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1996 Fiscal Year Final Research Report Summary

Hydration of components in BOF slag

Research Project

Project/Area Number 07455301
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

IWASE Masanori  Kyoto Univ.Energy Science Professor, エネルギー科学研究科, 教授 (00026329)

Project Period (FY) 1995 – 1996
KeywordsSteelmaking / Slag / Mineral phase
Research Abstract

Thermodynamic analysis of slag system with a particular emphasis on hydration with water vapor was conducted for the systems CaO+P2O5+FeO and binary alkaline sulphates. Kinetic studies were also made for the reaction CaO+H2O+=Ca(OH)2 at steam pressure of 0.1 to 0.3 atm and temperatures between 100 and 400 degree centi-grade. Kinetic analysis revealed that the rate controlling step for this reaction would be chemical reaction between solid lime and water vapor.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] H. Hoshino and M. Iwase: "Chamical potentials of components in the system CaO+P_2O_5+Fe_xO" Metallurgical Transactions. 24 B. 595-603 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Yamamoto and M. Iwase: "Oxydation-reduction equilibrium of Cu^<2+>/Cu^+ equilibrium in bainary alkaline sulfate melts" Metallurgical Transactions. 27 B. 385-392 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Hoshino and M. Iwase: "Chemical potentials of oxygen for mixtures of Cao (s)+Ca_4P_2O_9 (s)+{Cao+P_2O_5+Fe_xO} melts and Ca_4P_2O_9 (s)+Ca_3P_2O_8 (s)+{CaO+P_2O_5+Fe_xO} melts" Metallurgical Transactions. 27 B. 375-378 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Watanabe and M. Iwase: "Deprssion of vaporization of melts formed during the immobilization of high level nuclear waste by the addition of P_2O_5" Radioactive Waste Management Restoration and Environmental. 20. 61-71 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] V. Espejo and M. Iwase: "A Thermodynamic study of CaO+Al_2O_3+Fe_xO at 1673K" Metallurgical Transactions. 26 B. 257-264 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R. Kawabata and M. Iwase: "Activities of phosphorous in Ni+P alloys saturated with solid Ni" Metallurgical Transactions. 26 B. 783-787 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Hoshino and M.Iwase: "Chemical potentials of components in the system CaO+P_2O_5+Fe_xO" Metallurgical Transactions. vol.24B. 595-603 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Yamamoto, N.Yamano-uchi, M.Tamura and M.Iwase: "Oxydation-reduciton equilibrium of Cu^<2+>/Cu^+ equilibrium in bainary alkaline sulfate melts" Metallurgical Transactions. vol.27B. 385-392 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Hoshino and M.Iwase: "Chemical potentials of oxygen for mixtures of CaO (s) +Ca_4P_2O_9 (s) + {CaO+P_2O_5+Fe_xO} melts and Ca_4P_2O_9 (s) +Ca_3P_2O_8 (s) + {CaO+P_2O_5+Fe_xO} melts" Metallurgical Transactions. vol.27B. 375-378 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Watanabe and M.Iwase: "Depression of vaporization of melts formed during the immobilization of high level nuclear waste by the addition of P_2O_5" Radioactive Waste Management and Environmental Restoration. vol.20. 61-71 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] V.Espejo and M.Iwase: "A Thermodynamic study of CaO+Al_2O_3+Fe_xOat 1673 K" Metallurgical Transactions. vol.26B. 257-264 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Kawabata and M.Iwase: "Activities of phosphorous in Ni+P alloys saturated with solid Ni" Metallurgical Transactions. vol.26B. 783-787 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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