1995 Fiscal Year Annual Research Report

固体高分解能NMRによる先端高分子材料の構造と物性の精密解析

Research Project

Project/Area Number	07305064
Research Institution	Tokyo Institute of Technology
Principal Investigator	井上義夫東京工業大学, 生命理工学部, 教授 (60016649)
Co-Investigator(Kenkyū-buntansha)	辻田義治名古屋工業大学, 工学部, 教授 (70016591) 朝倉哲郎東京農工大学, 工学部, 教授 (30139208) 引地邦男北海道大学, 大学院・理学研究科, 教授 (30000805) 安藤勲東京工業大学, 工学部, 教授 (20016637) 堀井文敬京都大学, 化学研究所, 教授 (70124758)
Keywords	固体高分解能NMR / 高分子材料 / 高分子構造 / 高分子物性 / 機能性高分子 / 高分子結晶
Research Abstract	先端高分子材料の必須の精密分析法として期待されている固体高分解能NMR法の現状を把握し,先端高分子材料の構造と物性を精密解析するために解決すべき問題点を明らかにし,新測定技術の開発,精密解析の根拠となる理論の構築および種々の高分子材料の特性解析への応用展開を図る事を本総合研究の主目的とした。固体高分解能NMR法の新技術の開発,理論構築,応用展開のいずれかの分野ですでにかなりの成果をあげつつある多くの研究者を結集し,相互に情報を交換し,新たな協同研究を組織する機会を提供し,よって今後の先端高分子材料の精密解析の一層の促進を図るための基礎作りをすることも本総合研究の大きな目標の一つとして,「固体高分解能NMR法の新測定技術の開発」班,「NMR情報の理論解析」班,および「高分子分析への応用の新展開」班の3班を組織し,それぞれ5名,3名,5名それに研究代表者を加えて合計14名で研究を行った。本総合研究の採択が決定されたのは年度後半であったために,全体会議と公開講演会をそれぞれ1回開催するにとどまったが,第44回高分子討論会(9月,大阪),第33回生物物理学会(9月,札幌),第34回NMR討論会(9月,大阪)などの関連学会に本総合研究の分担研究者のほとんどが参加しており,分担研究者間の学術交流が活発に行われ,短期間ではあったが本総合研究の目的のほとんどは達成できた。また公開講演会については学会誌等に会告を掲載した結果,本総合研究の全分担研究者のほかに多数の一般来聴者があり,本研究の成果を公表する良い機会となった。さらに,本総合研究の成果を広く公表するために,研究成果報告書を作成した。

Research Products

(25 results)

All Other

All Publications (25 results)

