1998 Fiscal Year Annual Research Report

カーボンアロイ-炭素材料の空間制御と新機能の展開-

Research Project

Project/Area Number	09243103
Research Category	Grant-in-Aid for Scientific Research on Priority Areas (A)
Research Institution	Tokyo Institute of Technology
Principal Investigator	安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)
Co-Investigator(Kenkyū-buntansha)	田邊靖博東京工業大学, 応用セラミックス研究所, 助教授 (70163607) 稲垣道夫北海道大学, 工学部, 教授 (20023054) 大谷朝男群馬大学, 工学部, 教授 (10008469) 金子克美千葉大学, 理学部, 教授 (20009608) 遠藤守信信州大学, 工学部, 教授 (10021015)
Keywords	カーボンアロイ / 黒鉛 / ダイヤモンド / カルビン / ヘテロアトムアロイ / ホモアトミックアロイ / 炭素
Research Abstract	計画班29名、公募班48名の計77名を原子・結晶アロイ班、界面・微構造アロイ班、表面・裏面アロイ班、機能展開班ならびに総括班に分け、それぞれの分担者会議を3回、全体会議を2回、総括班会議を2回開催した。その中で、今年度の特徴は炭素分野以外からのメンバーが多いことから分担者会議でカーボンの基本のセミナーを開催し、1泊2日で、全員同じ宿舎に泊まり、夜遅くまで議論を深めることができた。また、炭素の用語辞典が世界的に無かったことから、用語辞典の編集の第一段階としての用語の洗い出しを行った。シンポジウムは7月28日・29日に群馬県桐生市において行った。また、成果報告会は千葉大学で炭素材料学会の研究会と合同で行った。70件以上の発表を全員で勉強し、議論を可能とするように1人2分のポスタープレビューを行い、その後ポスターで約3時間の個別な質疑が交わされた。これにより、幅広い議論が可能であった。成果報告会での全体会議において井口洋夫・元分子研所長の講演があり、炭素に関する研究の重要性に関してお話を伺うことができた。以上の全体会議、分担者会議、総括班会議によりカーボンアロイ学の検討、先端研究の進展、共同研究の実施により新分野の展開等が可能となった。

Research Products
(31 results)

All Other

All Publications (31 results)

