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1996 Fiscal Year Final Research Report Summary

STUDIES OF BERLINITE REFACTORY FOR DENTAL INVESTMENTS

Research Project

Project/Area Number 07672136
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 補綴理工系歯学
Research InstitutionASAHI UNIVERSITY

Principal Investigator

KAMEMIZU Hideo  ASAHI UNIVERSITY,SCHOOL OF DENTISTRY,ASSISTANT, 歯学部, 助手 (00152877)

Co-Investigator(Kenkyū-buntansha) GOTO Takayasu  ASAHI UNIVERSITY,SCHOOL OF DENTISTRY,LECTURER, 歯学部, 講師 (30121320)
DOI Yutaka  ASAHI UNIVERSITY,SCHOOL OF DENTISTRY,ASSOCIATE PROFESSOR, 歯学部, 助教授 (40116067)
Project Period (FY) 1995 – 1996
KeywordsDental investment / Refractory material / Aluminum phosphate / Berlinite / Hydrothermal synthesis
Research Abstract

AlPO_4 have been known to have the polymorphism similar to silica. The quarts from (berlinite) has been especially attracted by its superior thermal expansion character to silica, refractory material. Berlinite is suggested to be a promising refractory material for dental investments.
In this research, berlinite refractory material has been synthesized by heating and hydrothermal methods and thermal characteristics of synthetic berlinite were investigated by thermal analysis (TG-DTA,TMA).
With the heating method, amorphous AlPO_4? nH_2O was produced after spatulation with distillled water and changed to crystalline berlinite by heating at 100-700゚C for 1h. Berlinite with the reaction system of Al(H_2PO_4)_3-Al_2O_3? 5H_2O showed the highest crystallinity of those with the reaction system used.
Berlinite seed prepared by this heating method, which contained tridymite type and ciristobalite type, were hydrothermally treated in a autoclave at 200-250゚C for 1-7 d.The crystalline berlinite alone is detected by X-ray diffraction analysis. The growth run of crystal along the c-axis was observed by SEM.The crystallinity of berlinite showed higher than that of seed and influenced by the concentration of solution and the duration of hydrothermal treatments.
The reconstructive transformation of berlinite to cristobalite from occurred at 965-1,120゚C.
The dental investment containing synthetic berlinite showed 4-8% thermal expansion at 1,100-1,200゚C.The rapid increase in the thermal expansion occurred at the temperature of reconstructive transformation. The thermal expansion of investments increased with the increasing of both the purerity and the crystallinity of berlinite.
Berlinite refractory was found to be suitable for the use of high thermal expansion invesment, but it is necessary to control the amount of thermal expansion for practial use.

  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] H. Kamemizu: "ESR study on depth of cure of light-cured composite resins" Dentistry in Japan. 32. 92-95 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 鈴木 章一郎: "加熱収縮型埋没材を用いた場合のOptecポーセレンインレーの内側性窩洞への適合性" 岐歯学誌. 22. 410-415 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 後藤 隆泰: "シェブロンノッチを導入した金属焼付用陶材の破壊靭性の評価" 歯科材料・器材. 15. 169-175 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 土井 豊: "アパタイトの焼結に及ぼすレナニットの効果" 歯科材料・器材. 15. 218-225 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 幸田 起英: "炭酸含有アパタイトの加熱と焼結性との関連性" 岐歯学誌. 23. 69-76 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hideo Kamemizu et al: "ESR Study on Depth of Cure of Light-cured Composite Resins" Dent.in Japan. Vol.32. 92-95 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shichiro Suzuki et al: "Fitness of Optec porcelain Inlay to InternalCavity in Application with Shrinkage Type Refractory Cast material" J.Gifu.Dent.Soc.Vol.22 (2). 410-415 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takayasu Goto et al: "Evaluation of Fracture Toughness on Porcelain for Metal-ceramics with Chevron Notches" J.Japan Soc.Dent.Appar.Mat.Vol.15 (2). 169-175 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yutaka Doi et al: "Effect of Rhenanite on Sintering of Apatite" J.Japan Soc.Dent.Appar.Mat.Vol.15 (3). 218-225 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tatsuhide Koda et al: "Thermal Dilatometry and Sintering of Carbonate Apatite" J.Gifu.Dent.Soc.Vol.23 (1). 69-76 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-16  

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