[Publications] Naoko YOSHIE: "Complex Composition Distribution of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)" Macromolecules. 28. 6516-6521 (1995)
[Publications] Masafumi ICHIKAWA: "Morphological Study of Bacterial Poly(3-hydroxybutyrate-co-3-hydroxypropionate)" Macromolecular Chemistry and Physics. (印刷中).
[Publications] Ryuzo KITAMARU: "Solid-Solid Phase Transformation of Uniaxially Oriented n-Alkane Crystals of High Purity" Journal of Molecular Structure. 355. 95-104 (1995)
[Publications] M.WADA: "Characterization of Tension and Normally Lignified Wood Cellulose in Populous Maximowiczii" Cellulose. 2. 223-233 (1995)
[Publications] Akinori TEZUKA: "Solid State Deuteron NMR Study of Polystyrene/Poly(vinyl methylether)Blend" Journal of Molecular Structure. 355. 1-7 (1995)
[Publications] Akinori TEZUKA: "Phase Separation and Microscopic Homogenization of Polystyrene/Poly(vinyl methylether)by Solid State H-2 NMR" Journal of Molecular Structure. 355. 9-13 (1995)
[Publications] Toshifumi HIRAOKI: "Methyl Group Dynamics in Methyl-p-Nitrobenzenesulfonate by Solid State Deuterium NMR" Journal of Molecular Structure. 355. 143-146 (1995)
[Publications] Satoshi KITAZAWA: "Solid State H-2 NMR Study of Racemic Poly(γ-benzylglutamate)" Journal of Molecular Structure. 355. 87-94 (1995)
[Publications] Kiyonori TAKEGOSHI: "Miscibility and Molecular Motion of Poly(methyl acrylate)/Poly-(vinyl acetate)Blend as Studied by ^<13>C NMR IN THE Solid State" Polymer Journal. 27. 284-291 (1995)
[Publications] Toshikazu MIYOSHI: "High-Resolution Solid-State ^<13>c NMR Study of a Polymer Complex: Poly(methacrylic acid)/Poly(ethylene oxide)" Polymer. 37. 11-18 (1996)
[Publications] Keika SHIN: "Molecular Miscibility of Phosphatidylcholine and Phosphatidyl-ethanolamine in Binary Bilayers Studied by ^2H and ^<31>P NMR" Biochim. Biophys. Acta. 1238. 42-48 (1995)
[Publications] Toshimichi FUJIWARA: "^<13>C-^<13>C and ^<13>C-^<15>N Dipolar Correlation NMR of Uniformly Labeled Organic Solids for the Complete Assignment of Their ^<13>C and ^<15>N Signals" Journal of American Chemical Society. 117. 11351--11352 (1995)
[Publications] M.KOBAYASHI: "Structural Study of Poly(vinyl slcohol)in the Gel State by High Resolution Solid-State ^<13>C NMR Spectroscopy" Macromolecules. 28. 6677-6679 (1995)
[Publications] K. TSUCHIYA: "Hydrigen-Bonding Effect on ^<13>C NMR Chemical Shifts of Amino Acid Residue Carbonyl Carbons of Some Peptides in the Crystalline State" Journal of Molecular Structure. 350. 233-240 (1995)
[Publications] M. P. Williamson: "Application of ^1H NMR Chemical Shifts to Measure the Quality of Protein Structures" Journal of Molecular Biology. 247. 541-546 (1995)
[Publications] K. Umemoto: "Conformations of Synthetic Model Peptides for Plasmodium falciparum Circumsporozite Protein by ^1H NMR and Distance Geometry" Polymer Journal. 27. 347-360 (1995)
[Publications] Hiromichi KUROSU: "Structural Characterization of Polypyryole in the Solid State by High Resolution ^<15>N NMR Spectroscopy[II]" Journal of Polymer Science: Part B. 33. 769-775 (1995)
[Publications] Hiromichi KUROSU: "Structural Characterization of Polyacenic Polymers in the Solid State by High-Resolution ^<13>C NMR Spectroscopy" Journal of Molecular Structure. 355. 27-32 (1995)
[Publications] Akira NAITO: "Phenyl Ring Dynamics of the Insulin Fragment Gly-Phe-Phe(B23-B25) by Solid-State Deuterium NMR" Journal of Molecular Structure. 355. 55-60 (1995)
[Publications] Hajime SAITO: "Conformational Characterization of Polysaccharides as Studied by High-Resolution ^<13>C Solid State NMR" Annual Report on NMR Spectroscopy. 31. 157-170 (1995)
[Publications] Akira NAITO: "Conformational Diversity and Differential Tyrosyl Motions in Met-and Leu-Enkephalins and Related Peptides as Studied by High-Resolution Solid-State ^<13>C NMR Spectroscopy" Journal of Physical Chemistry.
[Publications] Takeshi YAMANOBE: "^<13>C CPMAS NMR Study of the Structure of p-t-butylcalix[4]arenealkylbenzene clathrates in the Solid State" Journal of Molecular Structure. 355. 15-20 (1995)
[Publications] Takeshi YAMANOBE: "Structure and Physical Properties of Naphthalene Containing Polyesters I. Structure of Poly(butylene 2,6-naphthalene)and Poly(ethylene 2,6-naphthalate)as Studied by Solid State NMR" Polymer Journal. 28. 177-181 (1995)
[Publications] Naoko YOSHIE: Journal of Applied Polymer Science.
[Publications] Naoko YOSHIE: "Crystallization and Compatibility of Poly(vinyl alcohol)/Poly-(3-hydroxybutyrate)Blends.Influence of Blend Composition and Tacticity of Poly(vinyl alcohol)" Polymer Journal. 28. 45-50 (1996)

1995 Fiscal Year Annual Research Report

固体高分解能NMRによる先端高分子材料の構造と物性の精密解析

Principal Investigator

井上 義夫 東京工業大学, 生命理工学部, 教授 (60016649)

Research Products

[Publications] Naoko YOSHIE: "Complex Composition Distribution of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)" Macromolecules. 28. 6516-6521 (1995)

[Publications] Masafumi ICHIKAWA: "Morphological Study of Bacterial Poly(3-hydroxybutyrate-co-3-hydroxypropionate)" Macromolecular Chemistry and Physics. (印刷中).

