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1998 Fiscal Year Final Research Report Summary

Crystal growth of III-V nitride semiconductor and its applications by short pulse supersonic beam epitaxy

Research Project

Project/Area Number 09650374
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionThe Institute of Physical and Chemical Research (RIKEN)

Principal Investigator

SHEN Xu-Qiang  RIKEN,Semiconductor Laboratory. Researcher, 半導体工学研究室, 基礎科学特別研究員 (50272381)

Co-Investigator(Kenkyū-buntansha) IWAI Sohachi  RIKEN,Semiconductor Laboratory. Advanced Researcher, 半導体工学研究室, 先任研究員 (40087474)
AOYAGI Yoshinobu  RIKEN,Semiconductor Laboratory. Chief Scientist, 半導体工学研究室, 先任研究員 (70087469)
Project Period (FY) 1997 – 1998
KeywordsSSBE / GSMBE / RHEED / GaN / AlGaN / Quantum dot / In-doping
Research Abstract

Wide band-gap GaN and related III-V nitride materials have shown a strong potential for use in optical devices, especially blue and ultraviolet light emitting diodes (LEDs) and laser diodea (LDs). Many efforts have been done to grow such kind of materials by various growth techniques, such as MOCVD, MBE and etc. We successfully combined two techniques namely SSBE and GSMBE together, for the fabrication of GaN quantum dot structures. We used Si as an "anti-surfactant" for the GaN dot fabrication, where methylsilane (CH_3SiH_3) was used as a Si source. It was reported that CH_3SiH_3 begins to decompose above 800゚C, therefore, it is difficult to use it because usually GSMBE growth is carried out at a relatively low temperature and no Si atoms could be obtained. But, by using SSBE technique, this difficulty was overcome since high energy of the source beam is thought to enhance the decompositon of the CH_3SiH_3 molecules into Si atoms. As a result, GaN quantum dot structures were successfully fabricated by GSMBE on the AlGaN surfaces. Photoluminescence (PL) measurement results showed that there was a strong PL peak from GaN QDs and this peak could be observed from low temperature (l0K) to room temperature (RT).
Furthermore, we developed a new technique to obtain high PL intensity of thin GaN film. This is called In-doping method. In this technique, In flux is supplied during the GaN growth at high growth temperature. From PL data, it was found that the PL intensity of band-edge emission was greatly enhanced by this method. The strongest one is about 37 times stronger in magnitude. Hall measurement results show that the electron mobility of In-doped GaN sample is higher than that of non-doped one. This is a promising way to improve the GaN quality, both optical and electrical, for the future device application.

  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] XO.Shen,S.Tanaka,S,Iwai and Y.Aoyagi: "Chemical beam epitaxy of GaN using triethylgallium and ammonia" J.Crystal Growth. 188. 86-91 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] XO.Shen,S.Tanaka,S.Iwai and Y.Aoyagi: "Real-time observations of the GaN dot formation by controlling growth mode on the AlGaN surface in gas-source molecular beam epitaxy" J.Crystal Growth. 189/190. 147-152 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] XO.Shen,S.Tanaka,S.Iwai and Y.Aoyagi: "Drastical change in the GaN film quality by in-situ controlling surface reconstruction in GSMBE" Mat.Res.Soc.Symp.Proc. 482. 223-226 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] XO.Shen,S.Tanaka,S.Iwai and Y.Aoyagi: "Influence of surface V/III ratio on the film quality during the GaN growth in gas-source molecular beam epitaxy" Jpn.J.Appl.Phys.37. L637-639 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] XO.Shen,S.Tanaka,S.Iwai and Y.Aoyagi: "Enhancement of surface decomposition using supersonic beam: direct evidence from GaN quantum dot formations on AlGaN surface in gas-source molecular beam epitaxy" J.Crystal Growth. in print.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] XO.Shen and Y.Aoyagi: "An approach to achieve intense photoluminescence of GaN" Jpn.J.Appl.Phys.38. L14-16 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "Chemical beam epitaxy of GaN using triethylgallium and ammonia." J.Crystal Growth.188. 86-91 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "The formation of GaN dots on Al_xGa_<1-x>N surfaces using Si in gas-source molecular beam epitaxy." Appl.Phys.Lett.72. 344-346 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "Real-time observations of the GaN dot formation by controlling growth mode on the AlGaN surface in gas-source molecular beam epitaxy" J.Crystal Growth. 189/190. 147-152 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "Drastical change in the GaN film quality by in-situ controlling surface reconstructions in GSMBE" Mat.Res.Soc.Symp.Proc. Vol.482. 223-226 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "Influences of surface V/III ratio on the film quality during the GaN growth in gas-source molecular beam epitaxy" Jpn.J.Appl.Phys.37. L637-639 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, S.Tanaka, S.Iwai and Y.Aoyagi: "Enhancement of surface decomposition using supersonic beam : direct evidence from GaN quantum dot formations on AlGaN surface in gas-source molecular beam epitaxy" J.Crystal Growth. (in print).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen and Y.Aoyagi: "An approach to achieve intense photoluminescence of GaN" Jpn.J.Appl.Phys. 38. L14-16 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] X.O.Shen, P.Ramvall, P.Riblet and Y.Aoyagi: "Improvements of the optical and electrical properties of GaN films by using In-doping method during growth" (submitted).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-12-08  

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