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1997 Fiscal Year Final Research Report Summary

Development of electrical conjugated polymers with liquid crystalline and magnetic properties

Research Project

Project/Area Number 07651092
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionUniversity of Tsukuba

Principal Investigator

AKAGI Kazuo  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (20150964)

Co-Investigator(Kenkyū-buntansha) SHIRAKAWA Hideki  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (40016720)
Project Period (FY) 1995 – 1997
KeywordsConjugated polymers / Polyacetylene derivatives / Liquid crystallinity / Stable radical group / Magnetic properties / Macroscopic orientation / Spin alignment / Organic ferromagnet
Research Abstract

Side-chain liquid crystalline (LC) conjugated polymer with stable radical group is expected to afford a parallel spin alignment with aids of spontaneous orientation and externally forced macroscopic alignment of LC side chains. The present study is aimed to achieve a macroscopic spin alignment through LC orientation, For this aim, di-substituted polyacetylene with LC group and stable radical group in side chains is useful, where the intrachain parallel spin alignment can be easily constructed on the basis of topological stereoregularity satisfying Ovchinnikov rule.
Di-substituted polyacetylene was synthesized by introducing both liquid crystalline LC group and stable radical group into side chains. Di-tert-butylphenol derivative, where the hydroxy moiety of the phenyl group was protected by trimethylsilyl group, was adopted as a stable radical precursor. Acetylene monomer substituted with the LC group and the radical precursor was polymerized using metathesis catalyst of TaCI_5-(n-Bu)_4Sn. The polymer synthesized was soluble in organic solvents and showed an enantiotropic smectic phase. ESR spin intensity of the polymer was evaluated after the radical precursor was deprotected and oxidized, Anisotropy in spin intensity, owing to spontaneous alignment of LC side chains, was confirmed.
Next, the mono-substituted polyacetylene copolymer was synthesized, where either the LC group or the radical group was substituted into the unit cell of main chain. The copolymer, in which the ratio of radical group-substituted polyene segment is less than 10 %, showed a smectic phase in 150 - 160゚C.The ESR intensity increased in the LC temperature. This is ascribed to the spin alignment of phenoxy radical electrons within LC domains.

  • Research Products

    (136 results)

All Other

All Publications (136 results)