[Publications] Ryuzo KITAMARU: "Solid-Solid Phase Transformation of Uniaxially Oriented n-Alkane Crystals of High Purity" Journal of Molecular Structure. 355. 95-104 (1995)

[Publications] M.WADA: "Characterization of Tension and Normally Lignified Wood Cellulose in Populous Maximowiczii" Cellulose. 2. 223-233 (1995)

[Publications] Akinori TEZUKA: "Solid State Deuteron NMR Study of Polystyrene/Poly(vinyl methylether)Blend" Journal of Molecular Structure. 355. 1-7 (1995)

[Publications] Akinori TEZUKA: "Phase Separation and Microscopic Homogenization of Polystyrene/Poly(vinyl methylether)by Solid State H-2 NMR" Journal of Molecular Structure. 355. 9-13 (1995)

[Publications] Toshifumi HIRAOKI: "Methyl Group Dynamics in Methyl-p-Nitrobenzenesulfonate by Solid State Deuterium NMR" Journal of Molecular Structure. 355. 143-146 (1995)

[Publications] Satoshi KITAZAWA: "Solid State H-2 NMR Study of Racemic Poly(γ-benzylglutamate)" Journal of Molecular Structure. 355. 87-94 (1995)

[Publications] Kiyonori TAKEGOSHI: "Miscibility and Molecular Motion of Poly(methyl acrylate)/Poly-(vinyl acetate)Blend as Studied by ^<13>C NMR IN THE Solid State" Polymer Journal. 27. 284-291 (1995)

[Publications] Toshikazu MIYOSHI: "High-Resolution Solid-State ^<13>c NMR Study of a Polymer Complex: Poly(methacrylic acid)/Poly(ethylene oxide)" Polymer. 37. 11-18 (1996)

[Publications] Keika SHIN: "Molecular Miscibility of Phosphatidylcholine and Phosphatidyl-ethanolamine in Binary Bilayers Studied by ^2H and ^<31>P NMR" Biochim. Biophys. Acta. 1238. 42-48 (1995)

[Publications] Toshimichi FUJIWARA: "^<13>C-^<13>C and ^<13>C-^<15>N Dipolar Correlation NMR of Uniformly Labeled Organic Solids for the Complete Assignment of Their ^<13>C and ^<15>N Signals" Journal of American Chemical Society. 117. 11351--11352 (1995)

[Publications] M.KOBAYASHI: "Structural Study of Poly(vinyl slcohol)in the Gel State by High Resolution Solid-State ^<13>C NMR Spectroscopy" Macromolecules. 28. 6677-6679 (1995)

[Publications] K. TSUCHIYA: "Hydrigen-Bonding Effect on ^<13>C NMR Chemical Shifts of Amino Acid Residue Carbonyl Carbons of Some Peptides in the Crystalline State" Journal of Molecular Structure. 350. 233-240 (1995)

[Publications] M. P. Williamson: "Application of ^1H NMR Chemical Shifts to Measure the Quality of Protein Structures" Journal of Molecular Biology. 247. 541-546 (1995)

[Publications] K. Umemoto: "Conformations of Synthetic Model Peptides for Plasmodium falciparum Circumsporozite Protein by ^1H NMR and Distance Geometry" Polymer Journal. 27. 347-360 (1995)

[Publications] Hiromichi KUROSU: "Structural Characterization of Polypyryole in the Solid State by High Resolution ^<15>N NMR Spectroscopy[II]" Journal of Polymer Science: Part B. 33. 769-775 (1995)

[Publications] Hiromichi KUROSU: "Structural Characterization of Polyacenic Polymers in the Solid State by High-Resolution ^<13>C NMR Spectroscopy" Journal of Molecular Structure. 355. 27-32 (1995)

[Publications] Akira NAITO: "Phenyl Ring Dynamics of the Insulin Fragment Gly-Phe-Phe(B23-B25) by Solid-State Deuterium NMR" Journal of Molecular Structure. 355. 55-60 (1995)

[Publications] Hajime SAITO: "Conformational Characterization of Polysaccharides as Studied by High-Resolution ^<13>C Solid State NMR" Annual Report on NMR Spectroscopy. 31. 157-170 (1995)

[Publications] Akira NAITO: "Conformational Diversity and Differential Tyrosyl Motions in Met-and Leu-Enkephalins and Related Peptides as Studied by High-Resolution Solid-State ^<13>C NMR Spectroscopy" Journal of Physical Chemistry.

[Publications] Takeshi YAMANOBE: "^<13>C CPMAS NMR Study of the Structure of p-t-butylcalix[4]arenealkylbenzene clathrates in the Solid State" Journal of Molecular Structure. 355. 15-20 (1995)

[Publications] Takeshi YAMANOBE: "Structure and Physical Properties of Naphthalene Containing Polyesters I. Structure of Poly(butylene 2,6-naphthalene)and Poly(ethylene 2,6-naphthalate)as Studied by Solid State NMR" Polymer Journal. 28. 177-181 (1995)

[Publications] Naoko YOSHIE: Journal of Applied Polymer Science.

[Publications] Naoko YOSHIE: "Crystallization and Compatibility of Poly(vinyl alcohol)/Poly-(3-hydroxybutyrate)Blends.Influence of Blend Composition and Tacticity of Poly(vinyl alcohol)" Polymer Journal. 28. 45-50 (1996)

井上義夫東京工業大学, 生命理工学部, 教授 (60016649)