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1997 Fiscal Year Final Research Report Summary

レーザーアブレーション機構解明のためのナノ秒形態観察・分光システムと解析法の確立

Research Project

Project/Area Number 07554063
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 機能・物性・材料
Research InstitutionOsaka University

Principal Investigator

MASUHARA Hiroshi  Osaka University・Faculty of Engineering, Professor, 工学部, 教授 (60029551)

Co-Investigator(Kenkyū-buntansha) OKA Kouichi  Ootsuka Electronics Co.Ltd., Exective researcher, 研究開発1部, 部長(研究者)
SASAKI Keiji  Hokkaido University・Research Institute of Electronic Science, Professor, 電子科学研究所, 教授 (00183822)
FUKUMURA Hiroshi  Osaka University・Faculty of Engineering, Associate Professor, 工学部, 助教授 (50208980)
Project Period (FY) 1995 – 1997
KeywordsLaser Ablation / Time-resolved Interferometic Imaging / Time-resolved Spectroscopy / Condensed Organic Matters / Cyclic Multiphotonic Absorption / Photochemical Ablation / Photothermal Ablation
Research Abstract

Photophysical and photochemical phenomena due to interactions of materials with light have received much attention and the 21st century is considered to be "Century of Light". We have devoted our efforts to the studies on organic materials including films, microcrystalline powders, polymer microspheres, and so on by ultrafast spectroscopy, microspectroscopy, photoreaction, and optical manipulation, during which we found that materials often undergo morphological changes due to high intensity laser excitation. This morphological dynamics is very interesting and important not only from photophysical and photochemical viewpoints but also for elucidating the dynamic aspects of structures and properties of materials.
In the present work, we have developed nanosecond interferometry by combining Michelson interferometry with nanosecond excitation and probe lasers. The spatial and temporal resolutions of our system are 20 nm and 10 ns, respectively. Morphological dynamics revealed by the interferometry is compared with time-resolved absorption and fluorescence spectroscopic data and considered in detail, which is opening a new stage of molecular photoscience.
Development of a new methodology
Establishment of photothermal ablation mechanism by "cyclic multiphotonic absorption"
Establishment of photochemical ablation mechanism
Expansion/contraction dynamics of polymer film
Photodecomposition reaction and etching dynamics of polymers

  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] T.Lippart, L.S.Bsmott, T.Kure, C.Hslar, A.Wokaum, H.Furutani, H.Fukumura, H.Masuhara, T.Nakamura.A.Yabe: "Photopolymers designed for high resolution laser ablation ata specific irradiation wavelength" CPIE. vol.2992. 135-143 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Hosoda, H.Furutani, H.Fukumura, H.Masuhara, M.Nishiji, N.Tohimasa, S.Kanbara: "Laser Ablation Dymanics of Amorphous Film of a Cu-Phthalocyanine Derivative" The Review of Laser Engineering. vol.25. 306-311 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Furutani, H.Fukumura, H.Masuhara, T.Lippart, A.Yabe: "Laser-Induced Decomposition and Ablation Dynamics Studied by Nanosecond Interferometry 1.A Triazenopolymer Film" J.Phys.Chem.vol.101. 5742-5747 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Hatanaka, M.Kawas, Y.Tsuboi, H.Fukumura, H.Masuhara: "Switching from photochemical to photothermal mechanism in laser ablation of benezene solutions" J.Appl.Phys.vol.82. 5799-5806 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tsuboi, K.Hatanaka, H.Fukumura, H.Masuhara: "The 248 nm examer laser ablation mechanism of liquid benzine derivatives : photochemical formation of bcnzyl radical lead to ablation" J.Phys.Chem.(印刷中).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Furutani, H.Fukumura, H.Masuhara, S.Kanbara, T.Kitaguchi, H.Tsukada: "Laser-induced decomposition and ablation dynamics studied by nanosecond interferometry 2.A reactive microcellulose film" J.Phys.Chem.(印刷中).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 増原 宏(編集協力者): "ビジュアルレーザーの科学" 丸善株式会社, 183 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hiroshi Fukumura, Ei-ichi Takahashi, and Hiroshi Masuhara: "Time-resolved spectroscopic and photographic studies on laser ablation of poly (methyl methacrylate) film doped with biphenyl" J.Phys.Chem.99. 750 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yasuyuki Tsuboi, Hiroshi Fukumura, and Hiroshi Masuhara: "UV laser-induced jet formation from liquid surface as revealed by nanosecond time-resolved imaging and spectroscopic studies" J.Phys.Chem.99. 10305 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hisashi Fujiwara, Yoshinori Nakajima, Hiroshi Fukumura, and Hiroshi Masuhara: "Laser ablation dynamics of a poly (methyl methacrylate) film doped with 5-diazo Meldrum's acid" J.Phys.Chem.99. 11481 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hisashi Fujiwara, Hiroshi Fukumura, and Hiroshi Masuhara: "Laser ablation of a pyrene-doped poly (methyl methacrylate) film : dynamics of pyrene transient species by spectroscopic measurements" J.Phys.Chem.99. 11844 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yasuyuki Tsuboi, Shin-ichi Sakashita, Koji Hatanaka, Hiroshi Fukumura, and Hiroshi Masuhara: "Photothermal ablation of polystirene film by 248 nm excimer laser irradiation : a mechanistic study by time-resolved measurements" Laser Chem.16. 167 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Fukutani, Hiroshi Fukumura, and Hiroshi Masuhara: "Photothermal transient expansion and contraction dynamics of polymer films by nanosecond interferometry" J.Phys.Chem.100. 6871 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] L.S.Bennett, T.Lippert, H.Furutani, Hiroshi Fukumura, and Hiroshi Masuhara: "Laser induced microexplosions of a photosensitive polymer" Appl.Phys.A63. 327 (1996)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T.Lippert, L.S.Bennett, T.Kunz, C.Hahn, A.Wokaun, H.Furutani, H.Fukumura, H.Masuhara, T.Nakamura, and A.Yabe: "Photopolymers designed for high resolution laser ablation at a specific irradiation wavelength" SPIE. 2992. 135 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Masahiro Hosoda, Hiroshi Furutani, Hiroshi Fukumura, Hiroshi Masuhara, Masanobu Nishii, Nobuyuki Ichinose, and Shunichi Kawanishi: "Laser ablation dynamics of amorphous film of a Cu-phthalocyanine derivative" The Review of Laser Engineering. 25 (in Japanese). 306 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Furutani, H.Fukumura, H.Masuhara, T.Lippert, and A.yabe: "Laser-induced decomposition and ablation dynamics studied by nanosecond interferometry.1.a triazenopolymer film" J.Phys.Chem.A. 101. 5742 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Koji Hatanaka, Mitsushi Kawao, Yasuyuki Tsuboi, Hiroshi Fukumura, and Hiroshi Masuhara: "Switching from photochemical to photothermal mechanism in laser ablation of benzene solutions" J.Appl.Phys.82. 5799 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yasuyuki Tsuboi, Koji Hatanaka, Hiroshi Fukumura, and Hiroshi Masuhara: "The 248 nm excimer laser ablation mechanism of liquid benzene derivatives : photochemical formation of benzyl radical leads to ablation" J.Phys.Chem.(in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hiroshi Furutani, Hiroshi Fukumura, Hiroshi Masuhara, Sigeki Kambara, Toru Kitaguchi, Harumichi Tsukada, and Takeo Ozawa: "Laser-induced decomposition and ablation dynamics studied by nanosecond interferometry. 2. a reactive nitrocellulose film" J.Phys.Chem.(in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-16  

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