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1998 Fiscal Year Final Research Report Summary

Synthesis of High Performance Composite Materials by using Charge transfer interaction and Their Mechanical Properties

Research Project

Project/Area Number 08651060
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionSophia University

Principal Investigator

SANUI Kohei  Sophia University, Faculty of Science and Technology, Professor, 理工学部, 教授 (30053664)

Co-Investigator(Kenkyū-buntansha) RIKUKAWA Masahiro  Sophia University, Faculty of Science and Technology, Lecturer, 理工学部, 講師 (10245798)
AOKI Takashi  Sophia University, Faculty of Science and Technology, Research Associate, 理工学部, 助手 (80231760)
Project Period (FY) 1996 – 1998
KeywordsCharge transfer / Phase transfer catalyst / Triazine-containing polymer / Nitrated poly (styrene) / Composites / Mechanical properties / Tensile strength / In-situ method
Research Abstract

In this study, Our attention has been focused on a pair of polymers having attractive interaction such as coulombic and charge transfer interactions. 1,3,5-triazine-containing polymers and nitrated poly(styrene)(NPS) were used as electron-donor polymers and electron-acceptor polymers, respectively. The relationship between dispersion of NPS in these composites and their mechanical properties was investigated. The following results could be obtained in this study.
(1) 1,3,5-Triazine-containing polymers(PTX) and (PTH) with high molecular weights could be prepared from 6-dibutylamino-1,3,5-triazine-2,4-dithiol and α, α'-dibromo-p-xylene or 1,6-dibromo-n-hexane by the two phase polycondensation reaction with phase transfer catalyst, respectively.
(2) The composites of (PTX) or (PTH) with poly(styrene) having various nitro group content could be obtained by the solution blend in chloroform. (PTX/NPS)composite films were more transparent than (PTH/NPS)composite films because of better miscibility between PTX and NPS. Nitration of poly(styrene) improved miscibility between PTX or PTH and NPS, which enhanced their tensile strength.
(3) Mechanical properties of the PTX films were greatly improved by blending with NPS in comparison with those of the PTH films.

  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] Kohei. Sanui: "Synthesis of high-performance composites by in situ polycondensation and their mechanical properties"Reactive & Functional Polymers. 30. 293-298 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kohei. Sanui: "Synthesis and Mechanical properties of polymer Composites Containing 1,3,5-Triazine-Based Polymer"Polymer Preprints, Japan. Vol.46. 674-674 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kohei. Sanui: "MACROMOLECULAR DESIGN OF POLYMERIC MATERIALS"KOICHI HATADA, TATSUKI KITAYAMA, OTTO VOGL. 313 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kohei Sanui: "Synthesis of High-Performance composites In-situ Polycondensation and Their Mechanical Properties"Reactive & Functional Polymers. 30. 293-298 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kohei Sanui: "Synthesis and Mechanical Properties of Polymer Composites Containing 1,3,5-Triazine-based Polymer"Polymer Preprints, Japan. 46. 674 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kohei Sanui: "In Situ Polycondensation for Synthesis of High-Performance Polymers"MACROMOLECULAR DESIGNOF POLYMERIC MATERIALS, Marcel Dekker, Inc.. 313 (1997)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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