1997 Fiscal Year Final Research Report Summary
Production and dissociation dynamics of singly, doubly and triply charged molecularions
| Project/Area Number |
08640651
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Osaka city University |
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Principal Investigator |
MASUOKA Toshio Osaka City University, Faculty of Engineering, Professor, 工学部, 教授 (80047208)
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| Project Period (FY) |
1996 – 1997
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| Keywords | Double ionization / Double ionization cross section / Dissociation of molecular ion / Fragment ions / kinetic-energyrelease / Triple coincidence / Synchrotron radiation / Anisotropic angular distribution |
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| Research Abstract |
Single, double, and triple photoionization of molecules such as CO_2, SO_2, NO_2, N_2O,and CF_4 has been investigated by using a multi coincidence (plotoelectron-photoion, phototion-photoion, photoelectron-photoion-photoion coincidence) system installed at BL3A2, the UVSOR facility of the Institute for Molecular Science, Okazaki. The following are the interesting results obtained on the production and dissociation dynamics of singly, doubly, and triply charged positive molecular ions using synchrotron radiation.
1.The ratio of double to single photoionization, and the single and double photoionization cross sections were determined for SO_2 and NO_2. This made possible to determine separately the ion branching rations of the precursors m^+ and m^<2+> at the excitation energy where the molecular and dissociative single and double photoionization takes place simultaneously.
2. Kinetic-energy release in the dissociation of m^<2+> was investigated by analyzing the photoion-photoion coincidence spectra from the double photoionization threshold to 100 eV.The results show that a major fraction of double photoionization of small molecules at low energy is due to indirect processes such as the nonresonant (m^<**+>) and resonant (m^<****>) autoionization.
3.The dissociation dynamics of NO^2+_ and N_<>O^<2+> was examined by using triple photoelectron-photoion-photoion coincidence (PEPIPICO) method. The PEPIPICO method is important is important to study three-body dissociations whether the dissociation is a simultaneous or sequential process.
Anisotropic dissociation of CO^2+_ and SO^2+_ was examined. From the resultant asymmetry parameter beta, the symmetry involved in the transition has been elucidated.
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