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2000 Fiscal Year Final Research Report Summary

Peculiar reactions between interstitial compounds of transition metals and hydrogen peroxide and characterization of resultant materials

Research Project

Project/Area Number 09450315
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 工業物理化学
Research InstitutionUniversity of Tokyo

Principal Investigator

KUDO Tetsuichi  Univ.of Tokyo, Inst.of Industrial Science, Professor, 生産技術研究所, 教授 (90205097)

Co-Investigator(Kenkyū-buntansha) HIBINO Mitsuhiro  Univ.of Tokyo, Inst.of Industrial Science, Associate Professor, 生産技術研究所, 助教授 (20270910)
MIZUNO Noritaka  Univ.of.Tokyo, Professor, 工学系研究科, 教授 (50181904)
Project Period (FY) 1997 – 2000
KeywordsTungsten carbide / Hydrogen peroxide / Proton conductivity / Nanohybrid materials / Malonic acid / Carboxylic acid / Dimethilmalonic acid / alchoxysillilate
Research Abstract

It has been found that some tungsten oxide clusters like peroxo-oxalato-polytungstate formed by a reaction of tungsten carbide with hydrogen peroxide show high proton conductivity. In this fiscal year have studied a methodology to incorporate such a cluster into an organic matrix to enhance chemical stability, and evaluated nanohybrid materials thus obtained as a proton conductive solid electrolyte membrane.
We obtained a homogeneous solution of a peroxotungstate complex by reacting tungsten trioxide monohydrate with hydrogen peroxide at 40℃ for 24 h. A carboxylic acid such as oxalic, malonic or dimethylmalonic acid was added to the solution at the ratio of 0.25-4.0 to tungsten atom, to yield a chelated complex. This solution was added to a methanol solution of alchoxysillilated poly (ethyleneoxide)-600 and polymerized at 60℃ by a sol-gel process. A homogeneous and transparent membrane was formed.
Proton conductivity of those membranes was measured in the temperature range of 25-160℃ under suturated water vapor pressure by the ac impedance method. Conductivity of a typical membrane at 80℃ was 1.4x10^<-2> Scm-1, which was 10 times higher that that of a composite membrane fabricated by simply blending PEO and tungsten trioxide dihydrate as an inorganic high proton conductor. This means that tungstate clusters dispersed at a nano-level homogeneity throughout the PEO-matrix form a percolation path for fast proton transport. Such a situation was also confirmed by vibration spectra and X-ray diffraction. Although conductivity fell with raising temperature above 100℃, it remained at a level of 10^<-4> Scm^<-1> in the range of 140-160℃. Bulky ligands such as dimethylmalonate tended to suppress conductivity fall at high temperature.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] H.Nakajima, et.al: "Proton Conductivity of Organic/Inorganic Hybrid Polymer Electrolyte Membrane"Proceedings Volume of International Synmposium on Fuel Cells for Vehicles. 190-195 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.M.LI, et.al: "Proton Conductivity of Tungsten Trioxide Hydrates at Intermediate Temperature"Solid State Ionics. 134. 271-279 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.M.LI, et.al: "Proton Conductivity of Some Hydrated Compounds at Intermediate Temperature up to 150℃ under High Water Vapor Pressure"Electrochemistry. 69. 2-5 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kudo: "Proton Conductivity of Tungsten Trioxide Hydrates at Intermediate Temperature"The 7^<th> Asian Conference on Solid State Ionics. (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Tanaka, et.al: "Proton Conductivity of Layered Niobium-doped Tungsten Oxide Hydrate System at Intermediate Temperature"The 12^<th> Symposium of the Materials Research Society of Japan, Program and Abstracts. 170-170 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 田中優実 ら: "酸化タングステン水和物のプロトン伝導性-電気自動車用中温作動燃料電池の開発を目指して"生産研究. 52. 523-527 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Nakajima, et.al: "Protonic Conductivity of Organic/Inorganic Hybrid Polymer Electrolyte Membrane"Proceedings volume of international symposium on fuel cells for vehicles. 190-195 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.M.LI, et.al: "Proton Conductivity of Tungsten Trioxide Hydrates at Intermediate Temperature"Solid State Ionics. 134. 271-279 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.M.LI, et.al: "Proton Conductivity of Some Hydrated Compounds at Intermediate Temperature up to 150℃ under High Water Vapor Pressure"Electrochemistry. 69. 2-5 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kudo: "Proton Conductivity of Tungsten Trioxide Hydrates at Intermediate Temperature"The 7^<th> Asian Conference on Solid State Ionics. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tanaka, et.al: "Proton Conductivity of Layered Niobium-doped Tungsten Oxide Hydrate System at Intermediate Temperature"The 12^<th> Symposium of the Materials Research Society of Japan, Program and Abstracts. 170-170 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Tanaka, et.al: "Proton Conductivity of Tungsten Trioxide Hydrates"Seisan-Kenkyu. 52. 523-527 (2000)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2002-03-26  

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