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1999 Fiscal Year Final Research Report Summary

Development of New Type Cu Base Alloys Obtained by Controling Ordering and Phase Separation

Research Project

Project/Area Number 09355022
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Structural/Functional materials
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

ISHIDA Kiyohito  NICHe, Tohoku University, Professor, 未来科学技術共同研究センター, 教授 (20151368)

Co-Investigator(Kenkyū-buntansha) SUZUKI Yuichi  Yokohama Research Center, Furukawa Electronic Ltd., Manager of the Center, 横浜研究所, 所長(研究職)
OHNUMA Ikuo  Graduate School of Engineering, Tohoku University, Research Associate, 大学院・工学研究科, 助手 (20250714)
KAINUMA Ryosuke  Graduate School of Engineering, Tohoku University, Associate Professor, 大学院・工学研究科, 助教授 (20202004)
KOBAYASHI Kazuo  Peripheral System Research Center Department, Fujitsu Research Center Ltd., Senior Researcher, ペリフェラルシステム研究所, 主管研究員
HOSHI Toshiharu  R & D Center for materials, Yamaha Ltd., Vice-manager of the Center, 研究開発本部・材料研究所, 副所長(研究職)
Project Period (FY) 1997 – 1999
KeywordsHigh Strength Alloys / Shape Memory Alloys / GMR Materials / Phase Separation / Order-disorder Transition / Cu-Mn-Al Alloys / Heusler Alloys / Cu-Al Base Alloys
Research Abstract

It is known that there are many kinds of transformations, such as A2/B2/D03/L21 order-disorder transitions, magnetic transition and phase separation in their ordered phases, in the β phase of the Cu-Al-Mn alloys. The purpose of this study is to develop some new types of Cu base alloys using these transformations. Actually high strength Cu alloys, shape memory (SM) alloys and giant magnetoresistance (GMR) thin films were examined in the present study. All the results obtained in this study are listed as follows :
(1) High Strength Cu Alloys :
In the Cu-13%Al-15%Mn-5%Ni alloys, very high level of tensile strength over 1000MPa were achieved due to aging at 300℃. According to TEM observation, it is seen that the microstructure of the as-aged specimens has a kind of bainate structure with very fine scale. Since such the high level of strength in the Cu base alloys has not been reported except the Cu-Be alloys, the present alloys have a potential for a new kind of high strength Cu base alloys.
(2) Shape Memory Alloys
Effects of alloying elements on the fabricability, Ms temperature and SM properties were examined. It was clarified that the precipitates decrease ductility, Si, Au and Co increase the Ms temperature and the SM properties are strongly influenced by grain size and texture.
(3) Giant Magnetoresistance Thin Films
GMR properties of Cu-Al-Mn alloys with wide range of compositions were examined. It was clarified that the Cu-25%Al-10%Mn alloy which has the volume fraction of Cu2MnAl:Cu3Al=3:7 shows the highest GMR ratio over 4%.
Based on the above results, joint projects for practical applications with some companies are running.

  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] Y.Sutou: "Effect of Co Addition on the Ordering and Martensitic Transformations in Cu-Al-Mn Shape Memory Alloys"Materials Science Forum. 印刷中. (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.J.Liu: "Thermodynamic Assessment of the Aluminum-Manganese Binary Phase Diagram"J.Phase Equilibria. 20. 45-56 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Sutou: "Effect of Alloying Elements on the Shape Memory Properties of Ductile Cu-Al-Mn Alloys"Mat.Sci.Eng.. A273-5. 375-379 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Kainuma: "Phase equilibria and heusler phase stability in the Cu-rich portion of the Cu-Al-Mn system"J.Alloys & Compounds. 266. 191-200 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.J.Liu: "Phase Equilibria in the Cn-rich Portion of the Cu-Al Binary Systems"J.Alloys & Compounds. 264. 201-208 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Sugimoto: "Giant magnetoresistance of Cu_3Al-Cu_2MnAl melt-spun ribbons"J.Alloys & Compounds. 265. 273-280 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石田清仁: "日本金属学会セミナー、計算機シミュレーションを用いた材料開発の基礎と応用"材料開発における状態図の利用. 11 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Sutou: "Effect of Co Addition on the Ordering and Martensitic Transformations in Cu-Al-Mn Shape Memory Alloys"Materials Science Forum. in press. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.J. Liu: "Thermodynamic Assessment of the Aluminum-Manganese Binary Phase Diagram"J. Phase Equilibria. 20. 45-56 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Sutou: "Effect Alloying Elements on the Shape Memory Properties of Ductile Cu-Al-Mn Alloys"Mat. Sci. Eng.. A273-275. 375-379 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R. Kainuma: "Phase equilibria and heusler phase stability in the Cu-rich portion of the Cu-Al-Mn system"J. Alloys and Comp.. 266. 191-200 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.J. Liu: "Phase Equilibria in the Cu-rich Portion of the Cu-Al Binary Systems"J. Alloys and Comp.. 264. 201-208 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Sugimoto: "Giant magnetoresistance of Cu3Al-Cu2MnAl melt-spun ribbons"J. Alloys and Comp.. 265. 273-280 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ishida: "Utilization of Phase Diagrams to Development of New Materials"The JIM Seminar "Fundamentals and Applications on Materials Developments Aided by Computer Simulations". 1-11 (1998)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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