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1997 Fiscal Year Final Research Report Summary

Construction of Fourier Transform Microwave Spectrometer for Unstable molecules

Research Project

Project/Area Number 07640670
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionShizuoka University

Principal Investigator

OGATA Teruhiko  Shizuoka University, Faculty of Science, Professor, 理学部, 教授 (60109121)

Project Period (FY) 1995 – 1997
Keywordsmicrowave spectroscopy / rotational spectrum / supersonic molecular beam / unstabie molecules / Fourier-transform / molecular structure
Research Abstract

The Fourier-transform microwave spectrometer has been successfully applied for the discovery of new molecules and the determinations of precise molecular structures. I myself have found many new molecules with FTMW spectrometers at University of British Columbia in Canada, at NIST in U.S.A., and at The University of Tokyo. This time, I have made the pulsed supersonic molecular beam, Fabry-Perot resonator, Fourier-transform microwave spectrometer at Faculty of Science, Shizuoka University. The followings are hte research results ;
1. The Fabry-Perot resonator has been designed and ordered
2. The vacuum chamber for the Fabry-Perot resonator has been designed and ordered.
3. The electronic circuits for the excitation of the molecular-beam and the detection of free induction decay signal have been designed and ordered.
4. The mechanical booster-pump was used for the faster measurements.
5. The spectrometer has been controlled by a personal computer with GB-IB interface.

  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] T.Ogata, S.Kuwano, and S.Oe: "Microwave spectrum,nuclear quadrupole coupling constants,and structure of bromodifluoromethane" J.Mol.Spectrosc.185. 147-152 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ogata, N.Yamashita, S.Takata: "Microwave spectrum,structure,nuclear quadrupole coupling constants of chlorine,and ab initio calculation of 2-chloropropionitrile" J.Mol.Struct.412. 39-46 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.A.Walker, T.Ogata, W.Jaeger, M.C.L.Gerry, and I.Ozier: "Pure rotational spectra of several rare gas-CO complexes:Ne-CO,Kr-CO and Xe-CO" J.Chem.Phys.106. 7519-7530 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ogata and Y.Niide: "Microwave spectra of monohalogenated allenes,Chloroallene and iodoallene" J.Chem.Soc.Faraday Trans.92. 4889-4895 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ogata and M.Kamitsuma: "″Microwave spectrum and iodine nuclear quadrupole coupling constants of 3-iodopropyne″" J.Mol.Struct.352/353. 345-355 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ogata, Y.Oshima, and Y.Endo: "Rotational spectra and structure of carbon monoxides C_5O,C_7O,and C_9O" J.Am.Chem.Soc.117. 3593-3598 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Oshima, Y.Endo, and T.Ogata: "Fourier-transform microwave spectroscopy of triplet carbon monoxides,C_2O,C_4O,C_6O,and C_8O" J.Chem.Phys.102. 1493-1500 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ogata, S.Kuwano, and S.Oe: "Microwave spectrum, nuclear quadrupole coupling constants, and structure of bromodifluoromethane" J.Mol.Spectrosc.185. 147-152 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ogata, N.Yamashita, S.Takata: "Microwave spectrum, structure, nuclear quadrupole coupling constants of chlorine, and ad initio calculation of 2-chloropropionitrile" J.Mol.Struct.412. 39-46 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.A.Walker, T.Ogata, W.Jaeger, M.C.L.Gerry, and I.Ozier: "Pure rotational spectra of several rare gas-CO complexes : Ne-CO,Kr-CO and Xe-CO" J.Chem.Phys.106 (18). 7519-7530 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ogata and Y.Niide: "Microwave spectra of monohalogenated allenes, Chloroallene and iodoallene" J.Chem.Soc.Faraday Trans.92 (24). 4889-4890 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ogata and M.Kamitsuma: "Microwave spectrum and iodine nuclear quadrupole coupling constants of 3-iodopropyne" J.Mol.Struct.352/353. 345-355 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ogata, Y.Oshima, and Y.Endo: "Rotational spectra snd structure of carbon monoxides C_5O,C_7O,and C_9O" J.Am.Chem.Soc.117 (12). 3593-3598 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Oshima, Y.Endo, and T.Ogata: "Fourier-transform microwave spectroscopy of triplet carbon monoxides, C_2O,C_4O,C_6O,and C_8O" J.Chem.Phys.102 (4). 1493-1500 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-16  

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