[Publications] 安田榮一: "C/C複合材料の新展開" まてりあ(Materia Japan). 37[4]. 226-229 (1998)
[Publications] 安田榮一、田邊靖博: "「炭素材料」から「カーボンアロイ」へ" 材料. 47[7]. 768-769 (1998)
[Publications] 安田榮一、早田喜穂: "炭素-炭素複合材料の展開" 高分子. 47[8]. 555-558 (1998)
[Publications] M.Endo,C.Kim,T.Hiraoka,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown,M.S.Dresselhaus: "Structural Characterization of Carbons Obtained from Polyparaphenylenes Prepared by the Kovacic and Yamamoto Methods" Journal of Materials Research.13[7]. 2023-2030 (1998)
[Publications] M.Endo,C.Kim,T.Hiraoka,T.Karaki,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Li Storage Behavior in Polyparaphenylene(PPP)-Based Disordered Carbon as a Negative Electrode for Li Ion Batteries" Mol.Cryst.Liq.Sryst.310. 353-358 (1998)
[Publications] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Analysis of the B-doped Mesophase Pitch-based Graphite Fibers by Raman Spectroscopy" Phys.Rev.B. 58[14]. 8991-8996 (1998)
[Publications] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Characterization of Milled Mesophase Pitch-based Carbon Fibers" Carbon. 36[11]. 1633-1641 (1998)
[Publications] M.Endo,C.Kim,T.Karaki,T.Fujino,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "In-situ Raman Study of PPP-based Disordered Carbon as an Anode in a Li Ion Battery" Synth.Met.98. 17-24 (1998)
[Publications] M.Endo,K.Oshida,T.Furuta,F.Minoura,C.Kim,G.Dresselhaus and M.S.Dresselhaus: "Visualized Observation of Pores in Activated Carbon Fibers by HRTEM and Combined Image Processor" Supramolecular Science. 5[3]. 261-266 (1998)
[Publications] C.-H.Kiang,M.Endo,P.M.Ajayan,G.Dresselhaus and M.S.Dresselhaus: "Size Effects in Carbon Nanotubes" Phys.Rev.Lett.81[9]. 1869-1872 (1998)
[Publications] M.Endo,C.Kim,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Anoda Performance in a Li Ion Battery based on Graphitized and B-doped Milled Mesophase Pitch-based Carbon Fibers" Carbon. (in press).
[Publications] M.J.Matthews,M.A.Pimenta,G.Dresselhaus,M.S.Dresselhaus and M.Endo: "Origin of Dispersive Effects of the Raman D Band in Carbon Materials" Phys.Rev.B. (in press).
[Publications] K.Kaneko,C.Ishii,N.Nagai,Y.Hanzawa,N.Setoyama and T.Suzuki: "Characterization of Porous Carbons with High Resolution αs-analysis and Low Temperature Magnetic Susceptibility" Advances Colloid Sci.[76-77]. 295-320 (1998)
[Publications] K.Kaneko: "Nanospace Geometry Sensitive Molecular Assembly" Supramolecular Sci.5. 267-273 (1998)
[Publications] K.Kaneko,Y.Hanzawa,T.Iiyama,T.Kanda,and T.Suzuki: "Cluster-mediated Water Adsorption on Carbon Nanospaces" Adsorption. [5]. 7-13 (1999)
[Publications] Y.Hanzawa,K.Kaneko,N.Yoshizawa,R.W.Pekala and M.S.Dresselhaus: "The Pore Structure Determination of Carbon Aerogels" Adsorption. [4]. 187-195 (1998)
[Publications] Y.Nishi,T.Suzuki,and K.Kaneko: "NO Reduction Over Ultrafine Metal-tailored Microporous Carbon at Ambient Temperature" Carbon. [36]. 1870-1871 (1998)
[Publications] M.E.-Merraoui,H.Tamai,H.Yasuda,T.Kanata,J.Mondori,K.Nadai and K.Kaneko: "Pore Structures of Activated Carbon Fibers from Organometallics/pitch Composites by Nitrogen Adsorption" Carbon. [36]. 1769-1774 (1998)
[Publications] N.Setoyama,T.Suzuki,K.Kaneko: "Simulation Study on Relationship between High Resolution alpha s-plot and Pore Size Distribution for Activated Carbon" Carbon. 36[10]. 1459-1467 (1998)
[Publications] M.Ruike,N.Murase,J.Imai,C.Ishii,T.Suzuki and K.Kaneko: "Intrasolid Interfacial Fractality of a Less-Crystalline Solid" J.Colloid Interface Sci.[207]. 355-362 (1998)
[Publications] K.Kaneko,J.Suzuki,and C.Ishii: "Low Temperature Mgnetic Properties of an O_2 and H_2O Mixed Molecular Assembly Confined in a Graphite Nanospace" Chem.Phys.Lett.[282]. 176-180 (1998)
[Publications] J.Miyawaki,T.Kanda,T.Suzuki,T.Okui,Y.Maeda and K.Kaneko: "Macroscpic Evidence of Enhanced Formation of Methane Nanohydrates in Hydrophobic Nanospaces" J.Phys.Chem.102B[12]. 2187-2192
[Publications] T.Ohkubo,T.Iiyama,K.Nishikawa,T.Suzuki and K.Kaneko: "Pore Width-Dependent Ordering of C_2H_5OH Molecules Confined in Graphitic Slit Nanospaces" J.Phys.Chem.(in press).
[Publications] K.Kaneko,N.Setoyama,G.Li and H.Touhara: "Pore Structures and adsorption properties of fluorinated activated carbon fibers" Tanso. (in press).
[Publications] J.Przepiorski,S.Shiraishi and A.Oya: "Potassium-Loaded ACF against H2S Gas by Blending and Dipping Method:Effect of Subsequent Deodorizations and Regenerations on Deodorant Abilities" J.Odor Res.and Eng.29[2]. 108-114 (1998)
[Publications] J.Przepiorski and A.Oya: "K_2CO_3-Loaded Deodorizing Activated Carbon Fibre against H_2S Gas:Factors Influencing the Deodorizing Efficiency and the Regeneration Method" J.Mater.Sci.Lett.17. 679-682 (1998)
[Publications] J.m.Skowronski,P.Krawczyk,A.Hirano,J.Ozaki and A.Oya: "Elektrochemiczne Wlasciwosci Wlokien Weglowych W Roztworze Alkalicznym(Electrochemical Properties of Carbon Fibers in Alkaline Solution)" Karbo. 43. 49-52 (1998)
[Publications] J.Ozaki,K.Nozawa and A.Oya: "Controlling Factor of Electrocatalytic Activity of Iron-Containing Carbon Materials" Chem.Lett.573-574 (1998)
[Publications] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Steam Activation of a Phosphorous-Containing Phenolic Resin-Based Carbon Fiber" Carbon. 36. 1243-1245 (1998)
[Publications] R.Imamura,K.Matsui,S.Takeda,J.Ozaki and A.Oya: "A New Role for Phosphorus in Graphitization of Phenolic Resin" Carbon. 37. 261-267 (1999)
[Publications] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Ammonia Deodorization Ability of Activated Carbon Fibers Prepared from Phenolic Resin Incorporating Phosphorus in the Network Structure" Carbon. (in press).

