1996 Fiscal Year Final Research Report Summary
CREATION OF SUPPER FUNCTIONAL DYES BASED ON NEW CONCEPT
| Project/Area Number |
07555586
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 試験 |
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| Research Field |
有機工業化学
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| Research Institution | KINKI UNIVERSITY |
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Principal Investigator |
MATSUBARA Yoshio Faculty of Science and Engineering, Kinki University, Professor, 理工学部, 教授 (80088450)
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| Co-Investigator(Kenkyū-buntansha) |
YOSHIDA Zen-ichi Kyoto University, Honorary Professor, 名誉教授 (60025814)
TAKEKUMA Shinichi Faculty of Science and Engineering, Kinki University, Assistant professor, 理工学部, 講師 (00171629)
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| Project Period (FY) |
1995 – 1996
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| Keywords | Supper Functional Dyes / 4npi (60pi, 8pi) dyes system / gamma-cyclodextrin-C_<60> dyes / Fixing nitrogen / Bicapped C_<60> / Pyrazoline ring fused C_<60> dyes / Tokiirohiratake / Indolone as new 8pi system |
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| Research Abstract |
Important results obtained in this research are as follows :
1. We tried appearance of metal catalystic function based on new idea of C_<60> as super atom and were successful in finding fixing nitrogen to produce NH_3 using bicapped C_<60> with gamma-cyclodextrin. This result was extremely important.
2. On the other hand, we succeeded high yield synthesis of 1,3-diphenyl-2-pyrazoline ring fused C_<60>, and found the electrochemical propaties and emissivity of fluoresecnce.
3. Specially, we found indolone as new 8pi system pigment in tokiirohiratake (mushroom), and protein was synthsized in photosynthesis by the protein which include indolone. This is extremely important find on natural science as comparison of carbohydrate was synthsized by chlorofile photosynthesis.
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