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1996 Fiscal Year Final Research Report Summary

Synthesis, Strucure and Properties of Rare Earth Oxide-Containing Silico phosphate Glasses and Glass Seramics

Research Project

Project/Area Number 07455350
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 無機工業化学
Research InstitutionTOKYO METROPOLITAN UNIVERSITY

Principal Investigator

YAMASHITA Kimihiro  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant Professor, 工学部, 助教授 (70174670)

Co-Investigator(Kenkyū-buntansha) HAMAGAMI Jun-ichi  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant, 工学部, 助手 (30285100)
SUDA Seiichi  Faculty of Engineering TOKYO METROPOLITAN UNIVERSITY Assistant, 工学部, 助手 (50226578)
Project Period (FY) 1995 – 1996
KeywordsRare-Earth Oxide / Silicophosphate / Solid Electolyte / Nasicon / Glass / Glass-Ceramics / Hydroxyapatite / Cerai Ceramics
Research Abstract

We have carried out the studies on the synthesis, structure and properties of the rare earth oxide-containing ceramics, which cover the projects of (1) glass and glass-ceramics of Na^+-Ion conducting silicophosphates (Narpsio) , (2) Stabilized zirconia and cerai ceramics, and (3) proton conducting hydroxyapatite and its coating methods.
In project (1), we successfully produced glass-ceramics of fast sodium ion conductors, which are invaluable for application of Na/S secondary batteries. The synthetic method, conduction mechanism, and other fundamental properties were established.
In project (2), rare earth oxide-stabilized zirconia and ceria ceramics were developed as high temperature pH and oxygen sensors. For this research, we have performed the electrophoretic lamination technique which enabled to insert thin zirconia layr into conducting ceria ceramics.
In project (3), we investigated the proton conduction in ceramic hydroxyapatite, which is the well-known bimedical material. Thin film methods were also developed for this prupose. Additionally, we founf that the use of polarization property of the material is effective for crystal growth.

  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] K.Yamashita: "Hydrothermal Synthesis and Low Temperature Conduction Prperties" Solid State Ionics. 81. 53-60 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Suda: "The Effects of Sol-Gel Processes on Na^+ Ionic Condactivity" Phosphorus Research Bulletin. 5. 93-98 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yamashita: "Microstructural Effects on Conduction Properties of Na_5YS_<14>O_<12>" Journal of Electrochemical Society. 143・7. 2180-2186 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Suda: "^<29>Si NMR Analysis of Reactions between Ethoxytrimethylsilane" Journal of Ceramic Society of Japan. 104・6. 476-480 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yamashita: "Composition Effects on Na^+-Ion Conduction Properties" Solid State Ionics. 86-88. 585-588 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inda: "High Temperature pH Sensitivities of Stabilized Zirconia and Ceria" Solid State Ionics. 86-88. 1121-1124 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Matsuda: "Conduction Properties of Oxide Ion Conductor Ca_<12>Al_<14>O_<33>" Journal of Materials Science Lecters. 15. 933-934 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Suda: "The Effects of Sodium Ion on Hydrolysis and Condenfation" Journal of Non-Crystalliue Solids. 197. 65-72 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Inda: "Field-Assisted Li^+-Ion Exchange of Na^+-Super Ionic Conductor" Phosphorus Research Balletin. 6. 251-254 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yamashita: "Accerelation and Decerelation of Bone-Like Crestal" Chemistry of Materials. 8・12. 2697-2700 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Suda: "Synthesis of Na^+ Super Ionic Conductor in the Na_2O-Y_2O_3-P_2O_5-SiO_2" Solid State Ionics. 89. 75-80 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yamashita: "Bonelike Coatings onto Ceramics by Reatlue Sputtering" Journal of American Ceramic Society. 79・12. 3313-3316 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yamashita, M.Greenblatt, K.V.Ramanujachary: "Hydrothermal Synthesis and Low Temperare Conduction Properties of Substituted Ceria Ceramics" Solid State Ionics. 81. 53-60 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "The Effects of Sol-Gel Processes on Na^+ Ionic Conductivity for the Na_2 O-Y_2 O_3 -P_2 O_5 -SiO_2 System" Phos. Res. Bull.5. 93-98 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yamashita, T.Umegaki, M.Tanaka, T.Nojiri: "Microstructural Effects on Conduction Properties of Na_5 YSi_4 O_<12>-Type Glass-Ceramic Na^+ -Fast Ionic Con ductors" J.Electrochem. Soc.143 (7). 2180-2186 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "^<29>Si NMR Analysis of Reactions between Ethoxytrimethylsilane and Alkali Ions" J.Ceram. Soc. Jpn.104 (6). 476-480 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yamashita, T.Kakuta, B.Sakurai, T.Umegaki: "Composition Effects on Na^+ -Ion Conduction Properties and Structure of Narpsio Glass-Ceramics" Solid State Ionics. 86-88. 585-588 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Inda, K.Yamashita, T.Umegaki, M.Greenblatt: "High Temperature pH Sensitivities of Stabilized Zirconia Ceramic Films and Ceria Ceramics" Solid State Ionics. 86-88. 1121-1124 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Matsuda, Y.Inda, W.Hisamatsu K.Yamashita, T.Umegaki: "Conduction Properties of Oxide Ion Conductor Ca_<12> Al_<14> O_<33> Prepared with Solution-Synthesized Powders" J.Mat. Sci. Lett.15. 933-934 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Suda, M.Iwaida, K.Yamashita, T.Umegaki: "The Effects of Sodium Ion on Hydrolysis and Condensation of Diethoxydimethylsilane" J.Non-Cryst. Solids. 197. 65-72 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Inda, K.Yamashita, T.Umegaki: "Field-Assisted Li^+ -Ion Exchange of Na^+ -Super Ionic Conductor Narpsio : Method and Experiments" Phos. Res. Bull.6. 251-254 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yamashita, N.Oikawa, T.Umegaki: "Acceleration and Deceleration of Bone-like Crystal Growth on Ceramic Hydroxyapatite by Electric Poling" Chem. Mat.8. 2697-2700 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Suda, K.Yamashita, T.Umegaki: "Synthesis of Na^+ Superionic Conductor in the Na_2 O-Y_2 O_3 -P_2 O_5 -SiO_2 System by the Gelation Induced by Moist Air or N_2" Solid State Ionics. 89. 75-80 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yamashita, T.Yagi, T.Umegaki: "Bonelike Coatings onto Ceramics by Reactive Magnetron Sputtering" J.Am. Ceram. Soc.79. 3313-3316 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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