  • [Publications] H.Shirakawa: "Synthesis and Characterization of Highly Conducting Polyacetylene" Synthetic Metals. 69. 3-8 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 69. 13-16 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Polyacetylene Films Prepared by Intrinsic Non-Solvent Polymerization Method-Mechanical Properties and Electrical Conductivities" Synthetic Metals. 69. 29-30 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Fused State ^<13>C-NMR Study on Liquid Crystalline Polyacetylene Derivatives-Magnetically Forced Alignment and Orientational Behavior" Synthetic Metals. 69. 33-34 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Sakamaki: "Thermodynamic Behavior of Cis-Trans Isomerization in S- and N-type Polyacetylene Films. DSC study" Synthetic Metals. 69. 57-58 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Thermotropic Liquid Crystalline Conjugated Polymers, Poly(cyclohexylphenoxyacetylenes)-Synthesis and Properties" Synthetic Metals. 71. 1899-1990 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Toyoshima: "Synthesis and Properties of Polythiophene Derivatives with Liquid Crystalline Substituents" Synthetic Metals. 69. 289-290 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] C.O.Yoon: "Effect of Anisotropy on the Temperature Dependence of Conductivity and Magnetoconductance in Heavily Doped Polyacetylene" Synthetic Metals. 69. 79-80 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yoshino: "Unique Electrical and Optical Properties of Polyacetylene Derivatives in Liquid Crystal Phase" Synthetic Metals. 69. 49-50 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E.B.Park: "Positive Thermoelectric Power of Alkali-Metal-Doped Polyacetylene" Synthetic Metals. 69. 61-62 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Electrically Conducting Liquid Crystalline Polymers,Mono-Substituted Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.267. 277-282 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Mizoguchi: "Analysis of the ESR Linewidth in Pristine Trans-Polyacetylene" Phys.Rev.B. 51. 8864-8873 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yoshino: "Unique Liquid Crystalline Behavior of Conducting Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.261. 637-647 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kyotani: "Isothermal Cis-Trans Isomerization Behavior of Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 581-585 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kyotani: "Thermal Isomerization and Morphology of Various Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 587-593 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tanabe: "Mechanism of Cis-Trans Thermal Isomerization of Polyacetylene" Macromolecules. 28. 4173-4178 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives" Macromolecular Symposia. 104. 137-158 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Conducting Polymers" Polymer Preprints, National Meeting of American Chemical Society. 37. 62-63 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Yoshino: "Liquid Crystalline Behaviors of Conducting Polyacetylene Derivative with Mesogenic Substituent and Its Mixture with Ferroelectric Liquid Crystal" Jpn.J.Appl.Phys.35. 3964-3970 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Aoki: "Current Progress in Synthesis of Polyacetylene Films" Synthetic Metals. 84. 307-310 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Mutable Morphologies of Polyacetylene Films" Synthetic Metals. 84. 419-420 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Sakamaki: "Relationship between Crystallinity and Electrical Conductivity of Highly Conducting Polyacetylene Films" Synthetic Metals. 84. 365-366 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers-Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. 84. 313-316 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Iino: "High Order Structures of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84. 967-968 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Synthesis and Properties of Photo-Responsible Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84. 373-374 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Synthesis and Propeties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic Metals. 84. 385-386 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly(thienylenevinylene) Derivatives with Hexyl Grops" Synthetic Metals. 84. 431-432 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Atoms" Synthetic Metals. 84. 1683-1684 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.Piao: "Spin Structures and Properties of Paramagnetic Nickel(II)Complexes with Liquid Crystalline β-Diketone Ligands" Synthetic Metals. 85. 1669-1670 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic Metals. 85. 1879-1880 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] D.Ichinohe: "Magnetic Properties of Poly(m-aniline)" Synthetic Metals. 85. 1671-1672 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Mizoguchi: "Neutral Soliton Dynamics in t-Polyacetylene-Consistent Picture for Magnetic Resonances" Synthetic Metals. 84. 865-866 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Mizoguchi: "Distribution of Neutral Solitons in t-Polyacetylene-Crystalline and Amorphous Regions" Synthetic Metals. 84. 913-914 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Photo-Responsible Liqued Crystalline Conducting Polymers" J.Photopolym.Sci.and Tech.10. 