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1996 Fiscal Year Final Research Report Summary

Simultaneous Epoxidation of Olefin and Hydroxylation of Aromatics during Water Electrolysis

Research Project

Project/Area Number 07455320
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 触媒・化学プロセス
Research InstitutionTokyo Institute of Technology

Principal Investigator

OTSUKA Kiyoshi  Tokyo Institute of Technology, Chemical Engineering, Professor, 工学部, 教授 (60016532)

Co-Investigator(Kenkyū-buntansha) YAMANAKA Ichiro  Tokyo Institute of Technology, Chemical Engineering, Associate Researcher, 工学部, 助手 (90240051)
Project Period (FY) 1995 – 1996
KeywordsEpoxidation / Propylene oxide / propylene / Hydroxylation / Phenol / Benzene / Water electrolysis / Active oxygen
Research Abstract

Epoxidation of olefins is extremely important both in the current industrial process and organic synthesis because epoxide is one of the most useful synthetic intermediates. Most of all commercial epoxidation reactions are indirect, multi-step co-oxidations. Moreover, these processes require a labile, explosive and expensive oxidant such as hydrogen peroxide or tert-butyl hydroperoxide. While, phenol that is also one of the most important chemical in industry, is manufactured by the Cumene process, multi process. Therefore, one-step syntheses of epoxide and phenol are most desirable process in industry.
The purpose in this work is to success simultaneous epoxidation of olefin at anode and hydroxylation of aromatics at cathode during the water electrolysis. First, many anodes were tested for the epoxidation of 1-hexene during the water electrolysis by using the cell, [1-hexene, CH_2Cl_2, anode|H_3PO_4/silica wool|cathode, H_2O/He]. We found that Pt-black anode is the most active for the epoxidation of 1-hexene at room temperature. This Pt-black anode is active for the epoxidation of propylene to propylene oxide at room temperature. During this epoxidation, much H_2 is produced at cathode. We have already reported that the hydroxylation of benzene to phenol during H_2-O_2 fuel cell reactions at cathode. The most active cathode for the formation of phenol is Pd-black+Fe_2O_3/Carbon Whisker. Then, we applied this cathode to the electrolysis cell for epoxidation. We found that simultaneou formation of 1,2-epoxyhexane at anode and formation of phenol at cathode during water electrolysis using the electrolysis cell, [1-hexene, CH_2Cl_2, Pt-black anode|H_3PO_4 aq./silica wool|Pd-balck+Fe_2O_3/CW cathode, benzne, O_2].

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Kiyoshi Otsuka: "Generation of Phenol and Electricity by Using Copper-Based Cathodes in O_2-H_2 Full Cell System" Electrochim. Acta. (in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiyoshi Otsuka: "Partial Oxidation of Light Alkanes during O_2-H_2 Cell Reactions at Room Temperature" Chem. Lett.(in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiyoshi Otsuka: "Electrocatalytic Synthesis of Propylene Oxide during Water Electrolysis" J. Catal.157. 450-460 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 大塚 潔: "電解酸化法によるプロピレンオキサイドの一段合成" 触媒. 37. 408-411 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiyoshi Otsuka: "Partial Oxidation of Benzene over the Carbon Whisker Cathode Added with Iron Oxide and Palladium Black during O_2-H_2 Fuel Cell Reactions" Stud. Surf. Sci. Catal.82. 703-711 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiyoshi Otsuka: "Simultaneous Epoxidation of 1-Hexene and Hydroxylation of Benzene during Electrolysis of Water" Chem. Lett.10. 1861-1864 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiyoshi Otsuka, Mituhiro Kunieda, Ichiro Yamanaka, and Qinghong Zhang: "Generation of Phenol and Electricity by using Copper-based Cathodes in O_2-H_2 Fuel Cell Systems." Electrochim, Acta. (in press.). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Qinghong Zhang, and Kiyoshi Otsuka: "Partial Oxidation of Light Alkanes during O_2-H_2 Fuel Cell Reactions at Room Temperature." Chem.Lett.(in press.). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiyoshi Otsuka, Tetsuya Ushiyama, and Ichiro Yamanaka: "Electrocatalytic Synthesis of Propylene Oxide during Water Electrolysis." J.Catal. 157. 450-460 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiyoshi Otsuka, Ichiro Yamanaka, and Tetsuya Ushiyama: "Epoxidation of Propylene with Nascent Oxygen Generated by H_2O Electrolysis." Shokubai. 37. 408-411 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiyoshi Otsuka, Mitsuhiro Kunieda, and Ichiro Yamanaka: "Partial Oxidation of Benzene over the Carbon Whisker Cathode Added with Iron Oxide and Palladium Black during O2-H2 fuel Cell Reactions." Stud.Surf.Sci.& Catal.82. 703-711 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiyoshi Otsuka, Ichiro Yamanaka, and Makoto Hagiwara: "Simultaneous Epoxidation of 1-Hexene and Hydroxylation of Benzene during Electrolysis of Water." Chem.Lett.1861-1864 (1994)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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