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1998 Fiscal Year Final Research Report Summary

Development of a new method for the evaluation of third nonlinear optical properties of powder crystals

Research Project

Project/Area Number 09554031
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

NAKAMURA Takayoshi  Research Institute for Electronic Science, Hokkaido Univ., Pro., 電子科学研究所, 教授 (60270790)

Co-Investigator(Kenkyū-buntansha) KIGUCHI Masashi  Advanced Research Laboratory, Hitachi, Ltd., Senior Researcher, 基礎研究所, 主任研究員
AKUTAGAWA Tomoyuki  Research Institute for Electronic Science, Inst., 電子科学研究所, 助手 (60271631)
HASEGAWA  Research Institute for Electronic Science, Asso.Pro., 電子科学研究所, 助教授 (00242016)
KAWAMATA Jun  Research Institute for Electronic Science, Hokkaido Univ., Inst., 電子科学研究所, 助手 (40214689)
INOUE Kuon  Research Institute for Electronic Science, Hokkaido Univ., Pro., 電子科学研究所, 教授 (30021934)
Project Period (FY) 1997 – 1998
Keywordsthe third optical non-linear effect / four wave mixing / evanescent wave / 電荷移動錯体
Research Abstract

In this work, we developed the equipment based on FWMEW to determine the third optical non-linearity precisely of the powder samples having a large absorption band in the visible range. We measured the chi^<(3)> values of the powder or thin-film samples using this equipment and confirmed the effectiveness of the method. At present, due to the large reflection from the prism surface and the diffraction at the prism-sample interface, the application of FWMEW method is limited to the large chi^<(3)> samples such as VO-Pc or Pt-dimethylglyoxim. Although the THEW method has much higher sensitivity, the FWMEW method has the merit that the measurements under non-resonant conditions are easy. Now, we are improving the SIN on the measurements of FWMEW.
In the mean time, we developed the charge-trensfer-complex LB films having optical non-linearity. The preliminary studies on the second order effect by the field modulating spectroscopy were performed. The evaluation of the optical non-linearlity on the power samples of charge transfer compleses such as (TBA)(EtO-C[C(CN)_2]_2and (EtO-TCA) is also started.