233-240 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Masuda: "Orientation Analysis of Polyacetylene with Liquid Crystalline Side Chains" J.Mol.Struct.441. 173-181 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.Piao: "Novel Liquid-Crystalline Titanocene Complexes with Catalytic Activity for Polymerizations of Acetylene and Phenylacetylene" Polymer. 39. 3559-3564 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Photoluminescent Conjugated Polymers with Liquid Crystallinities" J.Photopolym.Sci.Tech.11. 249-252 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Small Bandgap Type Liquid Crystalline Conjugated Polymers" Mol.Cryst.Liq.Cryst.316. 201-204 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized with a Chiral Nematic Reaction Field" Science. 282. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Syntheses and Properties of Polythiophene Derivatives with Phenylalkyl and Liquid Crystalline Groups" Mol.Cryst.Liq.Cryst.318. 157-177 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized under Chiral Nematic Liquid Crystals" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "A family of Liquid Crystalline Polyarylenevinylenes" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Polyacetylene Derivatives with Stable Radical Groups" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Liquid Crystalline Polyaniline Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Syntheses of Polyaniline Derivatives with Stable Radical Groups and Their Properties" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Syntheses and Properties of Thiophene and Pyrrole based Liquid Crystalline Small-Bandgap Polymers" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.Piao: "Synthesis and Properties of Helical Polyacetylene" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] G.Piao: "Chiroptical Titanium Complexes as Catalytically Active Chiral Dopants Available for Asymmetric Acetylene Polymerization" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.-M.Dai: "Synthesis and Properties of Novel Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.-M.Dai: "Synthesis and Properties of Polythiophene Derivatives with Ferroelectric Liquid Crystalline Substitutents" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.S.Liang: "Synthesis of Polyacetylene Ultra-thin Film" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Oguma: "Synthesis and Properties of Liquid crystalline Poly(p-phenylene) and Poly(p-phenylenevinylene) Derivatives" Synthetic Metals, in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] I.Osaka: "Synthesis and Properties of Liquid Crystalline Polythiophene Derivatives" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Matsushita: "Effects of Pressure on The Electrical Resistivity of Doped Polyacetylene" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X-.M.Dai: "Synthesis and Characterization of Side Chain Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Side-Chain Liquid Crystalline Polyacetylene Derivative-Synthesis,Chemical Doping,and Magnetically Forced Alignment" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Synthesis and Magnetic Propeties of Polyaniline Derivatives with Stable Radical Group" Trans.Mat.Res.Soc.Jpn.,. (in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Goto: "Liquid Crystalline Polyacetylene Derivative Bridged with Metallomesogenic Group" Trans.Mat.Res.Soc.Jpn.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Hilical Polyacetylene Synthesized Under Asymmetric Reaction Field Constructed with Chiral Nematic Liquid Crystals" Mol.Cryst.Liq.Cryst.(in press).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 赤木 和夫: "液晶性共役系高分子の合成と性質" 高分子論文集. 56. 217-233 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 赤木和夫: "光・電子機能有機材料ハンドブック" 編集、堀江一之、谷口彬雄 朝倉書店, 20 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "The Polymeric Materials Encyclopedia. Synthesis,Properties and Applications" J.C.Salamone,Editor,CRC Press,New York, 7 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "The Polymeric Materials Encyclopedia. Synthesis,Properties and Applications" J.C.Salamone,Editor,CRC Press,New York, 12 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Current Trends in Polymer Science" K.L.De Vries et al., Editor,Research Trends,India, 15 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Shirakawa: "Handbook of Conducting Polymers,2nd Ed." Skotheim,Elsenbaumer,Reynolds,Editor,Marcel Dekker,New York, 12 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 白川 英樹: "機能性超分子の設計と将来展望" 監修、緒方直哉、寺野 稔、由井伸彦,シーエムシー, 8 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akagi: "Electrical and Optical Polymer Systems: Fundamentals,Methods,and Applications" Wise,Trantolo,Wnek,Editor,Marcel Dekker,New York, 28 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Shirakara: "Synthesis and Characterization of Highly Conducting Polyacetylene" Synthetic Metals. 69. 3-8 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 69. 13-16 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Polyacetylene Films Prepared by Intrinsic Non-Solvent Polymerization Method - Mechanical Properties and Electrical Conductivities" Synthetic Metals. 69. 29-30 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Fused State ^<13>C-NMR Study on Liquid Crystalline Polyacetylene Derivatives - Magnetically Forced Alignment and Orientational Behavior" Synthetic Metals. 69. 33-34 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Sakamaki: "Solid State Properties and Thermal Isomerization Behavior in Polyactylene Films" Synthetic Metals. 