• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

1996 Fiscal Year Final Research Report Summary

New Polymer Synthesis by Radical/ion Transformation Polymerization

Research Project

Project/Area Number 07455375
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionOsaka University

Principal Investigator

KAMACHI Mikiharu  Osaka University Graduate School of Science, Professor, 大学院・理学研究科, 教授 (40028163)

Co-Investigator(Kenkyū-buntansha) KAJIWARA Atsusi  Osaka University Graduate School of Science, Research Associate, 大学院・理学研究科, 助手 (50224415)
Project Period (FY) 1995 – 1996
KeywordsRadical / ion transformation polymerisation / Electron transfer Reaction / Cationic Poolymersation / Block Copolymerisation / Block Polymer / Electron Acceptor / Transformation of Active Spicies / Propagating Radical
Research Abstract

p-Methoxystirene (MOS), n-butyl vinyl ether (BVE), and N-vinylcarbazole (VCZ) were polymerized in high yield by azoinitiators such as AIBN in the presence of electron acceptors such as Ph_2I^+PF_6^-. ESR study of the model radicals of the growing ends and the propagating radical showed the transformation of the radical to the corresponding cation in the presence of the electron acceptors. In the case of BVE,the polymer formation was caused by cationic species produced by the transformation of initiating radical. The polymerizations of MOS and VCZ were ascribed to the transformation of the growing radical to the corresponding cation during the propagation step which was classified as the radical/cation transformation polymerization. Block copolymers of MOS/cyclohexene oxide (CHO) and VCZ/CHO were effectively prepared by the radical/cation transformation polymerization of MOS and VCZ,respectively, with AIBN in the presence of electron acceptor and CHO.The formation of block copolymers was characterized by turbidmetry, thin-layr chromatography, and solubility test.

  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] H.Guo, A.Kajiwara, Y.Morishima, M.Kamachi: "Radical/Cation Transformation Polymerization and Its Application to the Preparation of Block Copolymers…" Macromolecules. 29(7). 2354-2358 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Guo, A.Kajiwara, Y.Morishima, M.Kamachi: "Study on the Mechanism of the Cationic Polymerization of Cyclohexene Oxide Initiated by the Photosvstem…" Polymer Journal. 28(11). 960-964 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Guo, A.Kajiwara, Y.Morishima, M.Kamachi: "Polymerization of n-Butyl Vinyl Ether Photoinitiated by the Initiator System Poly(methyl phenvl silane)…" Polymer Journal. 29(in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Guo, A.Kajiwara, Y.Morishima, M.Kamachi: "Radical/Cation Transformation Polymerization and Its Application to the Preparation of Block Copolymers" Polymers for Advanced Technologies. (in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kamachi, H.Guo, A.Kajiwara: "Radical/Cation Transformation Polymerization and Its Application to the Preparation of Block Copolymers" Macromolecular Symposia. (in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kamachi, H.Guo, A.Kajiwara: "Radical/Cation Transformation Polymerization and Its Application to the Preparation of Block Copolymers" J.Macromolecular Science-Pure and Applied Chemistry. A34(10)(in press). (1997)

    • Description
      「研究成果報告書概要(和文)」より

URL: 

Published: 1999-03-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi