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1996 Fiscal Year Final Research Report Summary

A study of wavefunction and chemical bonding by (e, 2e) electron momentum spectroscopy

Research Project

Project/Area Number 07404032
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

UDAGAWA Yasuo  Research Institute for Scientific Measurements, Tohoku Univ.Prof., 科学計測研究所, 教授 (00004458)

Co-Investigator(Kenkyū-buntansha) HAYASHI Hisashi  Research Institute for Scientific Measurements, Tohoku Univ.Asistant, 科学計測研究所, 助手 (60250833)
TAKAHASHI Masahiko  Research Institute for Scientific Measurements, Tohoku Univ.Asistant, 科学計測研究所, 助手 (80241579)
Project Period (FY) 1995 – 1996
Keywords(e, 2e) spectroscopy / inelastic scattering / thiol
Research Abstract

In modern chemistry, the basis on understanding of molecular properties and reactivities is the wavefunction. Fukui's theory, which won a Nobel prize, is just an exammple. Ususally, however, the wavefunction is understood to be an abstract concept, not as an real physical existence. It is because it is rare that the wavefunction is measured directly.
In this project it is aimed to establish (e, 2e) spectroscopy which makes it possible to determine wavefunctions. Thus a spectrometer, which consists of spherical electron analyzer and multichannel detectors, has been developed. It has been found that the energy resolution, momentum resolution and momentum range covered are 1.5eV,0.2au., and 3.5au., respectively. This spectrometer features in fast compilation of data owing to multichannel detection.
Using this spectrometer electronic states of thiols including hydrogen sulfide and furan are studied, which has been published already.

  • Research Products

    (4 results)

All Other

All Publications (4 results)

  • [Publications] M.Takahashi,H.Nagasaka,and Y.Udagawa,: "Electron Momentum Spectroscopy Study of Lone Pair Orbitals of Thiols and Dimethyl Sulfide." J.Phys.Chem.101. 528-532 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋正彦 他: "マルチチャンネル運動量(e,2e)分光装置の試作。" 東北大学科学計測研究所報告. 43. 55-72 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Takahashi, H.Nagasaka, and Y.Udagawa: "Electron Momentum Spectroscopy Study of Lone Pair Orbitals of Thiols and Dimethyl Sulfide." J.Phys.Chem.101. 528-532 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Takahashi et al.: "A construction of multichannel (e, 2e) spectrometer" Bull.RISM.44. 55-72 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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