69. 57-58 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Thermotropic Liquid Crystalline Conjugated Polymers, Poly (cyclohexylphenoxyacetylenes) -Synthesis and Properties" Synthetic Metals. 71. 1899-1990 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Toyoshima: "Synthesis and Properties of Polythiophene Derivatives with Liquid Crystalline Substituents" Synthetic Metals. 69. 289-290 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] C.O.Yoon: "Effect of Anisotropy on the Temperature Dependence of Conductivity and Magnetoconductance in heavily Doped Polyacetylene" Synthetic Metals. 69. 79-80 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tanabe: "Isothermal Cis-Trans Isomerization of Polyacetylene" Synthetic Metals. 69. 45-46 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yoshino: "Unique Electrical and Optical Properties of Polyacetylene Derivatives in Liquid Crystal Phase" Synthetic Metals. 69. 46-50 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E.B.Park: "Positive Thermoelectric Power of Alkali-Metal-Doped Polyacetylene" Synthetic Metals. 69. 61-62 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Electrically Conducting Liquid Crystalline Polymers, Mono-Substituted Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.267. 277-282 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Mizoguchi: "Analysis of the ESR Linewidth in Pristine Trans-Polyacetylene" Phys.Rev.B. 51. 8864-8873 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yoshino: "Unique Liquid Crystalline Behavior of Conducting Polyacetylene Derivatives" Mol.Cryst.Liq.Cryst.261. 637-647 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kyotani: "Isothermal Cis-Trans Isomerization Behavior of Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 581-585 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kyotani: "Thermal Isomerization and Morphology of Various Polyacetylene Films" J.Polym.Sci.Part B,Polym.Phys.32. 587-593 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tanabe: "Mechanism of Cis-Trans Tehrmal Isomerization of Polyacetylene" Macromolecules. 28. 4173-4178 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Morphological Alignment of Liquid Crystalline Conducting Polyacetylene Derivatives" Macromolecular Symposia. 104. 137-158 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Conducting Polymers" Polymer Preprints, National Meeting of American Chemical society. 37. 62-63 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Yoshino: "Liquid Crystalline Behaviors of Conducting Polyacetylene Derivative with Mesogenic Substituent and Its Mixture with ferroelectric Liquid Crystal" Jpn.J.Appl.Phys.35. 3964-3970 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Aoki: "Current Progress in Synthesis of Polyacetylene Films" Synthetic Metals. 84, No.1-3. 307-310 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Mutable Morphologies of Polyacetylene Films" Synthetic Metals. 84, No.1-3. 419-420 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Sakamaki: "Relationship between Crystallinity and Electrical Conductivity of Highley Conducting Polyacetylene Films" Synthetic Metals. 84, No.1-3. 365-366 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Ferroelectric Liquid Crystalline Conducting Polymers - Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. 84, No.1-3. 313-316 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Iino: "High Order Structures of Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84, No.1-3. 967-968 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Synthesis and Properties of Photo-Responsible Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. 84, No.1-3. 373-374 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Synthesis and Properties of Small-Bandgap Liquid Crystalline Conjugated Polymers" Synthetic Metals. 84, No.1-3. 385-386 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Toyoshima: "Syntheses and Properties of Poly (thienylenvinylene) Derivatives with Hexyl Groups" Synthetic Metals. 84, No.1-3. 431-432 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "synthesis and ESR Characterizations of Conjugated Polymers with Nitrogen Atoms" Synthetic Metals. 85, No.1-3. 1683-1684 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] G.Piao: "Spin Structures and Properties ofParamagnetic Nickel (II) Complexes with Liquid Crystalline beta-Diketone Ligands" Synthetic Metals. 85, No.1-3. 1669-1670 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Titanocenes with Catalytic Activity for Polymerizations of Acetylene Derivatives" Synthetic Metals. 86, No.1-3. 1879-1880 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] D.Ichinohe: "Magnetic Properties of Poly (m-aniline)" Synthetic Metals. 85, No.1-3. 1671-1672 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Mizoguchi: "Neutral Soliton Cynamics in t-Polyacetylene-Consistent Picture for Magnetic Resonances" Synthetic Metals. 84, No.1-3. 865-866 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Mizoguchi: "Distribution of Neutral Solitons in t-Polyacetylene-Crystalline and Amorphous Regions" Synthetic Metals. 84, No.1-3. 913-914 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Photo-Responsible Liquid Crystalline Conducting Polymers" J.Photoplym.Sci.and Tech.10, No.2. 233-240 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Liquid Crystallne Conducting Polyarylene and Polyarylenevinylene Derivatives-Synthesis and Properties" The Second Symposium on Harmonized Molecular Materials. 