  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] T. Nakamura,: "Langmuir-Blodgett Films of Molecular Conductors based on AlkylTCNQ Derivatives" Systhetic Metals. 86. 1843-1844 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Nakamura: "Langmuir-Blodgett Films of Binary Mixture of Donors and Acceptors with Long Alkyl Chains" Systhetic Metals. 86. 1903-1904 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Konuma: "Langmuir-Blodgett Films of Alkyl-Substituted Quinhydrone" Mol.Cryst.Liq.Cryst.294. 209-212 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Akutagawa: "Intermolecular Charge Transfer in the Langmuir-Blodgett Films : Formation of Mixed and Alternate-Layer LB films of Quinhydrone and TTF-TCNQ" Mol.Cryst.Liq.Cryst.296. 383-395 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J. Kawamata: "Molecular and Crystal Structure of Novel Second-Order Nonlinear Optical Crystals : a, a'-Dibenxylidenecycloalkanones" Bull.Chem.Soc.Jpn.71. 2777-2786 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Nakamura: "Electrical Conduction in Monolayers and LB films of BEDOTTF-C_<10>TCNQ/Arachidic Acid Mixed System" Thin Solid Films. 327. 450-453 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Konuma: "Charge-Transfer Interactions and Nonlinear Optical Properties of Tetrathiafulvalene-based Langmuir-Blodgett Films" Thin Solid Films. 327. 348-352 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Ikegami: "Possible Low-Temperature Phase Transition of Langmuir-Blodgett Films of a Charge-Transfer Complex Detected by ESR" Thin Solid Films. 327. 391-394 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Ikegami: "Preparation of Langmuir-Blodgett Films Containing a Charge-Transfer Complex of Alkylated Dicyanoquinonediimine (DCNQI) and Copper" Jpn.J.Appl.Phys. L550-L552 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Nakamura: "Electrical and Nonlinear Optical Properties of Langmuir-Blodgett Films of Charge Transfer Complexes" Mol.Cryst.Liq.Cryst. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Yumoto: "Langmuir-Blodgett Films of BEDO-TTF・CF_3TCNQ" Synthetic Metals. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Ikegami: "Optical Characterization of Langmuir-Blodgett Films of AlkyIDCNQI and AlkylDCNQI-Cu Complexes" Synthetic Metals. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Akutagawa: "Nonlinear Optical Properties of Langmuir-Blodgett Films of Pyrazine-based Dye Molecule" Nonlinear Optics. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Hasegawa: "Valance-Modulation-lnduced Optical Nonlinearlity of Intermolecular Charge-Transfer Langmuir-Blodgett Films" Nonlinear Optics. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J. Kawamata,: "New Method for Evaluating Third-Order Nonlinear Optical Efficiency of Powder Crystals" Nonlinear Optics. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J. Kawamata: "Observation of Third-Order Nonlinear Optical Effects of Metallo-Dimethylglyoxime Complexes by Methods Using the Evanescent Wave" Nonlinear Optics. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Nakamura, T.Konuma, T.Akutagawa, H.Tachibana, R.Azumi, M.Matsumoto, H.Isotalo, S.Horiuchi, H.Yamochi and G.Saito: "Langmuir-Blodgett Films of Molecular Conductors based on AlkylTCNQ Derivatives" Synthetic Metals. 86. 1843-1844 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Nakamura, T.Konuma and T.Akutagawa: "Langmuir-Blodgett Films of Binary Mixture of Donors and Acceptors with Long Alkyl Chains" Synthetic Metals. 86. 1903-1904 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Konuma, T.Akutagawa and T.Nakamura: "Langmuir-Blodgett Films of Alkyl-Substituted Quinhydrone" Mol.Cryst.Liq.Cryst.294. 209-212 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Akutagawa, T.Konuma and T.Nakamura: "Intermolecular Charge Transfer in the Langmuir-Blodgett Films : Formation of Mixed and Alternate-Layer LB films of Quinhydrone and TTF-TCNQ Derivatives" Mol.Cryst.Liq.Cryst.296. 383-395 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kawamata, K.Inoue and T.Inabe: "Molecular and Crystal Structure of Novel Second-Order Nonlinear Optical Crystals : a, a'-Dibenxylidenecycloalkanones" Bull.Chem.Soc.Jpn.71. 2777-2786 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ikegami and T.Nakamura: "Preparation of Langmuir-Blodgett Films Containing a Charge-Transfer Complex of Alkylated Dicyanoquinonediimine (DCNQI) and Copper" Jpn.J.Appl.Phys.37. L550-L552 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Konuma, T.Akutagawa, T.Yumoto, T.Nakamura, J.Kawamata, K.Inoue, T.Nakamura, H.Tachibana, M.Matsumoto, H.Ikegami, S.Horiuchi, H.Yamochi and G.Saito: "Charge-Transfer Interactions and Nonlinear Optical Properties of Tetrathiafulvalene-based Langmuir-Blodgett Films" Thin Solid Films. 327-329. 348-352 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ikegami, S.Kuroda, T.Akutagawa, T.Konuma, T.Nakamura, M.Matsumoto, S.Horiuchi, H.Yamochi and G.Saito: "Possible Low-Temperature Phase Transition of Langmuir-Blodgett Films of a Charge-Transfer Complex Detected by ESR" Thin Solid Films. 327-329. 391-394 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Nakamura, T.Yumoto, T.Akutagawa, R.Azumi, H.Tachibana, M.Matsumoto, S.Horiuchi, H.Yamochi and G.Saito: "Electrical Conduction in Monolayers and LB films of BEDOTTF-C_<10>TCNQ/Arachidic Acid Mixed System" Thin Solid Films. 327-329. 450-453 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Nakamura, T.Yumoto, T.Suzuki, T.Akutagawa, T.Hasegawa, H.Tachibana, M.Matsumoto, S.Horiuchi, H.Ikegami, H.Yamochi and G.Saito: "Electrical and Nonlinear Optical Properties of Langmuir-Blodgett Films of Charge Transfer Complexes" Mol.Cryst.Liq.Cryst.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Yumoto, T.Akutagawa, T.Hasegawa, T.Nakamura, H.Ikegami and G.Saito: "Langmuir-Blodgett Films of BEDO-TTF・CF_3TCNQ" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ikegami, M.Lan and T.Nakamura: "Optical Characterization of Langmuir-Blodgett Films of AlkylDCNQI and AlkylDCNQI-Cu Complexes" Synthetic Metals. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Akutagawa, T.Hasegawa, T.Konuma, T.Nakamura and M.Matsuoka: "Nonlinear Optical Properties of Langmuir-Blodgett Films of Pyrazine-based Dye Molecule" Nonlinear Optics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hasegawa, T.Akutagawa, T.Konuma, T.Nakamura, J.Kawamata and K.Inoue: "Valance-Modulation-Induced Optical Nonlinearlity of Intermolecular Charge-Transfer Langmuir-Blodgett Films" Nonlinear Optics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kawamata, M.Kiguchi, T.Nakamura and K.Inoue: "A New Method for Evaluating Third-Order Nonlinear Optical Efficiency of Powder Crystals" Nonlinear Optics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Kawamata, T.Akutagawa, T.Hasegawa, T.Nakamura, K.Inoue, M.Kiguchi and G.Saito: "Observation of Third-Order Nonlinear Optical Effects of Metallo-Dimethylglyoxime Complexes by Methods Using the Evanescent Wave" Nonlinear Optics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-12-08  

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