1998 Fiscal Year Annual Research Report

カーボンアロイ-炭素材料の空間制御と新機能の展開-

Principal Investigator

安田 榮一 東京工業大学, 応用セラミックス研究所, 教授 (70016830)

Research Products

[Publications] 安田榮一: "C/C複合材料の新展開" まてりあ(Materia Japan). 37[4]. 226-229 (1998)

[Publications] 安田榮一、田邊靖博: "「炭素材料」から「カーボンアロイ」へ" 材料. 47[7]. 768-769 (1998)

[Publications] 安田榮一、早田喜穂: "炭素-炭素複合材料の展開" 高分子. 47[8]. 555-558 (1998)

[Publications] M.Endo,C.Kim,T.Hiraoka,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown,M.S.Dresselhaus: "Structural Characterization of Carbons Obtained from Polyparaphenylenes Prepared by the Kovacic and Yamamoto Methods" Journal of Materials Research.13[7]. 2023-2030 (1998)

[Publications] M.Endo,C.Kim,T.Hiraoka,T.Karaki,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Li Storage Behavior in Polyparaphenylene(PPP)-Based Disordered Carbon as a Negative Electrode for Li Ion Batteries" Mol.Cryst.Liq.Sryst.310. 353-358 (1998)

[Publications] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Analysis of the B-doped Mesophase Pitch-based Graphite Fibers by Raman Spectroscopy" Phys.Rev.B. 58[14]. 8991-8996 (1998)

[Publications] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Characterization of Milled Mesophase Pitch-based Carbon Fibers" Carbon. 36[11]. 1633-1641 (1998)

[Publications] M.Endo,C.Kim,T.Karaki,T.Fujino,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "In-situ Raman Study of PPP-based Disordered Carbon as an Anode in a Li Ion Battery" Synth.Met.98. 17-24 (1998)

[Publications] M.Endo,K.Oshida,T.Furuta,F.Minoura,C.Kim,G.Dresselhaus and M.S.Dresselhaus: "Visualized Observation of Pores in Activated Carbon Fibers by HRTEM and Combined Image Processor" Supramolecular Science. 5[3]. 261-266 (1998)

[Publications] C.-H.Kiang,M.Endo,P.M.Ajayan,G.Dresselhaus and M.S.Dresselhaus: "Size Effects in Carbon Nanotubes" Phys.Rev.Lett.81[9]. 1869-1872 (1998)

[Publications] M.Endo,C.Kim,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Anoda Performance in a Li Ion Battery based on Graphitized and B-doped Milled Mesophase Pitch-based Carbon Fibers" Carbon. (in press).

[Publications] M.J.Matthews,M.A.Pimenta,G.Dresselhaus,M.S.Dresselhaus and M.Endo: "Origin of Dispersive Effects of the Raman D Band in Carbon Materials" Phys.Rev.B. (in press).

