1997 Fiscal Year Final Research Report Summary
Development of A New Optical Resolution Method by Distilllation
| Project/Area Number |
08554022
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Organic chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
TANAKA Koichi Ehime University, Dept.of Applied Chemistry, Associate Prof., 工学部, 助教授 (10116949)
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| Project Period (FY) |
1996 – 1997
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| Keywords | Optical Resolution / Chiral Recognition / Enantiomer / Separation / Inclusion Crystal / Host Compound / Distilllation |
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| Research Abstract |
A new optical resolution method for enantiomers by simple distilllation in the presence of optically active host compounds has been developed. Optically active host compounds having high chiral recognition ability have also been designated and prepared. For expmple, 2-hexanol was found to be resolved very efficiently by simple distilllation in the presence of a new tartaric acid dimer host compound.
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[Publications] F.Toda, K.Tanaka, C.Foces-Foces, L.Infantes, R.M.Claramunt, C.Lopez and J.Elguero: "Host-Guest Chemistry. The Structure and Proton Disorder of the Three-Component Crystal Formed by 3 (5) -Methyl-4-nitropyrazole, (R,R) - (-) trans-4,5-bis (hydroxydiphenylmethyl) -2,2-dimethyl-1,3-dioxolane and Toluene" J.Phys.Org.Chem.9. 611-618 (1996)
Description
「研究成果報告書概要(欧文)」より
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[Publications] K.Tanaka, A.Moriyama and F.Toda: "New Preparative Method for Optically Active 2,2'-and 4,4'-Dihydroxybiphenyl derivatives. A New Chiral Host Compound 4,4'-Dihydroxy-2,2', 3,3', 6,6'-hexamethylbiphenyl" J.Chem.Soc., Perkin Trans.1. 603-604 (1996)
Description
「研究成果報告書概要(欧文)」より
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