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1999 Fiscal Year Final Research Report Summary

Fabrication of Highly Efficient Slid State Indicator Phase for Chemiluminescence Sensing

Research Project

Project/Area Number 09650894
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業分析化学
Research InstitutionTOKYO METOROPOLITAN UNIVERSITY

Principal Investigator

YAMADA Masaki  University, Graduate school of Engineering, Department of Applied Chemistry, Professor, 工業研究科, 教授 (10087322)

Project Period (FY) 1997 – 1999
KeywordsChemiluminescence / Oxidative radical / Luminol / Oxygen sensor / Surfactant bilayer / Adrenaline sensor / Basic metal oxide / Anion-exchange resin
Research Abstract

1. Fabrication of solid state indicator phase using base catalyst
(1) Basic metal (magnesium and barium) peroxides obtained by treating their corresponding metal oxides with a hydrogen peroxide solution were found to be efficient indicator phases for chemiluminescence (CL) sensing of luminol and lucigenin. They were successfully utilized for the post-column detection of the luminol derivatives of some carbonic acids. And also it was found that the treatment of bariumoxide with a peroxomonosulfate solution and a mixed solution of hydrogen peroxide and nitrite yielded oxidative reaction media inducing CL for luminol and nucleic bases.
(2) Strongly anionic ion-exchange resins on which various chemical species were immobilized exhibited sensitive indicator phases for CL sensor. For instance, luminol-immobilized resins were usable for a OィイD22ィエD2 gas sensor capable of detecting OィイD22ィエD2 gas as low as ppm levels. The sensor was applied to determine OィイD22ィエD2 gas in city gas and NィイD22ィエD2 gas.
2. Fabrication of solid state indicator phase using surfactant bilayer
Both bilayer - forming surfactant and manganese (II) - porphylin complex molecules were immobolized on the matrices like polymers, sol-gel silica or paraffins. They were examined for adrenalin sensing and successfully applied to real samples.
3. Identification of reactive species on the indicator phase
The CL generation by just adding analyte solution on the indicator phase fabricated on the basic metal oxides strongly suggests the existence of reactive species on their surface. Thus spectroscopic (ESR and RF) and chemical methods were subjected to the identification of the reactive species. As results, hydroxyl, superoxide, sulfate and nitrogen dioxide radicals were found to exist on their surface, respectively.

  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] 後藤 肇: "ルミノール及びルシゲニン化学発光の反応場としての塩基性金属過酸化物"分析化学. 46. 711-717 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 後藤 肇: "塩基性金属過酸化物上でルミノール化学発光に関与する活性酸素種の同定"分析化学. 47. 417-422 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 林 金明: "新しい化学発光系による化学発光分析法"ぶんせき. 865-872 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sigeharu Tsukada: "Chemiluminescence from fluorescent organic comounds induced by dobalt(II) catalyzed decomposition of peroxymonosulfate"Anal. Chim. Acta. 371. 163-170 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Jin-Ming Lin: "Flow injection chemiluminescence determination of trace amounts of hydrogen peroxide in snow-water using KIO_4-K_2CO_3 system"Anal. Chim. Acta. 371. 171-176 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takuya Okamoto: "Luminol immobilized anion-exchange resin as an indicator phase for a chemiluminescence oxygen gas sensor"Anal. Commun.. 36. 181-183 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Jin-Ming Lin: "Oxidation reaction between periodate and polhydroxyl compounds and its application to chemiluminescence"Anal. Chem.. 71. 1760-1766 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Jin-Ming Lin: "On-line chmiluminescence detection for capilary electrophoresis based on the reaction of barium peroxide with luminscence reagents"J. Cromatogr. A. 844. 341-348 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 後藤 肇: "過酸化バリウムを化学発光反応場に用いる胆汁酸のポストカラム検出"分析化学. 48. 945-948 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 後藤 肇: "不均一反応場を利用する化学発光計測"ケミカル・エンジニヤリング. 44. 871-877 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Soichi Hnaoka: "Chemiluminescence behavior of the decomposition of hydrogen peroxide catalyzed by copper(II)-amino acid complexes and its aplication to the determination of tryptophan and phenylalanine"Anal. chim. Akta. (in print).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hajime Goto: "Basic metal peroxides as reaction media for luminol and lucigenin chemiluminescence sensing"Bunseki Kagaku. 46. 711-717 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hajime Goto: "Characterization of reactive oxygen species on basic metal peroxides as reaction media for luminol and lucigenin chemiluminescence sensing"Bunseki Kagaku. 47. 417-422 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Jin-M. Lin: "Chemiluminescence analysis using new chemiluminescence system"Bunseki. 865-872 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Shigeharu Tsukada: "Chemiluminescence from fluorescent organic compounds induced by cobalt (II) catalyzed decomposition of peroxymonosulfate"Anal. Chim. Acta.. 371. 163-170 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Jin-M. Lin: "Flow injection chemiluminescence determination of trace amounts of hydrogen peroxide in snow-water using KIOィイD24ィエD2 - KィイD22ィエD2COィイD23ィエD2 system"Anal. Chim. Acta.. 371. 171-176 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takuya Okamoto: "Luminol immobilized anion-exchange resin as an indicator phase for a chemiluminescence oxygen gas sensor"Anal. Commun.. 36. 181-183 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Jin-M. Lin: "Oxidation reaction between periodate and polyhydroxyl compounds and its application to chemiluminescence"Anal. Chem.. 71. 1760-1766 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Jin-M. Lin: "On-line chemiluminescence detection for capillary electrophoresis based on the reaction of barium peroxide with luminescence reagents"J. Cromatogr. A. 844. 341-348 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hajime Goto: "Post-column detection of isoluminol-labelled bile acids on bariumperoxide as chemiluminescence reaction media"bunseki Kagaku. 48. 945-948 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hajime Goto: "Cemiluminescence sensing in heterogeneous reaction media"Chem. Eng.. 44. 871-877 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Soichi Hanaoka: "Chemiluminescence behavior of the decomposition of hydrogen peroxide catalyzed by copper (II)-amino acid complexes and its"Anal. Chim. Acta. (in print).

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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