19-20 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.masuda: "Orientation Analysis of Polyacetylene with Liquid Crystalline Side Chains" J.Mol.Struct.441 (2-3). 173-181 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] G.Piao: "Novel Liquid-Crystalline Titanocene Complexes with Catalytic Activity for Polymerizations of Acetylene and Phenylacetylene" Polymer. 39, No.15. 3559-3546 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Photoluminescent Conjugated Polymers with Liquid Crystallinities" J.Photopolym.Sci.Tech.11, No.2. 249-252 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Small Bandgap Type Liquid Crystalline Conjugated Polymers" Mol.Cryst.Liq.Cryst.316. 201-204 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized with a Chiral Nematic Reaction Field" Science. 282, No.5394, Nov.27. 1683-1686 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Syntheses and Properties of Polythiophene Derivatives with Phenylalkyl and Liquid Crystalline Groups" Mol.Cryst.Liq.Cryst.318. 157-177 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized under Chiral Nematic Liquid Crystals" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "A family of Liquid Crystalline Polyarylenevinylenes" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Liquid Crystalline Polyacetylene Derivatives with Stable Radical Groups" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Liquid Crystalline Polyaniline Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Syntheses of Polyaniline Derivatives with Stable Radical Groups and Their Properties" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Syntheses and Properties ofThiophene and Pyrrole based Liquid Crystalline Small-Bandgap Polymers" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] G.Piao: "Synthesis and Properties of Helical Polyacetylene" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] G.Piao: "Chiroptical Tianium Complexes as Catalytically Active Chiral Dopants Available for Asymmetric Acetylene Polymerization" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.-M.Dai: "Synthesis and Properties of Novel Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.-M.Dai: "synthesis and Properties of Polythiophene Derivatives with Ferroelectric Liquid Crystalline Substitutents" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.S.Liang: "Synthesis of Polyacetylene Ultra-thin Film" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Oguma: "Synthesis and Properties of Liquid crystalline Poly (p-phenylene) and Poly (p-phenylenevinylene) Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] I.Osaka: "Synthesis and Properties of Liquid Crystalline Polythiophene Derivatives" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A.Matsushita: "Effects of Pressure on The Electrical Resistivity of Doped Polyacetylene" Synthetic Metals. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.M.Dai: "Synthesis and Charactirization of Side Chain Ferroelectric Liquid Crystalline Polyacetylene Derivatives" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Side-Chain Liquid Crystalline Polyacetylene Derivative-Synthesis, Chemical Doping, and Magnetically Forced Alignment" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Synthesis and Magnetic Properties of Polyaniline Derivatives with Stable Radical Group" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Goto: "Liquid Crystalline Polyacetylene Derivative Bridged with Metallomesogenic Group" Trans.Mat.Res.Soc.Jpn.Vol.23, (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Helical Polyacetylene Synthesized Under Asymmetric Reaction Field Constructed with Chiral Nematic Liquid Crystals" Mol.Cryst.Liq.Cryst.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Synthesis and Properties of Liquid Crystalline Conjugated Polymers (in Japanese)" Kobunshi Ronbun Shyu. 56, No.4. 217-233 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: Handbook of Origanic Materials with Light and Electronic Functions (in Japanese) "Conducting Polymers". Ed.by K.Horie and Y.Taniguchi, Asakura Syoten, 20 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: The Polymeric Materials Encyclopedia. Synthesis, Properties and Applications, 5 "Liquid Crystalline Polymers, Poly (acetylene) Derivatives". Ed.by J.C.Salamone.CRC Press, (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: "Polyacetylene Films". Ed.by J.C.Salamone, CRC Press The Polymeric Materials Encyclopedial Synthesis, Properties and Applications, 8, 12 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: Current Trends in Conducting Polymers-Liquid Crystalline Polyacetylene Derivatives. Ed.by K.L.DeVries et al., Research Trands Current Trends in Polymer Science, 2, 15 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Shirakawa: Synthesis ofPolyacetylene. Ed.by, Skotheim, Elsenbaumer, Reynolds, Marcel Dekker, 12 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Shirakawa: Ed.by N.Ogata, M.Terano, N.Yui, CMC Press Desing and Prospect of Functional Supramolecules, (in Japanese). Conducting Supramolecules, 8 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akagi: Ed.by D.L.Wise, D.J.Trantolo, G.E.Wnek, Marcel Dekker Electrical and Optical Polymer Systems : Funcdamentals, Methods, and Applications, Chap.28. Advances in Conducting Polymers, 28 (1998)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-12-08  

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