[Publications] K.Kaneko,C.Ishii,N.Nagai,Y.Hanzawa,N.Setoyama and T.Suzuki: "Characterization of Porous Carbons with High Resolution αs-analysis and Low Temperature Magnetic Susceptibility" Advances Colloid Sci.[76-77]. 295-320 (1998)

[Publications] K.Kaneko: "Nanospace Geometry Sensitive Molecular Assembly" Supramolecular Sci.5. 267-273 (1998)

[Publications] K.Kaneko,Y.Hanzawa,T.Iiyama,T.Kanda,and T.Suzuki: "Cluster-mediated Water Adsorption on Carbon Nanospaces" Adsorption. [5]. 7-13 (1999)

[Publications] Y.Hanzawa,K.Kaneko,N.Yoshizawa,R.W.Pekala and M.S.Dresselhaus: "The Pore Structure Determination of Carbon Aerogels" Adsorption. [4]. 187-195 (1998)

[Publications] Y.Nishi,T.Suzuki,and K.Kaneko: "NO Reduction Over Ultrafine Metal-tailored Microporous Carbon at Ambient Temperature" Carbon. [36]. 1870-1871 (1998)

[Publications] M.E.-Merraoui,H.Tamai,H.Yasuda,T.Kanata,J.Mondori,K.Nadai and K.Kaneko: "Pore Structures of Activated Carbon Fibers from Organometallics/pitch Composites by Nitrogen Adsorption" Carbon. [36]. 1769-1774 (1998)

[Publications] N.Setoyama,T.Suzuki,K.Kaneko: "Simulation Study on Relationship between High Resolution alpha s-plot and Pore Size Distribution for Activated Carbon" Carbon. 36[10]. 1459-1467 (1998)

[Publications] M.Ruike,N.Murase,J.Imai,C.Ishii,T.Suzuki and K.Kaneko: "Intrasolid Interfacial Fractality of a Less-Crystalline Solid" J.Colloid Interface Sci.[207]. 355-362 (1998)

[Publications] K.Kaneko,J.Suzuki,and C.Ishii: "Low Temperature Mgnetic Properties of an O_2 and H_2O Mixed Molecular Assembly Confined in a Graphite Nanospace" Chem.Phys.Lett.[282]. 176-180 (1998)

[Publications] J.Miyawaki,T.Kanda,T.Suzuki,T.Okui,Y.Maeda and K.Kaneko: "Macroscpic Evidence of Enhanced Formation of Methane Nanohydrates in Hydrophobic Nanospaces" J.Phys.Chem.102B[12]. 2187-2192

[Publications] T.Ohkubo,T.Iiyama,K.Nishikawa,T.Suzuki and K.Kaneko: "Pore Width-Dependent Ordering of C_2H_5OH Molecules Confined in Graphitic Slit Nanospaces" J.Phys.Chem.(in press).

[Publications] K.Kaneko,N.Setoyama,G.Li and H.Touhara: "Pore Structures and adsorption properties of fluorinated activated carbon fibers" Tanso. (in press).

[Publications] J.Przepiorski,S.Shiraishi and A.Oya: "Potassium-Loaded ACF against H2S Gas by Blending and Dipping Method:Effect of Subsequent Deodorizations and Regenerations on Deodorant Abilities" J.Odor Res.and Eng.29[2]. 108-114 (1998)

[Publications] J.Przepiorski and A.Oya: "K_2CO_3-Loaded Deodorizing Activated Carbon Fibre against H_2S Gas:Factors Influencing the Deodorizing Efficiency and the Regeneration Method" J.Mater.Sci.Lett.17. 679-682 (1998)

[Publications] J.m.Skowronski,P.Krawczyk,A.Hirano,J.Ozaki and A.Oya: "Elektrochemiczne Wlasciwosci Wlokien Weglowych W Roztworze Alkalicznym(Electrochemical Properties of Carbon Fibers in Alkaline Solution)" Karbo. 43. 49-52 (1998)

[Publications] J.Ozaki,K.Nozawa and A.Oya: "Controlling Factor of Electrocatalytic Activity of Iron-Containing Carbon Materials" Chem.Lett.573-574 (1998)

[Publications] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Steam Activation of a Phosphorous-Containing Phenolic Resin-Based Carbon Fiber" Carbon. 36. 1243-1245 (1998)

[Publications] R.Imamura,K.Matsui,S.Takeda,J.Ozaki and A.Oya: "A New Role for Phosphorus in Graphitization of Phenolic Resin" Carbon. 37. 261-267 (1999)

[Publications] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Ammonia Deodorization Ability of Activated Carbon Fibers Prepared from Phenolic Resin Incorporating Phosphorus in the Network Structure" Carbon. (in press).

安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)