Flash Vacuum pyrolysis of Trifluoromethylated Diphenyldiazomethanes. Role of Trifluoromethyl Group on the Arylcarbene Rearrangement" J.Chem.Soc.Chem.Commun.1745-1746 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 8) H.TOMIOKA: "Persistent Triplet Carbenes" Acc.Chem.Res.315-321 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 1) M.KUZUYA,J.Niwa, and T.Noguchi: "Electron Spin Resonance study on Plasma-Induced Surface Radicals of Ethylene-Tetrafluoroethylene Copolymer" Polymer J.27. 251-255 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 2) M.KUZUYA,Y.Yamauchi, J.Niwa, S.Kondo, and Y.Sakai: "Spectrochemistry of Plasma-Induced Free Radicals in Cellulose Derivatives" Chem.Pharm.Bull.43. 2037-2041 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 3) M.KUZUYA,and T.Yamashiro: "A Novel Method for Introduction of Plasma-Induced Hydrophilicity on Polyethylene-Naphthalate" J.Photopolym.Sci.Technol.8. 381-384 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 4) M.KUZUYA,M.Sugito, and S.Kondo: "Special Features of Peroxy Radicals on Plasma-Irradiated Polymers" J.Photopholym.Sci.Technol.9. 261-264 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 5) M.KUZUYA,Y.Yamauchi, J.Niwa, and S.Kondo: "Effect of Alkyl substituent on Plasma-Induced Free Radicals of Cellulose Derivatives" Proc.Jpn.Symp.Plasma Chem.9. 55-60 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 6) M.KUZUYA,S.Kondo, and M.Sugito: "Plasma-Induced Surface Radicals of Low Density Polyethylene Studied by Electron spin resonance" Polymer Preprints(ACS). 38. 1049-1050 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 7) M.KUZUYA,M.Sugito, and Kondo: "Nature of Auto-Oxidations on Plasma-Induced surface Radicals of Polyethylene Studied by Electron Spin Resonance" J.Photopolym.Sci.Technol.10. 135-138 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 6) H.TOMIOKA: Generation of Carbonyl Yides. Nitrene.Oxygen and Sulfur Ylides in Synthesis : A Practical Approach. ed.by J.S.Clark, Oxford University Press, Oxford, (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] 7) H.TOMIOKA: Persistent Triplet Carbenes. Advances in Carbene Chemistry, Vol.2 ed.by U.Brinker, JAI Press, Greenwich, (1997)

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 1999-03-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi