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1999 Fiscal Year Final Research Report Summary

Study on New Water Chemistry Control for Stabilization of Oxide Films in Coolant Systems of Light Water Reactors

Research Project

Project/Area Number 09558057
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field エネルギー学一般・原子力学
Research InstitutionThe University of Tokyo

Principal Investigator

ISHIGURE Kenkichi  Graduate School of Engineering, the University of Tokyo, Professor, 大学院・工学系研究科, 教授 (90010975)

Co-Investigator(Kenkyū-buntansha) HIROISHI Daisuke  Graduate School of Engineering, the University of Tokyo, Research Associate, 大学院・工学系研究科, 助手 (20199110)
ASAI Keisuke  Graduate School of Engineering, the University of Tokyo, Associate Professor, 大学院・工学系研究科, 助教授 (60231859)
KATSUMURA Yousuke  Graduate School of Engineering, the University of Tokyo, Professor, 大学院・工学系研究科, 教授 (70111466)
ONO Shoichi  Institute of Research and Innovation, Researcher, 研究員
HENMI Yukio  Toshiba Corp. Nuclear Technology Institute, Senior Researcher, 原子力技術研究所, 主幹
Project Period (FY) 1997 – 1999
Keywordslight water reactor / water chemistry / zinc injection / corrosion product / oxide film / stress corrosion cracking / hydrogen injection / noble metal chemical addition
Research Abstract

The present status of water chemistry in Japanese LWR was widely reviewed from literature and discussion with relevant experts. Then zinc injection and noble metal chemical addition were picked up as major subjects in this project.
It was shown experimentally and analytically that zinc ion injected forms complex ferrites and chromites as a result of interaction with Fe and Cr ions, respectively, on the surfaces of stainless steel and fuel cladding and that cobalt accumulation in the inner oxide layer (chromites) on the surface of stainless steel is suppressed effectively by zinc injection while it is not necessarily effective for the suppression of cobalt pick-up in the outer layer (ferrites).
The experimental result showed that zinc injection forms very thin inner oxide layer of zinc chromite that is very stable thermodynamically and thus reduces remarkably the corrosion of stainless steel, consequently being effective for reducing the cobalt accumulation.
It was also shown experimentall … More y that Cr(VI) ion in aqueous phase oxidizes Zr on contacting with Zircaloy and is precipitated on its surface as amorphous Cr(III) oxides in the absence of zinc ion but as crystaline zinc chromite in the presenee of zinc ion. This Cr deposition is considered to be closely related with cobalt dissolution from the surface deposits of the fuel and was found to be remarkably suppressed by the pre-conditioning of the Zircaloy.
Platinum injection is now expected to make hydrogen injection more effective in BWR, and the chemical behavior of a tetra-ammine complex of Pt(II) and hexa-hydroxo-complex of Pt(IV) was investigated in aqueous solutions under gamma-irradiation.
The Pt(II) complex is easily reduced and forms Pt metal in aqueous phase by heating to 120 〜 150 ℃ while the Pt(IV) complex is not reduced and consequently does not form Pt metal only by the heating. Gamma irradiation readily reduces both of the Pt complexes to Pt metal in the presence of HィイD22ィエD2 or alcohols, but not in the presence of OィイD22ィエD2. The diameters and the catalytic property of the small particles of Pt metal formed were found to be largely affected by the condition of the particle preparation. This result shows that the effect of radiation is very important in the noble metal addition in real plants. Less

  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] Yukiko Hanzawa: "Hydrolysis of Zinc Ion and Solubility of Zinc Oxide in High-Temperature Aqueous Systems"Nucl. Sci. Engineering. 127. 292-299 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kenkichi Ishigure: "The Present Status of Water Chemistry Research and Developments in Japan"Proc. of Seminar on Water Chemistry of Nuclear Reactor Systems '97. 1-13 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yukiko Hanzawa: "Solubility of Zinc Ferrite in High-Temperature Oxygenated Water"J. Nucl. Materials. 252. 209-215 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yosuke Katsumura: "Fast Neutron Radiolysis of Water at Elevated Temperature Relevant to Water Chemistry"Progress in Nuclear Energy. 32. 113-121 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 萩沼真之: "亜鉛イオン共存下の高温水中におけるSUS 304鋼の腐食及びコバルト蓄積に及ぼすγ線照射の効果"日本原子力学会誌. 40. 397-406 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Daisuke Hiroishi: "Thermodynamics of Non-stoichimetric Spinel Compunds"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 116-121 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Daisuke Hiroishi: "Thermodynamics of Chromium Compouds in High Temperature Water"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 847-849 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yukio Hemmi: "^<60>Co Transport Mechanism under Ultra Low Crud Control"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 137-144 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 石榑顕吉: "水化学管理高度化の実績と将来課題"日本原子力学会誌. 41. 842-852 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Hanzawa, D. Hiroishi, C. Matsuura, K. Ishigure, M. Nagao, M. Haginuma: "Hydrolysis of Zinc Ion and Solubility of Zinc Oxide in High-Temperature Aqueous Systems"Nucl. Sci. Engineering. 127. 292-299 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ishigure: "The Present Status of Water Chemistry Research and Developments in Japan"Proc. of Seminar on Water Chemistry of Nuclear Reactor Systems '97. 1-13 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Hanzawa, D. Hiroishi, C. Matsuura, K. Ishigure: "Solubility of Zinc Ferrite in High-Temperature Oxygenated Water"J. Nucl. Materials. 252. 209-215 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Katsumura, G. Sunaryo, D. Hiroishi, K. Ishigure: "Fast Neutron Radiolysis of Water at Elevated Temperature Relevant to Water Chemistry"Progress Nucl. Energy. 32. 113-121 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Haginuma, S. Ono, K. Ishigure et al.: "Effect of Gamma-irradiation on Corrosion and Cobalt Pick-up of 304 type Stainless Steel in the Presence of Zinc Ion in High Temperature Water"J. Atomic Energy Soc. Japan. 40. 397-406 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] D. Hiroishi, K. Ishigure: "Thermodynamics of Non-stoichiometric Spinel Compounds"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 116-121 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] D. Hiroishi, C. Matsuura, K. Ishigure: "Thermodynamics of Chromium Compounds in High Temperature Water"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 847-849 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Hemmi, K. Yamazaki, H. Hirosawa, T. Yotsuyanagi: "ィイD160ィエD1Co Transport Mechanism under Ultra Low Crud Control"Proc. Internat. Conf. on Water Chemistry in Nuclear Power Plants. 137-144 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Ishigure, T. Sakai, I. Makino et al.: "Operational Experience and Future Developments of Advanced Water Chemistry Control of Nuclear Power Plants"J. Atomic Energy Soc. Japan. 41. 842-852 (1999)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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